氮磷共掺杂石墨烯的制备及水性复合涂层的耐蚀性能

doi:10.11901/1005.3093.2023.498

材料研究学报

2024, Vol. 38

Issue (11): 861-871 DOI: 10.11901/1005.3093.2023.498

研究论文

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氮磷共掺杂石墨烯的制备及水性复合涂层的耐蚀性能

李玉峰¹^,²(

), 冯峰¹, 刘世博¹, 刘丽爽¹, 高晓辉¹

1 齐齐哈尔大学化学与化学工程学院齐齐哈尔 161006
2 齐齐哈尔大学轻工与纺织学院齐齐哈尔 161006

Preparation of Nitrogen and Phosphorus Co-doped Graphene Oxide and Corrosion Resistance of Waterborne Composite Coatings NPGO/Epoxy Resin

LI Yufeng¹^,²(

), FENG Feng¹, LIU Shibo¹, LIU Lishuang¹, GAO Xiaohui¹

1 College of Chemistry and Chemical Engineering, Qiqihar University, Qiqihar 161006, China
2 College of Light Industry and Textile, Qiqihar University, Qiqihar 161006, China

引用本文:

李玉峰, 冯峰, 刘世博, 刘丽爽, 高晓辉. 氮磷共掺杂石墨烯的制备及水性复合涂层的耐蚀性能[J]. 材料研究学报, 2024, 38(11): 861-871.
Yufeng LI, Feng FENG, Shibo LIU, Lishuang LIU, Xiaohui GAO. Preparation of Nitrogen and Phosphorus Co-doped Graphene Oxide and Corrosion Resistance of Waterborne Composite Coatings NPGO/Epoxy Resin[J]. Chinese Journal of Materials Research, 2024, 38(11): 861-871.

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摘要:

以氧化石墨烯(GO)为原料，植酸(PA)为磷源，氨水(NH₃·H₂O)为氮源，采用低温溶液法制备氮磷石墨烯(NPGO)，并以水性环氧树脂(EP)为成膜物制备氮磷石墨烯/环氧树脂(NPGO/EP)水性复合涂层。采用FTIR、XPS、XRD、SEM和TEM对NPGO的结构、形貌进行了表征。通过接触角测试、电化学测试和盐雾实验等研究复合涂层的耐蚀性能。结果表明：相比于EP涂层、GO/EP复合涂层、含磷石墨烯/环氧树脂(PGO/EP)复合涂层和含氮石墨烯/环氧树脂(NGO/EP)复合涂层，NPGO/EP复合涂层对金属的保护作用更好；当NPGO的添加量为1.5% (质量分数)时，电化学阻抗达到4.85 × 10⁸ Ω·cm²，盐雾实验480 h后才出现轻微腐蚀，表现出较好的防腐蚀性能。

关键词 ：材料失效与保护, 耐蚀性能, 氮磷石墨烯, 水性环氧树脂, 复合涂层

Abstract：

N and P co-doped graphene oxide (NPGO) was prepared by low temperature solution method with graphene oxide (GO) as raw material, phytic acid (PA) as P source, and aqueous ammonia solution (NH₃·H₂O) as N source, and then, N and P co-doped graphene/epoxy resin (NPGO/EP) waterborne composite coating was prepared by using waterborne epoxy resin (EP) as the film former. The structure and morphology of NPGO were characterized by FTIR, XPS, XRD, SEM and TEM. The corrosion resistance of composite coatings was assessed by contact angle measurement, electrochemical measurement and salt spray test. The results show that NPGO/EP composite coating has better metal protection effect than pure EP coating, GO/EP composite coating, as well as single P doped graphene/epoxy resin (PGO/EP) composite coating and single N doped graphene/epoxy resin (NGO/EP) composite coating. NPGO/EP composite coating showing good corrosion resistance when the addition amount of NPGO is 1.5% (mass fraction): the electrochemical impedance reaches 4.85 × 10⁸ Ω·cm², and slight rust marks appear only after 480 h of salt spray test.

Key words： materials failure and protection corrosion resistance nitrogen-phosphorus graphene waterborne epoxy resin composite coating

收稿日期: 2023-10-11

ZTFLH:

TB304

基金资助:黑龙江省省属高等学校基本科研业务费科研项目(135509128)

通讯作者: 李玉峰，教授，lyf1170@163.com，研究方向为防腐蚀功能涂层材料

Corresponding author: LI Yufeng, Tel: 15145240877, E-mail: lyf1170@163.com

作者简介: 李玉峰，男，1970年生，博士

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图1 NPGO合成路线示意图

表1 不同复合涂层石墨烯用量

图2 GO、PGO和NPGO的红外光谱图

图3 NPGO的XPS谱图

图4 GO、PGO和NPGO的XRD图

图5 GO、PGO和NPGO的SEM照片

图6 GO、PGO和NPGO的TEM照片

图7 NPGO含量对复合涂层接触角和吸水率的影响

图8 不同填料对涂层附着力的影响

图9 EP涂层和GO/EP、NGO/EP、PGO/EP、NPGO/EP复合涂层在3.5% (质量分数) NaCl溶液中浸泡24 h后的Nyquist和Bode图

表2 EIS拟合数据

图10 电化学阻抗数据拟合等效电路

图11 不同含量的NPGO/EP复合涂层在3.5%NaCl溶液中浸泡不同时间的Nyquist和Bode图

图12 不同涂层经不同时间的盐雾实验后的宏观形貌照片

图13 NPGO/EP复合涂层防腐蚀机理示意图

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