基于界面氢键结构的石墨烯<strong>/</strong>聚合物复合材料的阻尼性能

doi:10.11901/1005.3093.2022.337

材料研究学报

2023, Vol. 37

Issue (6): 401-407 DOI: 10.11901/1005.3093.2022.337

研究论文

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基于界面氢键结构的石墨烯/聚合物复合材料的阻尼性能

张藤心¹^,², 王函¹(

), 郝亚斌¹^,², 张建岗¹^,², 孙新阳¹^,², 曾尤¹^,²(

)

^1.中国科学院金属研究所沈阳材料科学国家研究中心沈阳 110016
^2.中国科学技术大学材料科学与工程学院沈阳 110016

Damping Enhancement of Graphene/Polymer Composites Based on Interfacial Interactions of Hydrogen Bonds

ZHANG Tengxin¹^,², WANG Han¹(

), HAO Yabin¹^,², ZHANG Jiangang¹^,², SUN Xinyang¹^,², ZENG You¹^,²(

)

^1.Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
^2.School of Materials Science and Engineering, University of Science and Technology of China, Shenyang 110016, China

引用本文:

张藤心, 王函, 郝亚斌, 张建岗, 孙新阳, 曾尤. 基于界面氢键结构的石墨烯/聚合物复合材料的阻尼性能[J]. 材料研究学报, 2023, 37(6): 401-407.
Tengxin ZHANG, Han WANG, Yabin HAO, Jiangang ZHANG, Xinyang SUN, You ZENG. Damping Enhancement of Graphene/Polymer Composites Based on Interfacial Interactions of Hydrogen Bonds[J]. Chinese Journal of Materials Research, 2023, 37(6): 401-407.

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摘要:

提出在石墨烯/聚合物复合材料内构筑界面氢键结构，利用氢键的动态可逆性和断裂/再生过程中的能量耗散可显著提高复合材料的阻尼性能。对石墨烯和聚(苯乙烯-乙烯-丁二烯-苯乙烯)(SEBS)进行接枝改性，引入氢键单元从而在石墨烯/SEBS复合材料的界面构筑了多重氢键结构。研究了这种复合材料的循环拉伸以及动态力学性能。结果表明，这种复合材料的弹性模量、滞后损耗、阻尼因子比SEBS分别提高165%、237%和42%。强度和阻尼性能的显著提高，主要归因于复合材料组元间界面氢键的相互作用、高效应力传递、以及氢键可逆断裂/再生过程中显著的能量耗散。

关键词 ：复合材料, 阻尼性能, 界面氢键, 石墨烯, 力学强度

Abstract：

Developing advanced composites with high strength and high vibration damping is extremely important for ensuring high safety and reliability of composites in high-frequency-vibration circumstances. In this paper, we proposed a novel strategy to remarkably enhance the damping property of composites by introducing reversible hydrogen bonds at the interfaces of graphene/polymer composites. Graphene and poly(styrene-ethylene-butadiene-styrene) (SEBS) were chemically modified to graft hydrogen bonding moiety, consequently forming multiple hydrogen-bonding networks at interfaces of graphene/SEBS composites. The cyclic tensile behavior and dynamic mechanical properties of the composites were investigated in detail. The results showed that the mechanical and damping properties of graphene/SEBS composites were greatly improved by introducing graphene and interfacial hydrogen-bonding structures. The elastic modulus, hysteresis loss, and damping ratio of the graphene/SEBS composites were increased by 165%, 237% and 42% in comparison with that of SEBS. Such remarkable enhancement in both mechanical and damping properties is mainly attributed to the interfacial hydrogen bonds between components, high-efficiency stress-transferring, and significant energy dissipation resulted from reversible breaking/formation of hydrogen bonds during cyclic deformation.

Key words： composites damping properties interfacial hydrogen bonds graphene mechanical strength

收稿日期: 2022-06-20

ZTFLH:

TB332

基金资助:国家自然科学基金(52130209);国家自然科学基金(51802317);辽宁省自然科学基金(2019JH3/30100008);纳米功能复合材料山西省重点实验室开放基金(NFCM202102);中国科学院金属所所创基金(2022-PY07);沈阳材料科学国家研究中心项目(2021-FP31)

通讯作者: 曾尤，研究员，yzeng@imr.ac.cn，研究方向为纳米炭复合材料;
王函，副研究员，hanwang@imr.ac.cn，研究方向为纳米炭复合材料

Corresponding author: ZENG You, Tel:(024)83978090, E-mail: yzeng@imr.ac.cn;
WANG Han, Tel:(024)83978090, E-mail: hanwang@imr.ac.cn

作者简介: 张藤心，女，1995年生，博士生

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图1 石墨烯/SEBS复合材料的界面氢键结构示意图

图2 GO、m-Gr、SEBS、m-SEBS和石墨烯/SEBS复合材料的红外光谱和变温原位红外光谱

图3 石墨烯/SEBS复合材料的循环拉伸特性

图4 石墨烯/SEBS复合材料的储能模量、损耗模量、损耗因子以及石墨烯含量不同的成立的储能模量与损耗因子

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