Crystallization and Thermal Shock Behaviors of SiO2-Al2O3-ZnO-CaO-based Glass with Added Different Contents of CeO2 at 900℃

doi:10.11901/1005.3093.2021.568

Chinese Journal of Materials Research

2022, Vol. 36

Issue (2): 90-98 DOI: 10.11901/1005.3093.2021.568

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Crystallization and Thermal Shock Behaviors of SiO₂-Al₂O₃-ZnO-CaO-based Glass with Added Different Contents of CeO₂ at 900℃

FENG Min¹, LIAO Yimin¹, CHEN Minghui¹(

), ZHU Shenglong², WANG Fuhui¹

^1.Shenyang National Laboratory for Materials Science, Northeastern University, Shenyang 110819, China
^2.Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China

Cite this article:

FENG Min, LIAO Yimin, CHEN Minghui, ZHU Shenglong, WANG Fuhui. Crystallization and Thermal Shock Behaviors of SiO₂-Al₂O₃-ZnO-CaO-based Glass with Added Different Contents of CeO₂ at 900℃. Chinese Journal of Materials Research, 2022, 36(2): 90-98.

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Abstract

SiO₂-Al₂O₃-ZnO-CaO enamels were prepared by adding 10%~20% (mass fraction, %) CeO₂ particles with a diameter of 20~50 nm into SiO₂-Al₂O₃-ZnO-CaO-ZrO₂-TiO₂ enamels, and the crystal evolution behavior and phase evolution at 900℃ were investigated by scanning electron microscopy (SEM)/ energy dispersive spectroscopy (EDS), X-ray diffraction (XRD) and transmission electron microscopy (TEM). The results show that: The addition of 20% CeO₂ particles can inhibit the precipitation of needle-like ZrSiO₄ and feather CaTiSiO₅ crystals, With the increase of CeO₂ particle addition level, this hindering effect is enhanced. CeO₂ combines with ZrO₂ in enamel to form solid solution can promote the precipitation of primary crystal CaZrTi₂O₇, while CaZrTi₂O₇ hardly transforms into ZrSiO₄ with the extension of sintering time. Meanwhile, the consumption of Ca and Ti also inhibited the precipitation of CaTiSiO₅crystals during the formation of CaZrTi₂O₇ crystals. These results show that the addition of 20% CeO₂ can make the enamel system maintain high stability and excellent thermal shock resistance at 900℃, and thus prolong the service life of the enamel.

Key words: inorganic non-metallic materials enamel additional CeO₂ crystallization phase transformation thermal shock

Received: 30 September 2021

ZTFLH:

TG174.4

Fund: National Natural Science Foundation of China(51871051)

About author: CHEN Minghui, Tel: (024)23904856, E-mail: mhchen@mail.neu.edu.cn

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	Min FENG
	Yimin LIAO
	Minghui CHEN
	Shenglong ZHU
	Fuhui WANG

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https://www.cjmr.org/EN/10.11901/1005.3093.2021.568 OR https://www.cjmr.org/EN/Y2022/V36/I2/90

Table 1 Nominal compositionof glass frit (mass fraction,%)

Fig.1 XRD patterns of E10C annealed at 900℃ for different time

Fig.2 Back-scattered electron micrographs of E10C annealed at 900℃ for different time (a) 1 h, (b) 4 h, (c) 6 h and (d) 10 h

Fig.3 XRD patterns of E15C annealed at 900℃for different time

Fig.4 Back-scattered electron micrographs of E15C annealed at 900℃ for different time (a) 1 h, (b) 4 h, (c) 6 h and (d) 10 h

Fig.5 XRD patterns of E20C annealed at 900℃for different time

Fig.6 Back-scattered electron micrographs of E20C annealed at 900℃ for different time (a) 1 h, (b) 4 h, (c) 6 h and (d) 10 h

Fig.7 TEM microstructure and elemental mapping of E20C annealed at 900℃ for 0.5 h

Fig.8 Mass change of specimens with E10C, E15C, and E20C enamel coatings after thermal shock at 900℃ for different cycles

Fig.9 Surface (a) and cross-sectional (b) microstructures of as fired E20C enamel coating

Fig.10 Cross-sectional microstructures of E10 C (a), E15C (b) and E20C (c) enamel coatings after thermal shock for 30 cyc at 900℃ (Inset in Fig.10b shows the local enlarged image)

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