Temperature Dependent Luminescence Properties of Graphene Oxide

doi:10.11901/1005.3093.2021.469

Chinese Journal of Materials Research

2022, Vol. 36

Issue (8): 597-601 DOI: 10.11901/1005.3093.2021.469

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Temperature Dependent Luminescence Properties of Graphene Oxide

LI Fulu¹, HAN Chunmiao¹, GAO Jiawang¹, JIANG Jian¹, XU Hui², LI Bing¹(

)

^1.College of Physics, Changchun Normal University, Changchun 130032, China
^2.Department of Ophthalmology, the First Hospital of Jilin University, Changchun 130021, China

Cite this article:

LI Fulu, HAN Chunmiao, GAO Jiawang, JIANG Jian, XU Hui, LI Bing. Temperature Dependent Luminescence Properties of Graphene Oxide. Chinese Journal of Materials Research, 2022, 36(8): 597-601.

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Abstract

The luminescence properties of GO were investigated by means of photoluminescence spectra and absorption spectra. It follows that the luminescence of GO originates from sp²C clusters in lamellar. Sp²C clusters are surrounded by high barrier oxidation functional groups (sp³C), forming a multi-quantum well structure. There are sp²C clusters of different sizes in GO, and the band gap is related to the size. The smaller the size, the wider the band gap, so that the luminous coverage is wider and depends on the excitation wavelength. The emission behavior of different local states in GO was investigated by changing the excitation wavelength and temperature. The results show that the thermal activation energy of sp²C clusters excited by 514 nm was 56 MeV higher than that excited by 830 nm. Temperature has little effect on smaller sp²C clusters, because the smaller the size, the stronger the confinement effect and the radiative transition probability of electron hole pair is increased.

Key words: inorganic non-metallic materials low dimensional carbon materials graphene oxide luminescence spectrum

Received: 17 August 2021

ZTFLH:

O613.7

Fund: National Natural Science Foundation of China(11404036);Jilin Provincial Science & Technology Department(20210101164JC);Science and Technology Project of Jilin Provincial Department of Education(JJKH20220824KJ);Natural Science Foundation of Changchun Normal University(2020-010)

About author: LI Bing, Tel: 13080016697, E-mail: libing@ccsfu.edu.cn

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	Fulu LI
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	Jiawang GAO
	Jian JIANG
	Hui XU
	Bing LI

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https://www.cjmr.org/EN/10.11901/1005.3093.2021.469 OR https://www.cjmr.org/EN/Y2022/V36/I8/597

Fig.1 UV-Vis absorption spectra of GO (a) and corresponding Tauc plot (b)

Fig.2 PL spectra of GO for excitation at E_ex =488 nm, E_ex =514 nm and E_ex =830 nm (a) and the dependences as the function of excitation wavelengths: (left) peak wavelength and (right) FWHM of PL spectra (b)

Fig.3 Schematic diagram of band structure of GO

Fig.4 Temperature dependence of the relative PL intensity of GO at two different exciting conditions: (a) E_ex =514 nm; (b) E_ex =830 nm

Fig.5 Relationship between relative PL intensity and 1/K_BT, exciting at E_ex =514 nm (a) and E_ex =830 nm (b)

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