三维有序氧化钛中空球薄膜的制备及其光电性能*

doi:10.11901/1005.3093.2014.592

材料研究学报

2015, Vol. 29

Issue (11): 835-842 DOI: 10.11901/1005.3093.2014.592

本期目录 | 过刊浏览

三维有序氧化钛中空球薄膜的制备及其光电性能*

陈爱莲¹,唐昭芳²,陈杨^2,³(

),陈志刚³

1. 常州大学机械工程学院常州 213164
2. 常州大学材料科学与工程学院常州 213164
3. 苏州科技学院江苏省环境功能材料重点实验室苏州 215009

Synthesis and Photovoltaic Performance of Three-dimensional Ordered TiO₂ Hollow Sphere Films

Ailian CHEN¹,Zhaofang TANG²,Yang CHEN^2,^**(

),Zhigang CHEN³

1. School of Mechanical Engineering, Changzhou University, Changzhou 213164, China
2. School of Materials Science and Engineering, Changzhou University, Changzhou 213164, China
3. Jiangsu Key Laboratory for Environment Functional Materials, Suzhou University of Science and Technology, Suzhou 215009, China

引用本文:

陈爱莲,唐昭芳,陈杨,陈志刚. 三维有序氧化钛中空球薄膜的制备及其光电性能*[J]. 材料研究学报, 2015, 29(11): 835-842.
Ailian CHEN, Zhaofang TANG, Yang CHEN, Zhigang CHEN. Synthesis and Photovoltaic Performance of Three-dimensional Ordered TiO₂ Hollow Sphere Films[J]. Chinese Journal of Materials Research, 2015, 29(11): 835-842.

全文: PDF(6083 KB) HTML

摘要:

为了提高染料敏化太阳能电池(DSSC)的光电转化效率, 以聚苯乙烯微球(290-300 nm)自组装形成的胶体晶体为牺牲模板制备了三维有序氧化钛中空球(3DOHS-TiO₂)薄膜材料, 考察了以P25-TiO₂/3DOHS-TiO₂双层膜为光阳极的电池的光电转化特性。扫描电镜结果表明: 3DOHS-TiO₂样品中的TiO₂中空球呈紧密六方排列, 其球心距为260-270 nm, 壁厚为40-50 nm, 相邻的TiO₂中空球彼此之间通过孔洞相互连接; 透射电镜结果表明: TiO₂中空球体由尺寸约为10 nm的锐钛矿相氧化钛颗粒组成, 其壳壁上有由颗粒间堆积形成的介孔。光电性能测试结果表明: P25-TiO₂/3DOHS-TiO₂/DSSC的光电转化效率可达6.98%, 明显优于常规的P25-TiO₂/DSSC(4.32%), 其原因是双层膜光阳极中的3DOHS-TiO₂薄膜对太阳光散射和捕捉能力的增强。

关键词 ：无机非金属材料, 氧化钛, 三维有序结构, 胶体晶体模板, 染料敏化太阳能电池

Abstract：

To improve the properties of dye-sensitized solar cells (DSSC), three-dimensional ordered TiO₂ hollow spheres (3DOHS-TiO₂) films were synthesized using polystyrene spheres (290-300 nm) colloidal crystals as sacrificial templates. The photoelectric conversion performances of the DSSC based on double-layered films P25-TiO₂/3DOHS-TiO₂ were investigated. SEM results show that the orderly arranged TiO₂ hollow spheres form hexangular and square arrays, and the hollow spheres connect to their neighbors through pores. The center-center spacing of the 3DOHS-TiO₂is 260-270 nm, and the thickness of the hollow shells is 40-50 nm. TEM results show that the shell is composed of a lot of tiny particles resulting in a mesoporous framework. The mean size of the anatase TiO₂ nanoparticles of the shells is ca.10 nm as estimated from the HRTEM image. By compared with the P25-TiO₂ nanocrystalline DSSC (η=4.32%), the DSSC based on the double-layered films P25-TiO₂/3DOHS-TiO₂ exhibit a higher photoelectric performance (η=6.98%). The enhancement of the cell performance can be attributed to the enhancement of light harvesting of the light scattering ability of the layer 3DOHS-TiO₂.

Key words： inorganic non-metallic materials TiO₂ three-dimensional ordered structure colloidal crystal template dye-sensitized solar cell

收稿日期: 2014-10-16

基金资助:*国家自然科学基金项目51205032,江苏省自然科学基金项目BK2012158,苏州市应用基础研究计划项目SYG201316和江苏省环境功能材料重点实验室开放课题SJHG1302资助项目。

	服务

	把本文推荐给朋友
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	陈爱莲
	唐昭芳
	陈杨
	陈志刚
44.8K

链接本文:

https://www.cjmr.org/CN/10.11901/1005.3093.2014.592 或 https://www.cjmr.org/CN/Y2015/V29/I11/835

图1 3DOHS-TiO2薄膜材料的制备工艺示意图

图2 胶体晶体模板表层和截面的SEM像

图3 胶体晶体模板和模板/氧化钛前驱体复合物的TGA曲线

图4 3DOHS-TiO2样品的XRD谱

图5 3DOHS-TiO2样品表层和截面的FESEM像

图6 四方排列胶体晶体模板和3DOHS-TiO2样品的FESEM像

图7 3DOHS-TiO2样品的TEM像和选区电子衍射花样

图8 3DOHS-TiO2样品的N2吸附-脱附等温线及孔径分布曲线

图9 电池的光电流密度-电压特征曲线

表1 电池的光电转化性能参数

1	B. O'Regan, M. Gr?tzel,A low-cost, high efficiency solar cell based on dye-sensitized colloidal TiO2 films, Nature, 353(6346), 737(1991)
2	A. Yella, H. Lee, H.N. Tsao, C. Yi, A.K. Chandiran, M. Nazeeruddin, E.W. Diau, C. Yeh, S.M. Zakeeruddin, M. Gr?tzel,Porphyrin-sensitized solar cells with Cobalt (II/III)-based redox electrolyte exceed 12 percent efficiency, Science, 334, 629(2011)
3	A. Hagfeldt, G. Boschloo, L. Sun, L. Kloo, H. Pettersson,Dye-Sensitized Solar Cells, Chem. Rev., 110(11), 6595(2010)
4	A. B. F. Martinson, J. W. Elam, J. T. Hupp, M. J. Pellin,ZnO nanotube based dye-sensitized solar cells, Nano Lett., 7(8), 2183(2007)
5	B. Tan, E. Toman, Y. Li, Y.Y. Wu,Zinc stannate (Zn2SnO4) dye-sensitized solar cells, J. Am. Chem. Soc., 129(14), 4162(2007)
6	H. Zheng, Y. Tachibana, K. Kalantar-zadeh. Dye-sensitized solar cells based on WO3, Langmuir, 26(24), 19148(2010)
7	S. Mori, S.Fukuda, S. Sumikura, Y. Takeda, Y. Tamaki, E. Suzuki, T. Abe,Charge-transfer processes in Dye-sensitized NiO solar cells, J. Phys. Chem. C, 12(41), 16134(2008)
8	P. Tiwana, P. Docampo, M.B. Johnston, H.J. Snaith, L.M. Herz,Electron mobility and injection dynamics in mesoporous ZnO, SnO2, and TiO2 films used in dye-sensitized solar cells, ACS Nano, 5(6), 5158(2011)
9	K. Fan, W. Zhang, T. Peng, J. Chen, F. Yang,Application of TiO2 fusiform nanorods for dye-sensitized solar cells with significantly improved efficiency, J. Phys. Chem. C, 115(34), 17213(2011)
10	B. Liu, E. S. Aydil,Growth of oriented single-crystalline rutile TiO2 nanorods on transparent conducting substrates for Dye-sensitized solar cells, J. Am. Chem. Soc., 131(11), 3985(2009)
11	M. Ye, X. Xin, C. Lin, Z. Lin,High efficiency Dye-sensitized solar cells based on hierarchically structured nanotubes, Nano Lett., 11(8), 3214(2011)
12	Q. Zheng, H. Kang, J. Yun, J. Lee, J.H. Park, S. Baik,Hierarchical construction of self-standing anodized titania nanotube arrays and nanoparticles for efficient and cost-effective front-illuminated dye-sensitized solar cells, ACS Nano, 5(6), 5088(2011)
13	LUO Huaming,LIU Zhiyong, BAI Chuanyi, LU Yuming, CAI Chuanbing, TiO2 nanotube based dye-sensitized photoanode, Journal of Inorganic Materials, 28(5), 521(2013)
13	(罗华明, 刘志勇, 白传易, 鲁玉明, 蔡传兵, 基于二氧化钛纳米管的染料敏化电池光阳极研究, 无机材料学报, 28(5), 521(2013))
14	Y. Chen, Z. Tang, Z. Chen,Fabrication of three-dimensionally ordered macroporous TiO2 films with enhanced photovoltaic conversion efficiency, J. Inorg. Organomet. Polym., 23, 839(2013)
15	J. Shin, J.H. Moon,Bilayer inverse opal TiO2 electrodes for dye-sensitized solar cells via post-treatment, Langmuir, 27(10), 6311(2011)
16	Y. J. Kim, Y. H. Lee, M. H. Lee, H. J. Kim, J. H. Pan, G. I. Lim, Y. S. Choi, K. Kim, N. Park, C. Lee, W. I. Lee,Formation of efficient dye-sensitized solar cells by introducing an interfacial layer of long-range ordered mesoporous TiO2 thin film, Langmuir, 24(22), 13225(2008)
17	F. Sauvage, D. Chen, P. Comte, F. Huang, L. Heiniger, Y. Cheng, R.A. Caruso, M. Graetzel,Dye-sensitized solar cells employing a single film of mesoporous TiO2 beads achieve power conversion efficiencies over 10%, ACS Nano, 4(8), 4420(2010)
18	X. Zhang, F. Liu, Q. Huang, G. Zhou, Z. Wang,Dye-sensitized W-doped TiO2 solar cells with a tunable conduction band and suppressed charge recombination, J. Phys. Chem. C, 115(25), 12665(2011)
19	W. Guo, Y. Shen, L. Wu, Y. Gao, T. Ma,Effect of N dopant amount on the performance of Dye-sensitized solar cells based on N-doped TiO2 electrodes, J. Phys. Chem. C, 115(43), 21494(2011)
20	Y. Zhang, J. Zhang, P. Wang, G. Yang, Y. Zhu,Anatase TiO2 hollow spheres embedded TiO2 nanocrystalline photoanode for dye-sensitized solar cells, Mater. Chem. Phys., 123, 595(2010)
21	J. Yu, Q. Li, Z. Shu,Dye-sensitized solar cells based on double-layered TiO2 composite films and enhanced photovoltaic performance, Electrochim. Acta, 56, 6293(2011)
22	J. Yu, J. Fan, B. Cheng,Dye-sensitized solar cells based on anatase TiO2 hollow spheres/carbon nanotube composite films, J. Power Sources, 196, 7891(2011)
23	J. Zhang, Z. Sun, B. Yang. Self-assembly of photonic crystals from polymer colloids, Curr. Opin. Colloid Interface Sci., 14, 103(2009)
24	D. Kang, Y. Lee, C. Cho, J. H. Moon,Inverse opal carbons for counter electrode of dye-sensitized solar cells, Langmuir, 28, 7033(2012)
25	CHEN Yang,TANG Zhaofang, ZHU Yajuan, YAO Chao, Synthesis, characterization and low-temperature reducibility of inverse opal three-dimensional ordered macroporous CeO2, Chinese Journal of Materials Research, 26(5), 527(2012)
25	(陈杨, 唐昭芳, 祝雅娟, 姚超, 反蛋白石结构三维有序大孔CeO2的制备、表征及其低温还原性能, 材料研究学报, 26(5), 527(2012)
26	YU Bing,CONG Hailin, XUE Lei, LIU Xuesong, CHEN Zhaojing, Fabrication and application progress of colloidal crystals, Chinese Science Bulletin, 59(9), 752(2014)
26	(于冰, 丛海林, 薛蕾, 刘学松, 陈昭晶, 胶体晶体制备与应用研究进展, 科学通报, 59(9), 752(2014))
27	ZHEN Yifan,LI Guohua, TIAN Wei, MA Chunan, In situ XRD study on the phase transformation of nanoanatase, Chinese Journal of Inorganic Chemistry, 23(6), 1121(2007)
27	(郑遗凡, 李国华, 田伟, 马淳安, 纳米锐钛矿相变的原位XRD研究, 无机化学学报, 23(6), 1121(2007))
28	J. Wang, F. Li, H. Zhou, P. Sun, D. Ding, T. Chen,Silica hollow spheres with ordered and radially oriented amino-functionalized mesochannels, Chem. Mater., 21, 612(2009)
29	M. T. Wu, T. J. Chow,TiO2 particles prepared by size control self-assembly and their usage on dye-sensitized solar cell, Microporous Mesoporous Mater., 196, 354(2014)

[1]	宋莉芳, 闫佳豪, 张佃康, 薛程, 夏慧芸, 牛艳辉. 碱金属掺杂MIL125的CO₂ 吸附性能[J]. 材料研究学报, 2023, 37(9): 649-654.
[2]	邵鸿媚, 崔勇, 徐文迪, 张伟, 申晓毅, 翟玉春. 空心球形AlOOH的无模板水热制备和吸附性能[J]. 材料研究学报, 2023, 37(9): 675-684.
[3]	任富彦, 欧阳二明. g-C₃N₄ 改性Bi₂O₃ 对盐酸四环素的光催化降解[J]. 材料研究学报, 2023, 37(8): 633-640.
[4]	刘明珠, 樊娆, 张萧宇, 马泽元, 梁城洋, 曹颖, 耿仕通, 李玲. SnO₂ 作散射层的光阳极膜厚对量子点染料敏化太阳能电池光电性能的影响[J]. 材料研究学报, 2023, 37(7): 554-560.
[5]	李延伟, 罗康, 姚金环. Ni(OH)₂ 负极材料的十二烷基硫酸钠辅助制备及其储锂性能[J]. 材料研究学报, 2023, 37(6): 453-462.
[6]	余谟鑫, 张书海, 朱博文, 张晨, 王晓婷, 鲍佳敏, 邬翔. N掺杂生物炭的制备及其对Co²⁺ 的吸附性能[J]. 材料研究学报, 2023, 37(4): 291-300.
[7]	朱明星, 戴中华. SrSc_0.5Nb_0.5O₃ 改性BNT基无铅陶瓷的储能特性研究[J]. 材料研究学报, 2023, 37(3): 228-234.
[8]	刘志华, 岳远超, 丘一帆, 卜湘, 阳涛. g-C₃N₄/Ag/BiOBr复合材料的制备及其光催化还原硝酸盐氮[J]. 材料研究学报, 2023, 37(10): 781-790.
[9]	周毅, 涂强, 米忠华. 制备方法对磷酸盐微晶玻璃结构和性能的影响[J]. 材料研究学报, 2023, 37(10): 739-746.
[10]	谢锋, 郭建峰, 王海涛, 常娜. ZnO/CdS/Ag复合光催化剂的制备及其催化和抗菌性能[J]. 材料研究学报, 2023, 37(1): 10-20.
[11]	余超, 邢广超, 吴郑敏, 董博, 丁军, 邸敬慧, 祝洪喜, 邓承继. 亚微米Al₂O₃ 对重结晶碳化硅的作用机制[J]. 材料研究学报, 2022, 36(9): 679-686.
[12]	方向明, 任帅, 容萍, 刘烁, 高世勇. 自供能Ag/SnSe纳米管红外探测器的制备和性能研究[J]. 材料研究学报, 2022, 36(8): 591-596.
[13]	李福禄, 韩春淼, 高嘉望, 蒋健, 许卉, 李冰. 氧化石墨烯的变温发光[J]. 材料研究学报, 2022, 36(8): 597-601.
[14]	朱晓东, 夏杨雯, 喻强, 杨代雄, 何莉莉, 冯威. Cu掺杂金红石型TiO₂ 的制备及其光催化性能[J]. 材料研究学报, 2022, 36(8): 635-640.
[15]	熊庭辉, 蔡文汉, 苗雨, 陈晨龙. ZnO纳米棒阵列和薄膜的同步外延生长及其光电化学性能[J]. 材料研究学报, 2022, 36(7): 481-488.

Viewed

Full text

Abstract

Cited

Shared

Discussed