Effect of Nano-Al2O3 and -TiO2 Modified Silicone Coatings on High Temperature Oxidation Resistance of 304 Stainless Steel

doi:10.11901/1005.3093.2020.258

Chinese Journal of Materials Research

2021, Vol. 35

Issue (6): 458-466 DOI: 10.11901/1005.3093.2020.258

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Effect of Nano-Al₂O₃ and -TiO₂ Modified Silicone Coatings on High Temperature Oxidation Resistance of 304 Stainless Steel

LU Yiliang¹^,², DU Yao¹^,², WANG Cheng²(

), XIN Li¹, ZHU Shenglong¹^,³^,⁴, WANG Fuhui³^,⁴

^1.Shi -Changxu Innovation Center for Advanced Materials, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
^2.School of Materials Science and Engineering, University of Science and Technology of China, Shenyang 110016, China
^3.School of Materials Science and Engineering, Northeastern University, Shenyang 110819, China
^4.Shenyang National Laboratory for Materials Science, Shenyang 110016, China

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LU Yiliang, DU Yao, WANG Cheng, XIN Li, ZHU Shenglong, WANG Fuhui. Effect of Nano-Al₂O₃ and -TiO₂ Modified Silicone Coatings on High Temperature Oxidation Resistance of 304 Stainless Steel. Chinese Journal of Materials Research, 2021, 35(6): 458-466.

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Abstract

Two modified silicone paints were prepared by physical mixing method with nano-Al₂O₃ and -TiO₂ as the main filler. The corresponding paints are sprayed on the surface of tinplate and 304 stainless steel and dried at room temperature to obtain two type of coated samples. The conventional mechanical properties of the two coatings were tested, and the effect of the coating on the oxidation resistance of 304 stainless steel in the air at 600℃ was studied. The results show that both coatings have good adhesion, flexibility and impact resistance. Both coatings can effectively slow down the oxidation of 304 stainless steel at 600℃. When the ratio of nano-Al₂O₃ to TiO₂ is 4:1, the nano-modified organic silicon coating has a better protective effect on 304 stainless steel.

Key words: material surface and interface silicone coating nano filler 304 stainless steel high temperature oxidation

Received: 28 June 2020

ZTFLH:

TG174.4

Fund: Supported by National Key R&D Program of China(2018YFB2003601)

About author: WANG Cheng, Tel: (024)23904856, E-mail: wangcheng@imr.ac.cn

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	Yiliang LU
	Yao DU
	Cheng WANG
	Li XIN
	Shenglong ZHU
	Fuhui WANG

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https://www.cjmr.org/EN/10.11901/1005.3093.2020.258 OR https://www.cjmr.org/EN/Y2021/V35/I6/458

Table 1 Compositions of two nano-modified organic silicone coatings (mass fraction, %)

Fig.1 Macro morphologies of (a, c, e) the coating 1# and (b, d, f) the coating 2 # after the tests of (a, b) adhesion, (c, d) flexibility and (e, f) impact resistance

Fig.2 Oxidation kinetics of uncoated and coated 304 stainless steel samples at 600℃ in air

Fig.3 XRD patterns of 304 stainless steel substrate and two coatings after oxidation at 600℃ for 1000 h

Fig.4 Surface (a) and cross-sectional (b, c) morphologies of 304SS sample after oxidation for 1000 h at 600℃

Fig.5 Surface (a) and cross-sectional (b) morphologies of 304SS coated with the coating 1# after oxidation for 1000 h at 600℃

Table 2 The contents of elements detected by EDS on the surface of the coating 1# after oxidation (atomic fraction, %)

Fig.6 Map scannings of main elements on the cross section of 304SS coated with the coating 1# after oxidation at 600℃ for 1000 h

Fig.7 Surface (a) and cross-sectional (b) morphologies of 304SS coated with the coating 2# after oxidation for 1000 h at 600℃

Table 3 The contents of main elements on the surface of the coating 2# after oxidation (atomic fraction, %)

Fig.8 Map scannings of main elements on the cross section of 304SS sample coated with the coating 2# after oxidation at 600℃ for 1000 h

1	Wang R G, Li E M. Research on W-800℃ silicone high-temperature resistant coating formulation [J]. J. Coat. Appl., 2011, 41(1): 5
	王荣国, 李二明. W-800℃有机硅耐高温涂料配方研究 [J]. 涂料与应用, 2011, 41(1): 5
2	Zhang A X, Zhou Q, Chen L. Progress of silicone industry in China in 2014 [J]. Silicone Mater., 2015, 29: 226
	张爱霞, 周勤, 陈莉. 2014年国内有机硅进展 [J]. 有机硅材料, 2015, 29: 226
3	Mathivanan L, Radhakrishna S. Heat-resistant anti-corrosive paint from epoxy-silicone vehicles [J]. Anti-Corros. Methods Mater., 1997, 44: 400
4	Zhang W J, Chen J H. High-temperature resistant silicone coating and adhesive [J]. Silicone Mater., 2002, 16(3): 28
	张文娟, 陈剑华. 耐高温有机硅涂料及粘接剂 [J]. 有机硅材料, 2002, 16(3): 28
5	Liu H Y, Zhang S. Preparation and properties of black organic silicone coating with high-temperature resistance [J]. Corros. Prot., 2010, 31: 222
	刘宏宇, 张松. 黑色有机硅耐高温涂料的制备及其性能 [J]. 腐蚀与防护, 2010, 31: 222
6	Yu L Y, Li X Y, Luo H. Effect of pigments and fillers on high temperature resistance and anticorrosion of silicone bonding coat modified by epoxy resin [J]. China Adhes., 2010, 19(4): 5
	喻兰英, 李新跃, 罗宏. 颜填料对EP改性有机硅粘接涂层耐高温性能和防腐性能的影响 [J]. 中国胶粘剂, 2010, 19(4): 5
7	Sun J T, Huang Y D, Cao H L, et al. Synthesis of heat-resistant silicone resin and studies on its thermal and curing properties [J]. J. Aeronaut. Mater., 2005, 25(1): 25
	孙举涛, 黄玉东, 曹海琳等. 耐高温有机硅树脂的合成及其耐热和固化性能研究 [J]. 航空材料学报, 2005, 25(1): 25
8	Luo F, Yan X H, Huang L J, et al. Influence of talcum powder on the performance of epoxy modified organosilicane heat-resistant coatings [J]. Fine Chem., 2009, 26: 3
	罗发, 闫晓红, 黄立军等. 滑石粉对环氧改性有机硅耐高温涂层性能的影响 [J]. 精细化工, 2009, 26: 3
9	Lian W Z, Zhang G L, Ma C F, et al. Preparation and properties of anti-corrosive coating with high temperature resistance and thermal insulation [J]. Polym. Mater. Sci. Eng., 2017, 33(6): 152
	廉卫珍, 张国梁, 马春风等. 耐高温防腐隔热涂料的制备与性能 [J]. 高分子材料科学与工程, 2017, 33(6): 152
10	Du Y, Wang C, Zhu S L, et al. High temperature oxidation and electrochemical corrosion behavior of Al nano-particle modified silicone coating on 304 stainless steel [J]. Chin. J. Mater. Res., 2019, 33: 942
	杜瑶, 王成, 朱圣龙等. 304不锈钢表面纳米铝改性有机硅涂层的高温氧化和电化学行为 [J]. 材料研究学报, 2019, 33: 942
11	Wang C, Jiang F, Wang F. Corrosion inhibition of 304 stainless steel by nano-sized Ti/silicone coatings in an environment containing NaCl and water vapor at 400~600℃ [J]. Oxidat. Met., 2004, 62: 1
12	Mitra S K, Roy S K, Bose S K. Influence of superficial coating of CeO₂ on the oxidation behavior of AISI 304 stainless steel [J]. Oxidat. Met., 1993, 39: 221
13	Jovanovic J D, Govedarica M N, Dvornic P R, et al. The thermogravimetric analysis of some polysiloxanes [J]. Polym. Degrad. Stabil., 1998, 61: 87
14	Min C Y, Huang Y D, Song H J, et al. Synthesis of high-temperature resistance hybrid silicon resin and evaluation of its composite material's high-temperature mechanical property [J]. J. Solid Rocket Technol., 2011, 34: 520
	闵春英, 黄玉东, 宋浩杰等. 耐高温杂化有机硅树脂的合成及复合材料的高温力学性能 [J]. 固体火箭技术, 2011, 34: 520
15	Zhang H, Zhang T, Shao Y Q, et al. Comparative study on the different protective coatings at high-temperature for stainless steel 304 [J]. Heat Treat. Met., 2012, 37(2): 96
	张浩, 张腾, 邵艳群等. 不同涂层对304不锈钢高温防护效果的对比研究 [J]. 金属热处理, 2012, 37(2): 96
16	Robino C V. Representation of mixed reactive gases on free energy (Ellingharn-Richardson) diagrams [J]. Metall. Mater. Trans., 1996, 27B: 65
17	Seybolt A U. Observations on the Fe-Cr-O system [J]. J. Electrochem. Soc., 1960, 107: 147
18	Du Y, Wang C, Yang L L, et al. Enhanced oxidation and corrosion inhibition of 1Cr11Ni2W2MoV stainless steel by nano-modified silicone-based composite coatings at 600°C [J]. Corros. Sci., 2020, 169: 108599
19	Wang H Q, Li Y, Gou G L, et al. Discussion on two-step film-forming mechanism of silicone heat resistant coatings [J]. Paint Coat. Ind., 2005, 35(10): 17
	王海侨, 李营, 苟国立等. 有机硅耐高温涂料二次成膜机理的探讨 [J]. 涂料工业, 2005, 35(10): 17
20	Li T F. High Temperature Oxidation and Hot Corrosion of Metals [M]. Beijing: Chemistry Industry Press, 2003
	李铁藩. 金属高温氧化和热腐蚀 [M]. 北京: 化学工业出版社, 2003
21	Zhou L X. Research on the reverse conversion emulsification of epoxy resin and waterborne epoxy resin anticorrosive coating [D]. Guangzhou: South China University of Technology, 2004
	周立新. 环氧树脂的相反转乳化与水性环氧树脂防腐涂料的研究 [D]. 广州: 华南理工大学, 2004

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