Preparation and Condensation Behavior of Wear Resistant Al-based Superhydrophobic Materials

doi:10.11901/1005.3093.2019.391

Chinese Journal of Materials Research

2020, Vol. 34

Issue (4): 277-284 DOI: 10.11901/1005.3093.2019.391

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Preparation and Condensation Behavior of Wear Resistant Al-based Superhydrophobic Materials

WANG Fang¹, ZHOU Baoyu¹, FENG Wei¹^,²(

), LEI Jialiu¹^,², JIANG Yufeng¹, WANG Qidi¹^,³

1.School of Materials Science and Engineering, Hubei Polytechnic University, Huangshi 435003, China
2.School of Materials Science and Engineering, Key Laboratory of Environmental Pollution Control and Restoration in Hubei Province, Huangshi 435003, China
3.Kunming University of Science and Technology, Faculty of Metallurgy and Energy, Kunming 650000, China

Cite this article:

WANG Fang, ZHOU Baoyu, FENG Wei, LEI Jialiu, JIANG Yufeng, WANG Qidi. Preparation and Condensation Behavior of Wear Resistant Al-based Superhydrophobic Materials. Chinese Journal of Materials Research, 2020, 34(4): 277-284.

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Abstract

Al-based superhydrophobic material with excellent wear resistance were prepared by hydrothermal method. SEM results reveal that there exists a distinct micro-nano hierarchical structure on the surface of the prepared material. After 2,000 cycles of friction test the surface of the prepared material became slightly smooth, but where a large number of ZnO nanorods still remained, which maintains superhydrophobic properties yet. Also, the Al-based superhydrophobic material has good resistance to acid- and alkali-corrosion. Condensation experiments shown that condensate droplets will be randomly generated on the micro-nano hierarchical structure. It is worth noting that the condensate droplets in the groove will gradually get out of the bottom of the groove during the growth and coalescence processes, and finally suspended on the surface. It confirmed that the condensate droplets remain in the Cassie state, which provides a guarantee for the frequent occurrence of self-propelled of condensate droplets.

Key words: surface and interface superhydrophobic materials hydrothermal method wear resistant condensation self-propelled of condensate droplets

Received: 15 August 2019

ZTFLH:

TG174.4

Fund: National Natural Science Foundation of China(No. 21603070);National Natural Science Foundation of China(No. 51704105);Hubei Provincial Central Government Guided Local Science and Technology Development Project(No. 2019ZYYD006)

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	Fang WANG
	Baoyu ZHOU
	Wei FENG
	Jialiu LEI
	Yufeng JIANG
	Qidi WANG

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https://www.cjmr.org/EN/10.11901/1005.3093.2019.391 OR https://www.cjmr.org/EN/Y2020/V34/I4/277

Table 1 Effect of hydrothermal reaction main parameters on Contact angle and Sliding angle

Fig.1 Contact angle (a) and sliding angle (b) of sample B

Fig.2 Contact angle of the samples varies with number of rubbing test

Fig.3 Comparison of surface morphology of samples before and after 2000 rubbing test: sample A (no seed layer, hydrothermal reaction 3 h) before (A) and after rubbing (A'); sample B (3 layers of seed layer, hydrothermal reaction 1 h) before (B) and after rubbing (B'); sample C (3 layers of seed layer, hydrothermal reaction 3 h) before (C) and after rubbing (C')

Fig.4 Contact angle of the sample changes with the number of immersion days (a) acid resistance test and (b) alkali resistance test

Fig.5 Condensed droplets “emerge” from the groove during condensation process on sample B before rubbing test

Fig.6 Self-propelled of condensate droplets of sample B before rubbing test

Fig.7 Condensation cycle process of sample B before rubbing test: (a~e) the first cycle of the condensation cycle; (e~f) the second cycle of the condensation cycle

Fig.8 Condensation cycle process of sample B after 2000 rubbing test: (a~e) the first cycle of the condensation cycle; (e~f) the second cycle of the condensation cycle

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