阳极氧化对钛合金表面HA-TiO<sub>2</sub>复合涂层的影响*

doi:10.11901/1005.3093.2014.336

材料研究学报

2014, Vol. 28

Issue (12): 887-894 DOI: 10.11901/1005.3093.2014.336

本期目录 | 过刊浏览

阳极氧化对钛合金表面HA-TiO₂复合涂层的影响*

王朴¹,何代华^2,^**(

),刘平²,刘新宽²,赵君³,陈冰玉²

1. 上海理工大学机械工程学院上海 200093
2. 上海理工大学材料科学与工程学院上海 200093
3. 中国科学院特种无机涂层重点实验室上海 200050

Influence of Anodic Oxidation on Hydroxyapatite-TiO₂ Coating Deposited on Ti6Al4V Alloy

Pu WANG¹,Daihua HE^2,^**(

),Ping LIU²,Xinkuan LIU²,Jun ZHAO³,Bingyu CHEN²

1. School of Mechanical Engineering, University of Shanghai for Science and Technology, Shanghai 200093
2. School of Materials Science and Engineering, University of Shanghai for Science and Technology, Shanghai 200093
3. Key Laboratory of Inorganic Coating Materials, Chinese Academy of Sciences, Shanghai 200050

引用本文:

王朴,何代华,刘平,刘新宽,赵君,陈冰玉. 阳极氧化对钛合金表面HA-TiO₂复合涂层的影响*[J]. 材料研究学报, 2014, 28(12): 887-894.
Pu WANG, Daihua HE, Ping LIU, Xinkuan LIU, Jun ZHAO, Bingyu CHEN. Influence of Anodic Oxidation on Hydroxyapatite-TiO₂ Coating Deposited on Ti6Al4V Alloy[J]. Chinese Journal of Materials Research, 2014, 28(12): 887-894.

全文: PDF(3601 KB) HTML

摘要:

对钛合金表面进行阳极氧化预处理, 然后用水热电化学方法在其上沉积羟基磷灰石-二氧化钛(HA-TiO₂)复合涂层, 研究了阳极电压对基体表面的物相、形貌、润湿性和粗糙度的影响, 以及对HA的物相、形貌及生物活性的影响。结果表明: 阳极氧化电压高于110 V时在钛基体表面出现金红石型和锐钛矿型TiO₂, 孔径尺寸随阳极电压的增加而增大。在120 V预处理的钛合金试样表面具有好的润湿性, 粗糙度R_a达到0.56 μm。HA涂层沿c轴方向择优生长, 并呈现分层生长, HA的结晶度随着阳极氧化电压的提高先增大后减小, 在120 V取得最大值。在120 V氧化处理的试样具有较好的生物活性。

关键词 ：无机非金属材料, Ti6Al4V, 阳极氧化, 水热电化学, HA-TiO₂涂层

Abstract：

Ti6Al4V substrate was pretreated by anodic oxidation and then hydroxyapatite coatings were deposited on the oxidized titanium surface by hydrothermal-electrochemical method. The effect of oxidation voltage on the phase composition, surface morphology, wettability and roughness of anodic films, as well as on the phase composition, micro-morphology and bioactivity of HA coatings were investigated. The results show that: after anodic oxidation the titanium alloy is covered by TiO₂ porous oxide film consisted of rutile and anatase when the voltage is higher than 110 V. The pore size of the titania layer increases with the increase of the anodic voltage and the alloy after anodic oxidation by 120 V has good wettability and the roughness is about R_a=0.56 μm. The HA coatings formed by hydrothermal-electrochemical deposition exhibits a layered structure with a preferential orientation (002) for several of oxidation voltage. The crystallinity of HA increases with anodic oxidation voltage up to 120 V and then decreases. The hydroxyapatite-TiO₂ coating deposited on the alloy which had been anodic-oxidized by 120 V has better bioactivity.

Key words： inorganic non-metallic materials Ti6Al4V anodic oxidation hydrothermal-electrochemical HA-TiO₂ coating

收稿日期: 2014-07-11

基金资助:* 中国科学院特种无机涂层重点实验室开放课题项目KLICM-2014-11和上海市自然科学基金15ZR1428300资助。

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https://www.cjmr.org/CN/10.11901/1005.3093.2014.336 或 https://www.cjmr.org/CN/Y2014/V28/I12/887

图1 钛合金在不同电压下阳极氧化10 min后的XRD图谱

图2 钛合金在不同电压下阳极氧化10 min的SEM像

图3 钛合金在不同电压下阳极氧化10 min后的粗糙度Ra变化趋势图

图4 钛合金在不同电压下氧化10 min后接触角变化趋势图

图5 钛合金在不同电压下阳极氧化后水热电化学沉积HA-TiO2的XRD物相分析

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