Effect of a NiCrAlSiY Coating on Cyclic Oxidation and Room Temperature Tensile Properties of Ti65 Alloy Plate

doi:10.11901/1005.3093.2022.145

Chinese Journal of Materials Research

2023, Vol. 37

Issue (7): 523-534 DOI: 10.11901/1005.3093.2022.145

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Effect of a NiCrAlSiY Coating on Cyclic Oxidation and Room Temperature Tensile Properties of Ti65 Alloy Plate

FENG Ye¹^,², CHEN Zhiyong¹(

), JIANG Sumeng¹, GONG Jun¹, SHAN Yiyin¹, LIU Jianrong¹, WANG Qingjiang¹(

)

^1.Shi -changxu Innovation Center for Advanced Materials, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
^2.School of Materials Science and Engineering, University of Science and Technology of China, Shenyang 110016, China

Cite this article:

FENG Ye, CHEN Zhiyong, JIANG Sumeng, GONG Jun, SHAN Yiyin, LIU Jianrong, WANG Qingjiang. Effect of a NiCrAlSiY Coating on Cyclic Oxidation and Room Temperature Tensile Properties of Ti65 Alloy Plate. Chinese Journal of Materials Research, 2023, 37(7): 523-534.

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Abstract

Cyclic oxidation resistance is an essential factor affecting the reliable use of Ti65 Ti-alloy plates in aerospace vehicles. In this paper, the cyclic oxidation resistance of Ti65 plates was investigated by cyclic oxidation testing at 650℃~800℃. The results showed that the NiCrAlSiY coated Ti65 plate was composed of three regions after 500 cycles of oxidation test: coating, diffusion layer, and substrate region. The interface of coating/plate was relatively compact, and the coated plate exhibited a fully antioxidant level. The major oxide on the surface of coated plate was found to be Al₂O₃, while TiO₂ was detected when oxidation temperature increased to 800℃. During cyclic oxidation, the elements diffusion between coating and substrate were mainly Ni and Ti, while the diffusion of a small amount of Cr occurred when temperature increased to 800℃. The inter-diffusion of Ni and Ti were thought to lead to the generation of Ti₂Ni and TiNi at coating/plate interface. After cyclic oxidation, the tensile strength retention of both coated and as-received plates were more than 90%, while the elongation of coated plates was only about 30% of the original plates (before cyclic oxidation). The plates without coating were failed by brittle fracture after cyclic oxidation, obviously, the significant reduction of tensile elongation might be due to the brittleness caused by infiltration of oxygen element at high temperature on the plate surface.

Key words: surface and interface in the materials Ti65 plate NiCrAlSiY coating cyclic oxidation mechanical properties

Received: 15 March 2022

ZTFLH:

TB31

Fund: National Science and Technology Major Project(J2019-VI-0012-0126);Shenyang Science and Technology Plan Project(20-203-5-31)

Corresponding Authors: CHEN Zhiyong, Tel: (024)23971586, E-mail: zhiyongchen@imr.ac.cn;

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	FENG Ye
	CHEN Zhiyong
	JIANG Sumeng
	GONG Jun
	SHAN Yiyin
	LIU Jianrong
	WANG Qingjiang

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https://www.cjmr.org/EN/10.11901/1005.3093.2022.145 OR https://www.cjmr.org/EN/Y2023/V37/I7/523

Fig.1 Size of tensile specimen for plate

Fig.2 Mass change curves of plates after 500 cycles oxidized at 650℃~800℃ (a) coated plates，(b) as-received plates

Table 1 Oxidation performance evaluation after 500 cycles oxidized at 650℃~800℃

Fig.3 XRD patterns of surface of coated plates cyclicly oxidized at different temperatures

Fig.4 Microstructure of as-received plates cyclicly oxidized at different temperatures: (a) 650℃; (b) 700℃;(c) 750℃;(d) 800℃

Fig.5 BSE microstructure of coated plates cyclicly oxidized at different temperatures: (a) 650℃; (b) 700℃; (c) 750℃; (d)800℃

Fig. 6 EPMA element distribution in near surface of coated plates cyclicly oxidized at different temperatures: (a) 650℃; (b)700℃; (c) 750℃ and (d) 800℃

Fig.7 BSE microstructure of coating/substrate interface in plate cyclicly oxidized at different temperatures: (a) 650℃; (b)700℃; (c) 750℃; (d) 800℃

Table2 EDS results (%, atomic fraction) of coating/substrate interface in plate oxidized at different temperature

Fig.8 Schematic diagram of microstructure and element diffusion at interface of coating/substrate: (a) oxidized at 650~750℃; (b) oxidized at 800℃

Fig.9 Hardness distribution of plates cyclicly oxidized at different temperatures: (a) coated plates; (b) as-received plates

Table 3 Room tensile properties of plate after 650℃/500 cycles oxidation

Fig.10 Fracture morphology of plates cyclicly oxidized at 650℃

Fig.11 Fracture morphology and microstructure near the fracture position of plates cyclicly oxidized at 650℃ (a, b) as-received plates; (c, d) coated plates

Fig.12 Schematic diagram of fracture process of as-received and coated plates

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