锌液中的Al含量对热冲压钢锌层组织的影响<sup>*</sup>

doi:10.11901/1005.3093.2013.548

材料研究学报

2014, Vol. 28

Issue (1): 23-30 DOI: 10.11901/1005.3093.2013.548

本期目录 | 过刊浏览

锌液中的Al含量对热冲压钢锌层组织的影响^*

杨洪林¹,张深根¹(

),洪继要²,刘昕²,李俊²,王华³

1. 北京科技大学材料科学与工程学院北京 100083
2. 宝钢集团中央研究院上海 201900
3. 上海大学材料科学与工程学院上海 200072

Effect of Al Content on the Microstructure of Hot-Depped Zinc Coating on Hot Stamping Steel

Honglin YANG¹,Shengen ZHANG^1,^**(

),Jiyao HONG²,Xin LIU²,Jun LI²,Hua WANG³

1. School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083
2. Central Research Institute of Baosteel, Shanghai, 201900
3. School of Materials Science and Engineering, Shanghai University, Shanghai 200072

引用本文:

杨洪林,张深根,洪继要,刘昕,李俊,王华. 锌液中的Al含量对热冲压钢锌层组织的影响^*[J]. 材料研究学报, 2014, 28(1): 23-30.
Honglin YANG, Shengen ZHANG, Jiyao HONG, Xin LIU, Jun LI, Hua WANG. Effect of Al Content on the Microstructure of Hot-Depped Zinc Coating on Hot Stamping Steel[J]. Chinese Journal of Materials Research, 2014, 28(1): 23-30.

全文: PDF(4265 KB) HTML

摘要:

采用热镀锌模拟实验装置在四种不同铝含量锌液中进行连续热镀锌实验, 分别制备出具有不同锌层组织的热冲压钢。用扫描电镜、能谱仪和辉光放电光谱仪等手段研究了锌液中不同铝含量对热冲压钢镀层组织形貌的影响。结果表明, 在不同铝含量的锌液中热冲压钢均具有良好的可镀性, 锌液中的铝含量对锌层/钢界面处的合金层组织、形貌、化学成分和锌层光亮性均有较大的影响。在光亮退火过程中钢板表面发生锰、硅等元素的富集及选择性氧化, 且Mn-Si氧化物与锌液中的铝发生氧化还原反应。锌液中的铝含量(质量分数, 下同)为0.11%时, 锌层/钢界面处形成了连续的ζ相; 当锌液中的铝含量为0.17%时, 锌层/钢界面处由Fe-Al相和ζ相组成; 当铝含量为0.25%时, 界面层主要为粗糙的Fe₂Al₅颗粒; 铝含量为0.43%时颗粒状的Fe₂Al₅相消失, 界面层变得光滑。同时, 随着锌液中铝含量的提高锌层的光亮性逐渐变差。

关键词 ：金属材料, 热冲压钢, 热镀锌, 抑制层, 选择氧化

Abstract：

Different galvanized coatings on hot stamping steel was obtained by using hot dip galvanizing simulation experiment device dipping in zinc baths with four different Al contents. The effect of Al content on the microstructure of galvanized was investigated using SEM/EDS and glow discharge optical emission spectrometer (GDOES).The results show that press-hardened steel has good reactive wetting in different Al content zinc bath. The Al content (mass fraction) in zinc bath has a significant influence on coating/steel interface composition, morphology and light property. Enrichment of Mn, Si elements occurred in the steel surface during bright annealing process, and the Mn-Si oxides react (redox reaction) with Al in zinc bath. For 0.11% dissolved Al bath, continuous ζ phases formed at the coating/steel interface. For 0.17% dissolved Al bath, the coating/steel interface consist of ζ phases and Fe-Al phases. A continuous Fe₂Al₅ inhibition layer achieved in baths with Al content 0.25% and 0.43%, and the morphology of interface layer became coarser when Al content in zinc bath was 0.25%. In addition, with the increase of Al content in zinc bath, the light property of zinc coatings gradually became worse.

Key words： metallic materials press-hardened steel galvanizing inhibition layer selective oxidation

收稿日期: 2013-07-30

基金资助:* 国家九七三计划2012CB723904 资助项目。

	服务

	把本文推荐给朋友
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	杨洪林
	张深根
	洪继要
	刘昕
	李俊
	王华
44.8K

链接本文:

https://www.cjmr.org/CN/10.11901/1005.3093.2013.548 或 https://www.cjmr.org/CN/Y2014/V28/I1/23

图1 试样的退火曲线

图2 退火后的钢板表面扫描照片及氧化物的EDS分析(质量分数)

图3 退火后钢板表面元素的GDOES深度分析（800℃/60 s, DP: -30℃, N2+5%H2）

图4 不同铝含量锌层的表面对比

图5 不同锌层表面处的铝元素分布

图6 不同铝含量钢/镀层界面处的SEM像

表1 图6中各点的EDS分析

图7 不同铝含量锌层的背散射照片

图8 不同铝含量镀层中各元素的GDOES深度分析

图9 铝含量对界面层形貌的影响

1	H. Karbasian, A.E. Tekkaya,A review on hot stamping, Journal of Materials Processing Technology, 210(15), 2103(2010)
2	K. Steinhoff, N. Barbakedze, M. Schupfer, Press hardening-form galvanized UHSS to body-in-white application, Galvatech 2011, Federica Bassani(Genova, AIM, 2011) p.IL12
3	P. Chen, M. Ko?,Simulation of springback variation in forming of advanced high strength steels, Journal of Materials Processing Technology, 190(1-3), 189(2007)
4	A. Bardelcik, C. P. Salisbury, S. Winkler, M. A. Wells, M. J. Worswick,Effect of cooling rate on the high strain rate properties of boron steel, International Journal of Impact Engineering, 37(6), 694(2010)
5	P. Hu, L. Ying, Y. Li, Z. Liao,Effect of oxide scale on temperature-dependent interfacial heat transfer in hot stamping process, Journal of Materials Processing Technology, 213(9), 1475(2013)
6	K. Mori, D. Ito,Prevention of oxidation in hot stamping of quenchable steel sheet by oxidation preventive oil, CIRP Annals-Manufacturing Technology, 58(1), 267(2009)
7	J. Kondratiuk, P. Kuhn, M. Kōyer, M. Meurer, A new coating solution for hot press forming, Galvatech 2011, Federica Bassani(Genova, AIM, 2011) p.182
8	J. Faderl, S. Kolnberger, M. Rosner, T. Kurz, Continuous galvanizing meets press-hardening, Galvatech 2011, Federica Bassani(Genova, AIM, 2011) p.161
9	D. W. Fan, H. S. Kim, J. Oh, K. Chin, B. C. de Cooman, Coating degradation in hot press forming, ISIJ International, 4(50), 2010
10	D. W. Fan, B. C. De Cooman,State-of-the-knowledge on coating systems for hot stamped parts, Steel Research International, 83(5), 412(2012)
11	YANG Honglin,LIU Xin, LI Jun, ZHANG Shengen, WANG Hua, Research status on hot stamping steel coating, Journal of Iron and Steel Research, 25(6), 1(2013)
11	(杨洪林, 刘昕, 李俊, 张深根, 王华, 热冲压钢镀层技术的研究现状, 钢铁研究学报, 25(6), 1(2013))
12	A. R. Marder,The metallurgy of zinc-coated steel, Progress in Materials Science, 45(3), 191(2000)
13	E. Baril, G. L Espérance,Studies of the morphology of the Al-rich interfacial layer formed during the hot dip galvanizing of steel sheet, Metallurgical and Materials Transactions A, 30(3), 681(1999)
14	E. M. Bellhouse, J. R. McDermid,Selective oxidation and reactive wetting during hot-dip galvanizing of a 1.0 pct Al-0.5 pct Si TRIP-assisted steel, Metallurgical and Materials Transactions A, 43(7), 2426(2012)
15	M. Blumenau, M. Norden, F. Friedel, K. Peters,Reactive wetting during hot-dip galvanizing of high manganese alloyed steel, Surface and Coatings Technology, 205(10), 3319(2011)
16	S. Alibeigi, R. Kavitha, R.J. Meguerian, J.R. McDermid,Reactive wetting of high Mn steels during continuous hot-dip galvanizing, Acta Materialia, 59, 3537(2011)
17	E. M. Bellhouse, J. R. McDermid,Selective oxidation and reactive wetting of 1.0 Pct Si-0.5 Pct Al and 1.5 Pct Si TRIP-assisted steels, Metallurgical and Materials Transactions A, 41(6), 1539(2010)
18	N. Gao, D. Y. H Liu, N. Y. Tang, Optimizing batch Al level for improved galvanizability of advanced high strength steels, Galvatech 2011, Federica Bassani(Genova, AIM, 2011)p. 2
19	E. M. Bellhouse, J. R. McDermid,Analysis of the Fe-Zn interface of galvanized high Al-low Si TRIP steels, Materials Science and Engineering A, 491(1-2), 39(2008)
20	S. Prabhudev, S. Swaminathan, M. Rohwerder,Effect of oxides on the reaction kinetics during hot-dip galvanizing of high strength steels, Corrosion Science, 53(7), 2413(2011)
21	G. M. Song, T. Vystavel, N. van der Pers, J. T. M. De Hosson, W.G. Sloof,Relation between microstructure and adhesion of hot dip galvanized zinc coatings on dual phase steel, Acta Materialia, 60, 2937(2012)
22	K. Lin, P. Chu, C. Lin, H. Chen,Galvanizing and galvannealing behavior of CMnSiCr dual-phase steels, Metallurgical and Materials Transactions A, 1(2013)
23	Kim M.S, Kim Y. H, Lee J. Y, Kim J.S, Effect of aluminium on galvanizability of TRIP assisted steels, Galvatech 2011, Federica Bassani(Genova, AIM, 2011) p. 107
24	P. Drillet, Z. Zermout, D. Bouleau, J. M. Mataigne,Selective oxidation of IFTi stabilized steels during recrystallization annealing, and steel/Zn reactivity, Galvatech 2001, P. Carlsson ( Brussel, Belgium, 2001) p.195
25	M. F. Guimon, G. Pfister-Guillouzo, M. Bremont, W. Brockmann, C. Quet, J.Y. Chenard,Application of X-ray photoelectron spectroscopy to the study of degradation mechanisms of epoxy-bonded joints of zinc coated steel, Applied Surface Science, 108(1), 149(1997)
26	S. Feliu Jr., V. Barranco,XPS study of the surface chemistry of conventional hot-dip galvanised pure Zn, galvanneal and Zn-Al alloy coatings on steel, Acta Materialia, 51, 5413(2003)
27	R. Khondker, A. Mertens, J.R. McDermid,Effect of annealing atmosphere on the galvanizing behavior of a dual-phase steel, Materials Science and Engineering A, 463(1-2), 157(2007)
28	N. Y. Tang,Modeling Al enrichment in galvanized coatings, Metallurgical and Materials Transactions A, 26(7), 1699(1995)
29	M. Dutta, S. B. Singh,Effect of strip temperature on the formation of an Fe2Al5 inhibition layer during hot-dip galvanizing, Scripta Materialia, 60(8), 643(2009)

[1]	毛建军, 富童, 潘虎成, 滕常青, 张伟, 谢东升, 吴璐. AlNbMoZrB系难熔高熵合金的Kr离子辐照损伤行为[J]. 材料研究学报, 2023, 37(9): 641-648.
[2]	宋莉芳, 闫佳豪, 张佃康, 薛程, 夏慧芸, 牛艳辉. 碱金属掺杂MIL125的CO₂ 吸附性能[J]. 材料研究学报, 2023, 37(9): 649-654.
[3]	赵政翔, 廖露海, 徐芳泓, 张威, 李静媛. 超级奥氏体不锈钢24Cr-22Ni-7Mo-0.4N的热变形行为及其组织演变[J]. 材料研究学报, 2023, 37(9): 655-667.
[4]	邵鸿媚, 崔勇, 徐文迪, 张伟, 申晓毅, 翟玉春. 空心球形AlOOH的无模板水热制备和吸附性能[J]. 材料研究学报, 2023, 37(9): 675-684.
[5]	幸定琴, 涂坚, 罗森, 周志明. C含量对VCoNi中熵合金微观组织和性能的影响[J]. 材料研究学报, 2023, 37(9): 685-696.
[6]	欧阳康昕, 周达, 杨宇帆, 张磊. 含LPSO相Mg-Y-Er-Ni合金的组织和拉伸性能[J]. 材料研究学报, 2023, 37(9): 697-705.
[7]	徐利君, 郑策, 冯小辉, 黄秋燕, 李应举, 杨院生. 定向再结晶对热轧态Cu71Al18Mn11合金的组织和超弹性性能的影响[J]. 材料研究学报, 2023, 37(8): 571-580.
[8]	熊诗琪, 刘恩泽, 谭政, 宁礼奎, 佟健, 郑志, 李海英. 固溶处理对一种低偏析高温合金组织的影响[J]. 材料研究学报, 2023, 37(8): 603-613.
[9]	刘继浩, 迟宏宵, 武会宾, 马党参, 周健, 徐辉霞. 喷射成形M3高速钢热处理过程中组织的演变和硬度偏低问题[J]. 材料研究学报, 2023, 37(8): 625-632.
[10]	由宝栋, 朱明伟, 杨鹏举, 何杰. 合金相分离制备多孔金属材料的研究进展[J]. 材料研究学报, 2023, 37(8): 561-570.
[11]	任富彦, 欧阳二明. g-C₃N₄ 改性Bi₂O₃ 对盐酸四环素的光催化降解[J]. 材料研究学报, 2023, 37(8): 633-640.
[12]	王昊, 崔君军, 赵明久. 镍基高温合金GH3536带箔材的再结晶与晶粒长大行为[J]. 材料研究学报, 2023, 37(7): 535-542.
[13]	刘明珠, 樊娆, 张萧宇, 马泽元, 梁城洋, 曹颖, 耿仕通, 李玲. SnO₂ 作散射层的光阳极膜厚对量子点染料敏化太阳能电池光电性能的影响[J]. 材料研究学报, 2023, 37(7): 554-560.
[14]	秦鹤勇, 李振团, 赵光普, 张文云, 张晓敏. 固溶温度对GH4742合金力学性能及γ' 相的影响[J]. 材料研究学报, 2023, 37(7): 502-510.
[15]	刘天福, 张滨, 张均锋, 徐强, 宋竹满, 张广平. 缺口应力集中系数对TC4 ELI合金低周疲劳性能的影响[J]. 材料研究学报, 2023, 37(7): 511-522.

Viewed

Full text

Abstract

Cited

Shared

Discussed