Flame Retard Modification of Vinyl Ester Resin with Phosphorous Polymer Type Flame Retardant

doi:10.11901/1005.3093.2021.217

Chinese Journal of Materials Research

2021, Vol. 35

Issue (11): 843-849 DOI: 10.11901/1005.3093.2021.217

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Flame Retard Modification of Vinyl Ester Resin with Phosphorous Polymer Type Flame Retardant

XU Chunping¹^,², CHEN chunyue¹^,², ZHANG yonghang¹, Gong wei², BAN daming¹^,²(

)

^1.School of Chemistry and Materials Science, Guizhou Normal University, Guiyang 550001 China
^2.Guizhou Functional Polymer Materials Science and Technology Innovation Talent Team, Guiyang 550025, China

Cite this article:

XU Chunping, CHEN chunyue, ZHANG yonghang, Gong wei, BAN daming. Flame Retard Modification of Vinyl Ester Resin with Phosphorous Polymer Type Flame Retardant. Chinese Journal of Materials Research, 2021, 35(11): 843-849.

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Abstract

The flame retardant poly (p-methoxy phenoxy phosphate) -4,4 '-dihydroxy biphenyl ester (PMP) was prepared by reaction process with 4-methoxy phenol and phosphorus trichloride as raw materials and its structure was characterized by Fourier transform infrared spectroscopy (FTIR) and nuclear magnetic resonance (¹H-NMR,¹³C-NMR,³¹P-NMR). Its carbon residue after calcination was measured by X-ray photoelectron spectroscopy (XPS). Further, the composite of PMP/APP/VER was fabricated with vinyl ester resin (VER) as raw material and the compound of ammonium polyphosphate (APP) and flame retardant PMP as modifier. The flame retardancy and thermal stability of the prepared composite was investigated by means of thermogravimetric analysis (TGA), limiting oxygen index (LOI) and vertical combustion (UL-94). The results show that the PMP/APP/VER composite with 15% PMP/APP could be rated as grade V-1 corresponding to the UL-94 test. When the composite with 20% PMP/APP, its LOI value reached 25.0%, and carbon residue was 34.6% after calcined at 700℃, which was 3.72 times that of the bare VER. These results demonstrate that PMP/APP can significantly improve the flame retardant performance and thermal stability of VER matrix.

Key words: functional polymer material VER APP flame retardancy thermal stability

Received: 06 April 2021

ZTFLH:

O623.4

Fund: National Natural Science Foundation of China(51763005);Guizhou Science Project (No. Qian Kehe [2017]5726)

About author: BAN Daming, Tel: 13984374705, E-mail: bdaming@gznu.edu.cn

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	Chunping XU
	chunyue CHEN
	yonghang ZHANG
	wei Gong
	daming BAN

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https://www.cjmr.org/EN/10.11901/1005.3093.2021.217 OR https://www.cjmr.org/EN/Y2021/V35/I11/843

Table 1 Formulation, LOI and UL-94 of PMP/VER and PMP/APP/VER composites

Fig.1 FT-IR spectra of MPC and PMP

Fig.2 ¹H-NMR (a), ³¹P NMR (b) and ¹³C NMR (c) spectra of PMP

Fig.3 XPS spectra of the char residue of PMP after combustion

Table 2 Thermal degradation behavior of VER、PMP/VER and PMP/APP/VER composites

Fig.4 TGA and DTG cures of pure VER, PMP/APP/VER and PMP/VER composites

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