聚丙烯酰胺凝胶合成尖晶石纳米铝酸锌的络合机理及发光性能

doi:10.11901/1005.3093.2014.570

材料研究学报

2015, Vol. 29

Issue (10): 721-728 DOI: 10.11901/1005.3093.2014.570

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聚丙烯酰胺凝胶合成尖晶石纳米铝酸锌的络合机理及发光性能

孙光壮^1,²,王仕发¹,孙光爱¹(

),向霞²,祖小涛²

1. 中国工程物理研究院核物理与化学研究所绵阳 621900
2. 电子科技大学物理电子学院成都 610054

Synthesis of Spinel Nano-ZnAl₂O₄by Polyacrylamide Gel Method and Its Chelating Mechanism and Photoluminescence Performance

Guangzhuang SUN^1,²,Shifa WANG¹,Guangai SUN^1,^**(

),Xia XIANG²,Xiaotao ZU²

1. Institute of Nuclear Physics and Chemistry, China Academy of Engineering Physics, Mianyang 621900, China
2. School of Physical Electronics, University of Electronic Science and Technology of China, Chengdu 610054, China

引用本文:

孙光壮,王仕发,孙光爱,向霞,祖小涛. 聚丙烯酰胺凝胶合成尖晶石纳米铝酸锌的络合机理及发光性能[J]. 材料研究学报, 2015, 29(10): 721-728.
Guangzhuang SUN, Shifa WANG, Guangai SUN, Xia XIANG, Xiaotao ZU. Synthesis of Spinel Nano-ZnAl₂O₄by Polyacrylamide Gel Method and Its Chelating Mechanism and Photoluminescence Performance[J]. Chinese Journal of Materials Research, 2015, 29(10): 721-728.

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摘要:

用改进的聚丙烯酰胺凝胶法制备颗粒近似呈球形且粒度均匀的ZnAl₂O₄纳米颗粒, 并制备了3种锌铝摩尔比的ZnAlO样品。XRD结果表明, 当锌铝摩尔比为1∶1.8和1∶2时, 在900℃煅烧干凝胶制备的样品均为纯相的ZnAl₂O₄粉体。SEM结果表明, 锌铝摩尔比为1∶2制备的样品其颗粒尺寸随着煅烧温度的提高而增大, 且在900℃出现严重的团聚。荧光光谱分析结果表明, 激发波长为352 nm时出现一个469 nm的蓝光发射峰。基于实验结果, 研究了其络合机理和发光机理。

关键词 ：无机非金属材料, 聚丙烯酰胺凝胶法, ZnAl₂O₄, 蓝光发射, 络合机理

Abstract：

Spherical ZnAl₂O₄ nanoparticles with uniform size distribution were synthesized by a modified polyacrylamide gel method, and three xerogel ZnAlO samples with different ratios of Zn to Al were prepared. X-ray diffraction analysis results show that the ZnAl₂O₄ powders can be obtained after calcination at 900℃ for the two xerogel samples with mole ratios of Zn²⁺:Al³⁺=1:1.8 and 1:2, respectively. Scanning electron microscope images reveal that the particle size of the sample with mole ratio of 1:2 increases with the increasing calcination temperature; when calcination at 900℃, significant agglomeration of particles can be observed. The photoluminescence emission spectrum for ZnAl₂O₄ nanoparticles detected at λ_ex= 352 nm shows a blue emission peak located at 469 nm. Finally, the chelating mechanism and luminescence mechanism of ZnAl₂O₄ nanoparticles have been discussed based on the experimental results.

Key words： inorganic non-metallic materials polyacrylamide gel method ZnAl₂O₄ blue-light emission chelating mechanism

收稿日期: 2014-10-08

基金资助:* 国家自然科学基金11105128资助项目。

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图1 S-0–Zn∶Al=1∶1 和 S-01- Zn∶Al=1∶1.8制备的干凝胶在900℃煅烧样品的XRD谱和Zn∶Al=1∶2干凝胶在不同温度煅烧ZnAl2O4样品的XRD谱

表1 样品S-01-S5的晶胞体积、晶粒尺寸、晶面间距以及晶胞参数

图2 不同锌铝离子比柠檬酸络合锌、铝离子的3种可能的络合机理

图3 ZnAl2O4干凝胶的TG/DTA曲线

图4 不同煅烧温度ZnAl2O4纳米颗粒的SEM像

图5 不同煅烧温度ZnAl2O4颗粒的尺寸分布图

图6 不同煅烧温度ZnAl2O4样品的红外光谱图

图7 不同煅烧温度样品的激发谱和发射谱, 插图为ZnAl2O4干凝胶在600℃煅烧样品分别在313 nm 和352 nm两个波长激发下的发射谱

图8 ZnAl2O4纳米颗粒的发光机制

1	E. L. Foletto, S. Battiston, J. M. Sim?es, M. M. Bassaco, L. S. F. Pereira,é. M. de Moraes Flores, E. I. Müller, Synthesis of ZnAl2O4 nanoparticles by different routes and the effect of its pore size on the photocatalytic process, Microporous and Mesoporous Materials, 163, 29(2012)
2	R. Ianos, S. Borcanescu, R. Lazau,Large surface area ZnAl2O4 powders prepared by a modi?ed combustion technique, Chemical Engineering Journal, 240, 260(2014)
3	F. Davar, M. S. Niasari,Synthesis and characterization of spinel-type zinc aluminate nanoparticles by a modi?ed sol-gel method using new precursor, Journal of Alloys and Compounds, 509(5), 2487(2011)
4	WANG Shifa, YANG Hua, XIAN Tao, JIANG Jinlong, WEI Zhiqiang, FENG Youcai, LI Ruishan, FENG Wangjun, Preparation an characterization of YMnO3 nanoparticles, Journal of China Ceramics Society, 38(12), 2303(2010)
4	(王仕发, 杨华, 县涛, 姜金龙, 魏智强, 冯有才, 李瑞山, 冯旺军, YMnO3 纳米颗粒的制备与表征, 硅酸盐学报, 38(12), 2303(2010))
5	M. Ranjbar, M. S. Niasari, S. M. H. Mashkani,Microwave synthesis and characterization of spinel-type zinc aluminate nanoparticles, Journal of Inorganic Organometallic Polymers and Materials, 22(5), 1093(2012)
6	S. Kurajica, E. Tkalcec, J. Sipusic, G. Matijasic, I. Brnardic, I. Simcic,Synthesis and characterization of nanocrystalline zinc aluminate spinel by sol–gel technique using modi?ed alkoxide precursor, Journal of Sol-Gel Science and Technology, 46(2), 152(2008)
7	V. Ciupina, I. Carazeanu, G. Prodan,Characterization of ZnAl2O4 nanocrystals prepared by coprecipitation and microemulsion techiniques, Journal of Optoelectronics and Advanced Materials, 6(4), 1317(2004)
8	S. Farhadi, S. Panahandehjoo,Spinel-type zinc aluminate (ZnAl2O4) nanoparticles prepared by the co-precipitation method: A novel, green and recyclable heterogeneous catalyst for the acetylation of amines, alcohols and phenols under solvent-free conditions, Applied Catalysis A: General, 382(2), 293(2010)
9	Z. Z. Chen, E. W. Shi, Y. Q. Zheng, W. J. Li, N. C. Wu, W. Z. Zhong,Synthesis of mono-dispersed ZnAl2O4 powders under hydrothermal conditions, Materials Letters, 56(4), 601(2002)
10	X. Y. Chen, C. Ma, Z. J. Zhang, B. N. Wang,Ultra?ne gahnite (ZnAl2O4) nanocrystals: Hydrothermal synthesis and photoluminescent properties, Materials Science and Engineering B, 151(3), 224(2008)
11	C. Ragupathi, J. J. Vijaya, A. Manikandan, L. J. Kennedy,Phytosynthesis of nanoscale ZnAl2O4 by using Sesamum (Sesamum indicum L.) optical and catalytic properties, Journal of Nanoscience and Nanotechnology, 13(12), 8298(2013)
12	A. A. Da Silva, A. de Souza Goncalves, M. R. Davolos,Characterization of nanosized ZnAl2O4 spinel synthesized by the sol-gel method, Journal of Sol-Gel Science and Technology, 49(1), 101(2009)
13	WANG Yun,WANG Hong, SUN Guangai, CHEN Xiping, WANG Shifa, Prepared and photoluminescence of SnO2 nanoparticles, Chinese Journal of Materials Research, 28(6), 420(2014)
13	(王云, 王虹, 孙光爱, 陈喜平, 王仕发, SnO2纳米颗粒的制备及其发光性能, 材料研究学报, 28(6), 420(2014))
14	S. F. Wang, H. Yang, T. Xian, X. Q. Liu,Size-controlled synthesis and photocatalytic properties of YMnO3 nanoparticles, Catalysis Communications, 12(7), 625(2011)
15	S. F. Wang, C. F. Zhang, G. A. Sun, B. Chen, W. Liu, X. Xiang, H. Wang, L. M. Fang, Q. Tian, Q. P. Ding, X. T. Zu,Effect of carbon and sintering temperature on the structural and magnetic properties of SrFe12O19 nanoparticles, Journal of Sol-Gel Science and Technology, 73(2), 371(2015)
16	S. F. Wang, H. B. Lv, X. S. Zhou, Y. Q. Fu, X. T. Zu,Magnetic nanocomposites through polyacrylamide gel route, Nanoscience and Nanotechnology Letters, 6(9), 758(2014)
17	WEI Zhiqiang,XIA Tiandong, WANG Jun, WU Zhiguo, YAN Pengxun, Lattice expansion of Ni nanopowders, Acta Physica Sinica, 56(2), 1004(2007)
17	(魏智强, 夏天东, 王君, 吴志国, 闫鹏勋, 纳米镍粉体的晶格膨胀, 物理学报, 56(2), 1004(2007))
18	WANG Weipeng, YANG Hua, XIAN Tao, WEI Zhiqiang, LI Ruishan, FENG Wangjun, Polyacrylamide gel synthesis, characterization and magnetic properties of CoFe2O4 nanopowders, Chinese Journal of Inorganic Chemistry, 27(6), 1071(2011)
18	(王伟鹏, 杨华, 县涛, 魏智强, 李瑞山, 冯旺军, CoFe2O4纳米粉体的聚丙烯酰胺凝胶法合成、表征及磁特性, 无机化学学报, 27(6), 1071(2011))
19	YANG Hua,LIN Guanjun, XIAN Tao, WEI Zhiqiang, FENG Wangjun, Influence of chelating agents and crosslinking on TbMnO3 nanoparticles prepared by a gel route, Nanotechnology and Precision Engineering, 10(1), 46(2012)
19	(杨华, 林贯军, 县涛, 魏智强, 冯旺军, 络合剂和交联剂对凝胶法制备 TbMnO3 纳米颗粒的影响, 纳米技术与精密工程, 10(1), 46(2012))
20	XIAN Tao,YANG Hua, DAI Jianfeng, WEI Zhiqiang, MA Jinyuan, FENG Wangjun, Preparation and photocatalytic performance of nano-bismuth ferrite with tunable size, Chinese Journal of Catalysis, 32(4), 618(2011)
20	(县涛, 杨华, 戴剑锋, 魏智强, 马金元, 冯旺军, 粒径可控的纳米铁酸铋的制备及其光催化性能, 催化学报, 32(4), 618(2011))
21	WANG Zhiyong,PENG Chaoqun, WANG Richu, WANG Xiaofeng, LIU Bing, Influence of calcining process on optical properties of Al-doped-ZnO powders, Journal of Inorganic Materials, 28(2), 171(2013)
21	(王志勇, 彭超群, 王日初, 王小锋, 刘兵, 煅烧工艺对氧化锌铝(AZO)粉体光学性能的影响, 无机材料学报, 28(2), 171(2013))
22	T. Xian, H. Yang, X. Shen, J. L. Jiang, Z. Q. Wei, W. J. Feng,Preparation of high-quality BiFeO3 nanopowders via a polyacrylamide gel route, Journal of Alloys and Compounds, 480(2), 889(2009)
23	X. Y. Song, S. H. Zheng, J. Zhang, W. Li, Q. Chen, B. Q. Cao,Synthesis of monodispersed ZnAl2O4 nanoparticles and their tribology properties as lubricant additives, Materials Research Bulletin, 47(12), 4305(2012)
24	R. Ianos, R. Lazau, I. Lazau, C. Pacurariu,Chemical oxidation of residual carbon from ZnAl2O4 powders prepared by combustion synthesis, Journal of the European Ceramic Society, 32(8), 1605(2012)
25	R. Khenata, M. Sahnoun, H. Baltache, M. Rerat, Ali H. Reshak, Y. Al-Douri, B. Bouhafs,Full- potential calculations of structural, elastic and electronic properties of MgAl2O4 and ZnAl2O4 compounds, Physics Letters A, 344(2-4), 271(2005)
26	S. F. Wang, C. F. Zhang, G. A. Sun, Y. G. Yuan, L. Chen, X. Xiang, Q. P. Ding, B. Chen, Z. J. Li, X. T. Zu,Self - assembling synthesis of α-Al2O3 - carbon composites and a method to increase their photoluminescence, Journal of Luminescence, 153, 393(2014)

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