Thermal Stability of TiC0.81N0.48 and TiC0.61N0.44O0.15 Coatings

Chinese Journal of Materials Research

2013, Vol. 27

Issue (3): 312-316 DOI:

Original Article

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Thermal Stability of TiC_0.81N_0.48 and TiC_0.61N_0.44O_0.15 Coatings

ZHU Lihui¹^** ZHANG Yumeng ¹ PENG Xiao¹ Peter Leicht ² LIU Yixiong ²

1. School of Materials Science and Engineering, Shanghai University, Shanghai 200072, China
2. Kennametal Inc., Latrobe, PA 15650, USA

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ZHU Lihui , ^**, ZHANG Yumeng , PENG Xiao , Peter Leicht , LIU Yixiong. Thermal Stability of TiC_0.81N_0.48 and TiC_0.61N_0.44O_0.15 Coatings. Chinese Journal of Materials Research, 2013, 27(3): 312-316.

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Abstract TiC_0.81N_0.48 coating and TiC_0.61N_0.44O_0.15 coating deposited by medium temperature chemical vapor deposition, were characterized by Vickers hardness tester, X-ray diffraction (XRD) and confocal Raman spectrometer, and the effect of microstructure transformation on the hardness was investigated. Results show that the hardness of TiC_0.81N_0.48 and TiC_0.61N_0.44O_0.15 coatings declines after annealing at 700 ℃ in vacuum, and then tends to be stable. At the beginning of the annealing, some C atoms escape from the lattice of TiCN, resulting in the formation of sp³C. As the annealing time prolongs, sp³C transforms to sp²C gradually. Thereafter the clustering of sp²C increases, the disorder degree decreases, and TiCN decomposes into TiC and TiN. The decrease of hardness is related with the release of residual stress due to the defect annihilation. Besides, the microstructure transformation especially the formation of sp³C and sp²C decreases the hardness of coatings. Compared with TiC_0.61N_0.44O_0.15, the microstructure transformation takes places earlier in TiC_0.81N_0.48 coating, which exhibits worse thermal stability.

Key words: materials failure and protection TiCN coatings thermal stability microstructure transformation hardness

Received: 11 March 2013

ZTFLH:

TG174

Fund: *Supported by Kennametal Inc.. Manuscript received March 11, 2013; in revised form April 18, 2013.

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https://www.cjmr.org/EN/ OR https://www.cjmr.org/EN/Y2013/V27/I3/312

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