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Chin J Mater Res  2012, Vol. 26 Issue (4): 372-376    DOI:
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Performance of Positive Graphite Felt Electrode in the Lead Acid Flow Battery
LIU Xudong, BI Xiaoguo, GUAN Xin, DONG Yingnan
Shenyang Institute of Engineering, Shenyang 110136
Cite this article: 

LIU Xudong BI Xiaoguo GUAN Xin DONG Yingnan. Performance of Positive Graphite Felt Electrode in the Lead Acid Flow Battery. Chin J Mater Res, 2012, 26(4): 372-376.

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Abstract  The chemistry system with graphite felt electrode and a single electrolyte, lead(II) in methanesulfonic acid was described in this paper. The effects of treatment methods on kinetics and cyclic voltammetry behavior of PbO2/Pb(II) couple were investigated. The results show that the equilibrium electrode potential PbO2/Pb(II) couple is 1.25 V and the PbO2/Pb(II) couple on graphite felt electrode has a good kinetics behavior. The cyclic voltammetry behavior of PbO2/Pb(II) couple on graphite felt electrode was investigated, and the oxidization and reduction peak potentials are 1.54V and 1.238V, respectively. The graphite felt treated with methanesulfonic acid, heat and both showed good electrocatalytic activity for PbO2/Pb(II) couple, and the treatment method with methanesulfonic acid is best.
Key words:  inorganic non-metallic materials      graphite felt      PbO2/Pb(II) couple      lead acid flow battery      cyclic voltammetry characteristics     
Received:  09 February 2012     
ZTFLH: 

TM911

 
Fund: 

Supported by Natural science fund in liaoning province No.20102160 and Liaoning Provincial Science And Technology Fund No.L2010384.

URL: 

https://www.cjmr.org/EN/     OR     https://www.cjmr.org/EN/Y2012/V26/I4/372

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