Effect of Preparing Methods on Structure and Properties of Phosphate Glass-ceramics

doi:10.11901/1005.3093.2023.087

Chinese Journal of Materials Research

2023, Vol. 37

Issue (10): 739-746 DOI: 10.11901/1005.3093.2023.087

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Effect of Preparing Methods on Structure and Properties of Phosphate Glass-ceramics

ZHOU Yi¹(

), TU Qiang², MI Zhonghua³

^1.School of Materials Science and Engineering, Taiyuan University of Science and Technology, Taiyuan 030024, China
^2.Shanghai Nuclear Engineering Research and Design Institute Co. Ltd., Shanghai 200233, China
^3.Taiyuan Branch of CSIC Electrical Machinery Scienceand Technology Co. Ltd., Taiyuan 030027, China

Cite this article:

ZHOU Yi, TU Qiang, MI Zhonghua. Effect of Preparing Methods on Structure and Properties of Phosphate Glass-ceramics. Chinese Journal of Materials Research, 2023, 37(10): 739-746.

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Abstract

Gass-ceramics can be well used for making energy storage capacitors because of their unique structure of crystalline particles uniformly distributed in the glass matrix. Compared with conventional silicon glass-based glass-ceramics, phosphate glass-ceramics have significant advantage of less energy consumption. In this study, glass-ceramics of P₂O₅-Nb₂O₅-BaO-Na₂O-CeO₂ were prepared by melting and sintering respectively. The structure of the prepared phosphate glass-ceramics was characterized through XRD and SEM. The effect of preparation method on the structure and properties of the phosphate glass-ceramics were systematically studied in terms of the bulk density, microhardness, dielectric properties, polarization performance and energy storage etc. The results showed that the more compact glass-ceramics could be obtained by the melting method, which could improve the bulk density and micro-hardness of the glass-ceramics, the corresponding dielectric loss was reduced. In addition, when the addition of CeO₂ was increased to 1% (mole fraction), the phosphate glass-ceramics obtained by the two methods were also achieved good densification. The addition of CeO₂ played a role in promoting crystallization, which enhanced the dielectric constant and polarization performance. The released energy density of 13.5 mJ/cm³ and energy storage efficiency of 50.1% were obtained for the glass-ceramic with addition of 1% CeO₂ (mole fraction) prepared by melting method.

Key words: inorganic non-metallic materials glass-ceramics preparing method mechanical properties dielectric properties P-E hysteresis loops energy storage characteristics

Received: 05 January 2023

ZTFLH:

TQ110.1

Fund: National Natural Science Foundation of China(51902221);University-enterprise Technology Tra-nsfer Project(C2022007)

Corresponding Authors: ZHOU Yi, Tel: 18335130685, E-mail: zhouyi@tyust.edu.cn

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Fig.1 XRD plots of the phosphate glass-ceramics made by melting method (a) and sintering method (b)

Fig.2 SEM graphs of the phosphate glass-ceramics made by melting method with CeO₂ addition of 0 (A), 0.5% (B), 1% (C), 1.5% (D), and by sintering method with CeO₂ addition of 0 (a), 0.5% (b), 1% (c), 1.5% (d). % represents mole fraction

Fig.3 Bulk density, micro-Vickers hardness and Knoop hardness of the phosphate glass-ceramics made by melting method (a) and sintering method (b)

Fig.4 Frequency dependent curves of the dielectric constant and dielectric loss of the phosphate glass-ceramics made by melting method (a) and sintering method (b)

Fig.5 P-E hysteresis loops, discharged energy density, energy efficiency of the phosphate glass-ceramics made by melting method (A~C) and sintering method (a~c)

Table 1 Electric property of glass-ceramics

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