Preparation of Phosphorus-containing Graphene and Corrosion Resistance of Composite Coating

doi:10.11901/1005.3093.2021.556

Chinese Journal of Materials Research

2022, Vol. 36

Issue (12): 933-944 DOI: 10.11901/1005.3093.2021.556

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Preparation of Phosphorus-containing Graphene and Corrosion Resistance of Composite Coating

LI Yufeng¹^,²(

), ZHANG Nianfei¹, LIU Lishuang¹, ZHAO Tiantian¹, GAO Wenbo¹, GAO Xiaohui¹

^1.College of Chemistry and Chemical Engineering, Qiqihar University, Qiqihar 161006, China
^2.College of Light Industry and Textile, Qiqihar University, Qiqihar 161006, China

Cite this article:

LI Yufeng, ZHANG Nianfei, LIU Lishuang, ZHAO Tiantian, GAO Wenbo, GAO Xiaohui. Preparation of Phosphorus-containing Graphene and Corrosion Resistance of Composite Coating. Chinese Journal of Materials Research, 2022, 36(12): 933-944.

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Abstract

The phosphorus-containing graphene (PhA-G) was prepared by pyrolysis method with phytic acid (PhA) as raw material, and next the PhA-G/SiR composite anticorrosion coating was prepared with silicone resin (SiR) as film forming material. The structure and morphology of phosphorus-containing graphene was characterized by means of Raman spectroscope, X-ray photoelectron spectroscope (XPS), scanning electron microscope (SEM), transmission electron microscope (TEM) and atomic force microscope (AFM). The prepared coatings with the different additive amount of PhA-G (1%~4% in mass fraction), were comparatively examined by means of measurements of contact angle, water absorption, potentiodynamic polarization curves, electrochemical impedance spectroscopy (EIS), as well as salt spray test. The results show that the protectiveness of PhA-G/SiR composite coatings for metal substrate is greater than that of the plain SiR coating, and graphene oxide/silicone resin (GO/SiR) coating. The PhA-G/SiR composite coating exhibits good hydrophobicity and excellent corrosion resistance when the mass fraction of PhA-G is 3%. Correspondingly, which exhibits hydrophobic contact angle of 103.5° and water absorption rate of 3.72%, while corrosion current density of 3.53×10^-10 A/cm²and electrochemical impedance as high as 3.82×10⁷ Ω·cm² in 3.5%(mass fraction) NaCl solution. Furthermore, the PhA-G/SiR composite coating presents excellent resistance to salt spray testing, up to above 960 h.

Key words: materials failure and protection corrosion resistance phosphorus-containing graphene silicone resin composite coating

Received: 26 September 2021

ZTFLH:

TB304

Fund: the Fundamental Research Funds in Heilongjiang Provincial Universities(135509128)

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	Yufeng LI
	Nianfei ZHANG
	Lishuang LIU
	Tiantian ZHAO
	Wenbo GAO
	Xiaohui GAO

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https://www.cjmr.org/EN/10.11901/1005.3093.2021.556 OR https://www.cjmr.org/EN/Y2022/V36/I12/933

Fig.1 Raman spectra of GO and PhA-G

Fig.2 XPS spectra of GO and PhA-G

Fig.3 SEM images of GO (a, b) and PhA-G (c, d)

Fig.4 TEM images of GO (a, b) and PhA-G (c, d)

Fig.5 AFM image (a) and thickness analysis results of PhA-G sample (b)

Fig.6 Surface morphologies of PhA-G/SiR composite coatings containing different mass fractions of PhA-G: (a) 1%, (b) 2%, (c) 3%, (d) 4%

Fig.7 Effects of the content of PhA-G on the contact angle and water absorption of the composite coating

Fig.8 Nyquist and Bode plots of SiR coating, GO/SiR coating and four PhA-G/SiR coatings after immersion in 3.5% NaCl solution for (a, b) 0 h, (c, d) 48 h, (e, f) 96 h, (g, h) 144 h, (i, j) 192 h

Fig.9 Potentiodynamic polarization curves of bare steel, SiR coating, GO/SiR coating and four PhA-G/SiR coatings

Table 1 Fitting data of polarization curves

Fig.10 Macro-photos of (a) SiR, (b) GO/SiR, (c) 1% PhA-G/SiR, (d) 2% PhA-G/SiR, (e) 3% PhA-G/SiR, (f) 4% PhA-G/SiR coatings after salt spray test for different time, and steel substrate after removing the corroded coatings

Fig.11 Microscope photos of the surfaces of steel substrates after salt spray test for 960 h and then removal of (a) SiR, (b) GO/SiR, (c) 1% PhA-G/SiR, (d) 2% PhA-G/SiR, (e) 3% PhA-G/SiR, (f) 4% PhA-G/SiR surface coatings

Fig.12 Schematic diagram of corrosion prevention mechanism of PhA-G/SiR composite coating

1	BERRY V. Impermeability of graphene and its applications [J]. Carbon, 2013, 62: 1 doi: 10.1016/j.carbon.2013.05.052
2	Qi K, Sun Y M, Duan H W, et al. A corrosion-protective coating based on a solution-processable polymer-grafted graphene oxide nanocomposite [J]. Corros. Sci., 2015, 98: 500 doi: 10.1016/j.corsci.2015.05.056
3	Wang N, Chen J S, Wang S W, et al. Application of aminated grap-hite oxide for waterborne anti-corrosion and fireproof coatings [J]. Chin. J. Mater. Res., 2018, 32(10): 721
	王娜, 陈俊声, 王树伟等. 氨基化氧化石墨烯在水性防腐防火一体化涂料中的应用 [J]. 材料研究学报, 2018, 32(10): 721
4	Palaniappan N, Cole I, Kuznetsov A E. Experimental and computational studies of graphene oxide covalently functionalized by octylamine: electrochemical stability, hydrogen evolution, and corrosion inhibition of the AZ13 Mg alloy in 3.5%NaCl [J]. RSC Adv., 2020, 10(19): 11426 doi: 10.1039/c9ra10702a pmid: 35495345
5	Wen S, Ma J. Synergistic effect of polyvinylpyrrolidone noncovalently modified graphene and epoxy resin in anticorrosion application [J]. High. Perform. Polym., 2020, 33(2): 146 doi: 10.1177/0954008320942293
6	Ning L, Wang D D, Wang L, et al. Interesting corrosion inhibition performance and mechanism of two silanes containing multiple phosphate group [J]. Silicon-Neth., 2019, 12(6): 1455
7	Hermas A A, Wahdan M H, Ahmed E M. Phosphate-doped polyaniline/Al₂O₃ nanocomposite coating for protection of stainless steel [J]. Anti-Corros. Method. M, 2020, 64(5): 491
8	Zhu K, Li J Y, Fei G Q. Anticorrosive performance of phosphorylated graphene oxide applied at waterborne epoxy coating [J]. China Adhes., 2018, 27(9): 501
	朱科, 李菁熠, 费贵强. 磷酸化氧化石墨烯对水性环氧涂料防腐增强作用研究 [J]. 中国胶粘剂, 2018, 27(9): 501
9	Huang H, Tian Y, Xie Y, et al. Modification of graphene oxide with acrylate phosphorus monomer via thiol-Michael addition click reaction to enhance the anti-corrosive performance of waterborne epoxy coating [J]. Prog. Org. Coat., 2020, 146: 105724
10	Ding J, Rahman O U, Peng W, et al. A novel hydroxyl epoxy phosp hate monomer enhancing the anticorrosive performance of waterborne Graphene/Epoxy coatings [J]. Appl. Surf. Sci., 2018, 427: 981 doi: 10.1016/j.apsusc.2017.08.224
11	Albero J, Vidal A, Migani A, et al. Phosphorus-doped graphene as a metal-free material for thermochemical water reforming at unusually mild conditions [J]. Acs. Sustain. Chem. Eng., 2019, 7(1): 838 doi: 10.1021/acssuschemeng.8b04462
12	Suleiman R, Estaitie M, Mizanurahman M. Hybrid organosiloxane coatings containing epoxide precursors for protecting mild steel against corrosion in a saline medium [J]. J. Appl. Polym. Sci., 2016, 133(38): 1
13	Zhang L, Shi Z, Hu W H, et al. Curing mechanism, heat resistance, and anticorrosion properties of a furan/methyl phenyl silicone coating [J]. Polym. Advan. Technol., 2018, 29(7): 1913 doi: 10.1002/pat.4300
14	Wu J X, Xu H, Zhang J. Raman spectroscopy of graphene [J]. Atca. Chim. Sin. 2014, 72(3): 301
	吴娟霞, 徐华, 张锦. 拉曼光谱在石墨烯结构表征中的应用 [J]. 化学学报, 2014, 72(3): 301 doi: 10.6023/A13090936
15	Wang C, Jia Y J, Liu Z C, et al. Preparation and characterization of phosphorus-doped graphene [J]. Ind. Catal., 2014, 22(7): 510
	王灿, 贾银娟, 刘志成等. 磷掺杂石墨烯的制备与表征 [J]. 工业催化, 2014, 22(7): 510
16	Yuan B H, Xing W Y, Hu Y X, et al. Boron/phosphorus doping for retarding the oxidation of reduced graphene oxide [J]. Carbon., 2016, 101: 152 doi: 10.1016/j.carbon.2016.01.080
17	Shen X Y, Li X D, Zhao F H, et al. Preparation and structure study of phosphorus-doped porous graphdiyne and its efficient lithium storage application [J]. 2D Mater., 2019, 6(3): 035020
18	Balaji S S, Ganesh P A, Moorthy M, et al. Efficient electrocatalytic activity for oxygen reduction reaction by phosphorus-doped graphene using supercritical fluid processing [J]. B. Mater. Sci., 2020, 43: 151 doi: 10.1007/s12034-020-02142-2
19	Yu Y, Zhang Q, Wu L, et al. Reaction mechanism of N-(4-hydroxyphenyl)ethanamide electrodegradation via phosphorus-graphene prepared from triphenylphosphine: Generation and destruction of the reactive species [J]. Chem. Eng. J., 2021, 403: 126322 doi: 10.1016/j.cej.2020.126322
20	Kong S, Hu W J, Li J S. Tribological properties of graphene in PAO base oil [J]. China Surf. Eng., 2019, 32(3): 162
	孔尚, 胡文敬, 李久盛. 石墨烯在PAO基础油中的摩擦学性能 [J]. 中国表面工程, 2019, 32(3): 162
21	Li Y, Xu Y, Wang S, et al. Preparation of graphene/polyaniline nanocomposite by in situ intercalation polymerization and their application in anti-corrosion coatings [J]. High Perform. Polym., 2019, 31(9-10): 1226 doi: 10.1177/0954008319839442
22	Pourhashem S, Vaezi M R, Rashidi A, et al. Distinctive roles of silane coupling agents on the corrosion inhibition performance of graphene oxide in epoxy coatings [J]. Prog. Org. Coat., 2017, 111: 47
23	Li Y F, Li J Y, Gao X H, et al. Synthesis of stabilized dispersion covalently-jointed SiO₂@polyaniline with core-shell structure and anticorrosion performance of its hydrophobic coating for Mg-Li alloy [J]. Appl. Surf. Sci., 2018, 462(1): 362 doi: 10.1016/j.apsusc.2018.08.118

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