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Chin J Mater Res  2011, Vol. 25 Issue (2): 129-134    DOI:
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High Temperature Cycle Oxidation Behavior of PS45/CuAl8 Pseudo-Alloy Composite Coating
WU Yaosha, QIU Wanqi, YU Hongya, ZHONG Xichun, LIU Zhongwu, ZENG Dechang, LI Shangzhou
School of Materials Science and Engineering, South China University of Technology, Guangzhou 510640
Cite this article: 

WU Yaosha QIU Wanqi YU Hongya ZHONG Xichun LIU Zhongwu ZENG Dechang LI Shangzhou. High Temperature Cycle Oxidation Behavior of PS45/CuAl8 Pseudo-Alloy Composite Coating. Chin J Mater Res, 2011, 25(2): 129-134.

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Abstract  A pseudo-alloy coating PS45/CuAl8 was prepared on Q235 steel by activated combustion high-velocity electirc arc spraying(HVAA). The cycle oxidation experiments at 600oC and 800oC in air for these coatings were accomplished, the microstructure, crystal structure and oxidation resistance properties were haracterized and analyzed by means of X-ray diffraction, scanning electron microscopy (SEM) with energy spectrometer (EDS) and the cycle oxidation behaviors were investigated. The results show that the pseudo-alloy coatings PS45/CuAl8 compose of Al2O3, Cr2 O3, α–Cu and γ–Ni solid solution, and possess dense and typical lamellar structure which were homogeneous. After high temperature oxidation, the coating was covered by dense, continuous and complete oxide films of Cr2O3, Al2O3 and Ni(Cr,Al)2O4, which can avoid spalling of Al2O3 film and reduce the oxidation rate of the composite coating, play an important role for protecting the substrate.
Key words:  surface and interface in the materials      PS45/CuAl8 pseudo-alloy composite coating      activated combustion high-velocity electric arc spraying      high temperature oxidation     
Received:  30 August 2010     
ZTFLH: 

TG146.2

 
Fund: 

Supported by Key Projects of the Guangdong Provincial Science & Technology Program Nos.2009A090100045, 2010A090200077 and 00567440136976033, Project of the Zhongshan Civic Science & Technology Program No.20103A262.

URL: 

https://www.cjmr.org/EN/     OR     https://www.cjmr.org/EN/Y2011/V25/I2/129

1 DONG Chongli, LI Shangzhou, LIN Jiedong, NIE Ming, LIU Hongwen, Active function of Cr2C3 coating properties as HVAF-ARC sprayed, Electromechanical Technology, 34(3), 26(2005)

(董重里, 李尚周, 林介东, 聂铭, 刘红文, HVAF--ARC喷涂Cr2C3活性功能涂层性能的研究, 机电工程技术,  34(3), 26(2005))

2 XIANG J H, Gesmundo F, NIU Y, The oxidation of two ternary Ni–Cu–10at.% Al alloys in 1 atm of pure O2 at 800–900oC, Corrosion Science, 46, 2025(2004)

3 Gabriel Plascencia, Torstein A Utigard, High temperature oxidation mechanism of dilute copper aluminium alloys, Corrosion Science, 47, 1149(2005)

4 ZHANG Zhongli, LI Deyuan, WANG Shuiyong, High temperature performance of ARC-Sprayed aluminium bronze coating for steel, Trans. Nonferrous Met. Soc. China, 16,868(2006)

5 XIANG Junhuai, NIU Yan, WU Weitao, Critical Al content to form external–alumina scales on Cu–Al alloys, Intermetallics, 15, 635(2007)

6 N.F.Ak, C.Tekmen, I.Ozdemir, H.S.Soykan, E.Celik, NiCr coating on stainless by HVOF technique, Surface and Coatings Technology, 173-174, 1070(2003)

7 M.Kemdehoundja, J.F.Dinhut, Grosseau-Poussord, M.Jeannin, High temperature oxidation of Ni70Cr30 alloy: Determination of oxidation kinetics and stress evolution in chromia layers by Raman spectros copy, Materials Sience and Engineering A, 435-436, 666(2006)

8 T.S.Sidhu, S.Prakash, R.D.Agrawal, Characterisation of NiCr wire coatings on Ni- and Fe- based superalloys by the HVOF process, Surface and Coatings Technology, 200, 5542(2006)

9 LI Xuefeng, High temperature oxidation behavior of two Ni-based coatings, Chinese Journal of Rare Metals, 26(2), 108(2002)

(李学锋, 两种镍基合金涂层抗高温氧化性能研究, 稀有金属,  26(2), 108(2002))

10 T.S.Sidhu, S.Prakash, R.D.Agrawal, Characterizations and hot corrosion resistance of Cr3C2–NiCr coating on Ni-base superalloys in an aggressive environment, Journal of thermal spray technology, 15(4), 811(2006)

11 J.Stringer, Coatings in the electricity supply industry: past, present, and opportunities for the future, Surface and coatings technology, 108-109, 1(1998)

12 WANG Xue, ZHANG Janli, ZHOU Hanxiang, MIAO Kasha, Study on microstructure and oxidation resistance properties at elevated temperature of FeCrAl coatings produced by high velocity arc spraying, Journal of aeronautical materials, 26(3), 75(2006)

(王学,张晋丽, 周汉湘, 苗卡沙, 高速电弧喷涂FeCrAl涂层组织结构及抗高温氧化性能研究, 航空材料学报,  26(3), 75--78(2006))

13 S.Sampath, X.Y.Jiang, J.Matejicek, A.C.Leger, A.Vardelle, Substrate temperature effects on splat formation, microstructure development and properties of plasma sprayed coatings Part I :Case study for partially stabilized zirconia, Materials Science and Engineering A, 272, 181(1999)

14 X Jiang, J Matejicek, S Sampath, Substrate temperature effects on the splat formation, microstructure development and properties of plasma sprayed coatings Part II: case study for molybdenum, Materials Science and Engineering A, 272, 189(1999)

15 XIANG Junhuai, NIU Yan, WU Weitao, Oxidation of a ternary Cu-10Ni-5Al in 1×105Pa pure O2 at 700oC∼800oC, Rare Metal Materials and Engineering, 33(10), 1104(2004)

(向军淮, 牛焱, 吴维, Cu--10Ni--5Al三元合金在700℃~800℃, 1×105Pa氧气中的氧化, 稀有金属材料与工程,  33(10), 1104(2004))

16 M.D.Sanderson, J.C.Scully, The high–temperature oxidation of Some oxidation–resistant copper–based alloys, Oxidation of Metals, 3(1), 59(1972)

17 H.J.Ellingham, Society of Chemical Industry, 63, 125(1944)

18 ZHANG Xuejun, GAO Chunxiang, SUN Ling, WANG Shuju, High temperature oxidation behavior of Cu–50Cr two–phase contact material, Rare Metal Materials and Engineering, 37(6), 1078(2008)

(张学军, 高春香, 孙伶, 王淑菊, 双相电触材料Cu--50Cr合金的高温氧化行为, 稀有金属材料与工程,  37(6), 1078(2008))
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