Preparation and High Temperature Oxidation Resistance of Si Modified Aluminide Coating on Titanium Alloy

doi:10.11901/1005.3093.2024.052

Chinese Journal of Materials Research

2024, Vol. 38

Issue (12): 881-892 DOI: 10.11901/1005.3093.2024.052

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Preparation and High Temperature Oxidation Resistance of Si Modified Aluminide Coating on Titanium Alloy

LIU Guoqiang¹, FENG Changjie¹, XIN Li²(

), MA Tianyu³, CHANG Hao², PAN Yuxuan², ZHU Shenglong²

1 School of Materials Science & Engineering, Shenyang Aerospace University, Shenyang 110136, China
2 Shi -Changxu Innovation Center for Advanced Materials, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
3 School of Materials Science &Engineering, Northeastern University, Shenyang 110819, China

Cite this article:

LIU Guoqiang, FENG Changjie, XIN Li, MA Tianyu, CHANG Hao, PAN Yuxuan, ZHU Shenglong. Preparation and High Temperature Oxidation Resistance of Si Modified Aluminide Coating on Titanium Alloy. Chinese Journal of Materials Research, 2024, 38(12): 881-892.

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Abstract

Al-Si coatings with different Si content were deposited on the surface of Ti-alloy Ti-6Al-4V by multi-arc ion plating, then which were subjected to vacuum heat treatment at 900^oC for 1 h and thereby Si-modified aluminide coatings with gradually decreasing Al-content along the normal of coating inwards were acquired The aluminide coatings exhibited layered structure and were mainly composed of Ti-Al intermetallics including TiAl₃, TiAl₂, TiAl and precipitates including Ti₅Si₃ and Ti₅Si₄, and certain amount of Si atoms were dissolved in the TiAl₃ as substitutes and formed Ti(Al, Si)₃. The Si modified aluminide coatings showed excellent cyclic oxidation resistance at 650^oC. It is worthy to note that at 750^oC, the cyclic oxidation resistance of the aluminide coatings increased with the increasing of Si content.

Key words: metallic materials Si modified aluminide coating titanium alloy high temperature oxidation diffusion

Received: 22 January 2024

ZTFLH:

TG156

Fund: National Natural Science Foundation of China(52371085);Liaoning Revitalization Talents Program(XLYC2002031)

Corresponding Authors: XIN Li, Tel: 13664116162, E-mail: xli@imr.ac.cn

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	LIU Guoqiang
	FENG Changjie
	XIN Li
	MA Tianyu
	CHANG Hao
	PAN Yuxuan
	ZHU Shenglong

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https://www.cjmr.org/EN/10.11901/1005.3093.2024.052 OR https://www.cjmr.org/EN/Y2024/V38/I12/881

Fig.1 XRD patterns of 0Si, 5.2Si, 12.5Si and 25.7Si coatings

Fig.2 SEM surface and cross-sectional morphologies and EDS cross-sectional elemental maps of 0Si, 5.2Si, 12.5Si and 25.7Si coatings (a) 0Si, (b) 5.2Si, (c) 12.5Si, (d) 25.7Si

Table 1 Compositions of the areas marked by 1~19 in Fig.2 determined by EDS (atomic fraction, %)

Table 2 Standard Gibbs free energy changes of the reactions possibly took place during annealing at 900^oC (ΔG^θ )

Fig.3 Cyclic oxidation kinetic curves of TC4 alloy, 0Si, 5.2Si, 12.5Si, and 25.7Si coatings at 650^oC

Fig.4 Pictures of the samples after cyclic oxidation at 650^oC (a) TC4 for100 cycles; (b) 0Si, (c) 5.2Si, (d) 12.5Si and (e) 25.7Si coatings for 300 cycles

Fig.5 XRD patterns of 0Si, 5.2Si, 12.5Si and 25.7Si coat-ings after cyclic oxidation at 650^oC for 300 cycles

Fig.6 SEM surface and cross-sectional morphologies of the coatings after oxidation at 650^oC for 300 cycles (a) 0Si, (b) 5.2Si, (c) 12.5Si, (d) 25.7Si

Table 3 Composition of surface oxide scale of 0Si, 5.2Si, 12.5Si and 25.7Si coating after cyclic oxidation at 650^oC for 300 cycles by EDS (atomic fraction, %)

Fig.7 Cyclic oxidation kinetic curves of TC4 alloy, 0Si, 5.2Si, 12.5Si, and 25.7Si coatings at 750^oC

Fig.8 Pictures of the samples after cyclic oxidation at 750℃ (a) TC4 for 80 cycles; (b) 0Si and (c) 5.2Si coatings for180 cycles; (d) 12.5Si and (e) 25.7Si coatings for 300 cycles

Fig.9 XRD patterns of 0Si, 5.2Si, 12.5Si and 25.7Si coatings after oxidation at 750^oC for different time (a) 10°~90°, (b) 15°~34°

Fig.10 Surface and cross-sectional morphologies of the coatings after cyclic oxidation at 750^oC (a) 0Si and (b) 5.2Si for 180 cycles; (c) 12.5Si and (d) 25.7Si for 300 cycles (IDZ—inter diffusion zone)

Fig.11 EPMA cross-sectional elemental maps of the coatings after oxidation at 750^oC for 300 cycles (a) 12.5Si, (b) 25.7Si

Table 4 Compositions of the areas marked by 1~18 in Fig.10 determined by EDS (atomic fraction, %)

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