Preparation of SnO2@Ti3C2Tx and Its Application in Lithium Ion Battery as Anode Material

doi:10.11901/1005.3093.2021.443

Chinese Journal of Materials Research

2022, Vol. 36

Issue (8): 602-608 DOI: 10.11901/1005.3093.2021.443

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Preparation of SnO₂@Ti₃C₂T_x and Its Application in Lithium Ion Battery as Anode Material

LI Lingfang¹(

), YUAN Zhipeng², FAN Changling²

^1.College of Mechanical Engineering, Hunan University of Arts and Science, Changde 415000, China
^2.College of Materials Science and Engineering, Hunan University, Changsha 410082, China

Cite this article:

LI Lingfang, YUAN Zhipeng, FAN Changling. Preparation of SnO₂@Ti₃C₂T_x and Its Application in Lithium Ion Battery as Anode Material. Chinese Journal of Materials Research, 2022, 36(8): 602-608.

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Abstract

SnO₂ nanopoints were in-situ grown on and between Ti₃C₂T_x layers, and the nanostructured SnO₂@Ti₃C₂T_x composites were prepared by ultrasonic adsorption and low temperature heat treatment. SnO₂@Ti₃C₂T_x composites were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and high resolution transmission electron microscopy (HRTEM). Results show that SnO₂ nanoparticles are densely distributed between the layers of Ti₃C₂T_x. Ti₃C₂T_xowns outstanding limiting effect and graphite-like structure, it inhibits the volume expansion and agglomeration of SnO₂ and accelerates the transition of lithium ions and electrons. In addition, SnO₂ is embedded between the layers to improve the longitudinal structural stability of Ti₃C₂T_x by preventing the restacking. Therefore, SnO₂@Ti₃C₂T_x shows a synergistic effect between the two components and has good rate and cycle performance as anode of LIBs.

Key words: composite SnO₂/Ti₃C₂T_x ultrasound-aided anode material

Received: 13 August 2021

ZTFLH:

TM912.9

Fund: National Natural Science Foundation of China(51802096);Natural Science Foundation of Hunan Province(2020JJ4449);Key Project of Hunan Provincial Education Department(20A346)

About author: LI Lingfang, Tel: 13875010806, E-mail: yourvicky@126.com

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https://www.cjmr.org/EN/10.11901/1005.3093.2021.443 OR https://www.cjmr.org/EN/Y2022/V36/I8/602

Fig.1 SEM (a, b) and TEM (c, d) images of Ti₃C₂T_x

Fig.2 SEM (a, b) and TEM (c) images of ultra-Sn-MX, SEM images of Sn-MX (d, e)

Fig.3 Composition analysis of samples (a) XRD patterns; (b) XPS patterns of ultra-Sn-MX

Fig.4 Electrochemical performances of sampels (a) rate performance; (b) charge and discharge curves and (c) cycle performance

Fig.5 CV curves of Ti₃C₂T_x (a) and ultra-Sn-MX (b), including first three cycles and after 100 cycles and EIS patterns of three samples (c)

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