锂离子电池负极材料<strong>TiS<sub>3</sub></strong> 纳米片的制备和性能

doi:10.11901/1005.3093.2021.281

材料研究学报

2022, Vol. 36

Issue (11): 821-828 DOI: 10.11901/1005.3093.2021.281

研究论文

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锂离子电池负极材料TiS₃ 纳米片的制备和性能

肖揽, 于文华, 黄昊(

), 吴爱民, 靳晓哲

大连理工大学材料科学与工程学院辽宁省能源材料及器件重点实验室大连 116024

Preparation and Performance of TiS₃ Nanoflakes as Anode Material for Lithium-ion Batteries

XIAO Lan, YU Wenhua, HUANG Hao(

), WU Aimin, JIN Xiaozhe

Key Laboratory of Energy Materials and Devices (Liaoning Province), School of Materials Science and Engineering, Dalian University of Technology, Dalian 116024, China

引用本文:

肖揽, 于文华, 黄昊, 吴爱民, 靳晓哲. 锂离子电池负极材料TiS₃ 纳米片的制备和性能[J]. 材料研究学报, 2022, 36(11): 821-828.
Lan XIAO, Wenhua YU, Hao HUANG, Aimin WU, Xiaozhe JIN. Preparation and Performance of TiS₃ Nanoflakes as Anode Material for Lithium-ion Batteries[J]. Chinese Journal of Materials Research, 2022, 36(11): 821-828.

全文: PDF(7534 KB) HTML

摘要:

先用直流(DC)电弧法制备TiH_1.924纳米粉作为前驱体，再用固-气相反应制备了片状结构的TiS₃纳米粉体。使用X射线衍射(XRD)、扫描电镜(SEM)、透射电镜(TEM)、原子力显微镜(AFM)、拉曼光谱分析和性能测试等手段对其表征，研究了TiS₃纳米片的结构和将其用作负极的锂离子电池的性能。结果表明：TiS₃纳米片具有特殊的片状结构，其厚度约为35 nm。将TiS₃纳米片用作负极的锂离子电池具有良好的电化学性能，在500 mA/g电流密度下循环300圈后其容量仍保持在430 mAh/g。以5 A/g的大电流密度放电其比容量为240 mAh/g，电流密度恢复到100 mA/g其放电比容量稳定在500 mAh/g。TiS₃良好的倍率性能，源于其特殊的纳米片状结构。这种单层片状结构，能较好地适应电极材料在大电流密度多次放电/充电过程中产生的应变引起的体积变化，使其免于粉碎。

关键词 ：无机非金属材料, 三硫化钛, 直流电弧法, 锂离子电池, 负极, 纳米材料

Abstract：

TiH_1.924 nanometer powder was prepared by DC arc method, and then taking TiH_1.924 as precursor,TiS₃ nanometer flakes with laminar structure was prepared by solid-gas reaction. The structure and performance of TiS₃ nanoflakes as anode material for lithium-ion batteries were characterized by X-ray diffractometer (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), atomic force microscopy (AFM), Raman spectroscopy and performance testing. The performance of TiS₃ nanoflakes as anode for lithium-ion battery was also investigated. The results show that the TiS₃ nanoflake has a special nano-laminar structure, and its thickness is about 35 nm. The lithium-ion battery using TiS₃ nanoflakes as anode material has good electrochemical performance with the remained capacity of 430 mAh/g after 300 cycles at a current density of 500 mA/g. When the current density is 5 A/g the discharge capacity is 240 mAh/g and when the current density is restored to 100 mA/g, the discharge capacity is stable at 500 mAh/g. The good magnification properties of TiS₃ are due to its special nano-flake structure. The mono-laminar structure can better adapt to the volume change caused by the strain in the process of multiple discharge/charging at high current density, so as to prevent the electrode from crushing.

Key words： inorganic non-metallic materials TiS₃ DC arc discharge lithium-ion battery cathode nano materials

收稿日期: 2021-04-30

ZTFLH:

O646

基金资助:中央高校基本科研业务费重点实验室专项经费(DUT20LAB123);江苏省自然科学基金(BK20191167)

作者简介: 肖揽，男，1998年生，硕士生

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图1 TiS3的晶体结构示意图

图2 TiH1.924和TiS3的XRD谱

图3 TiS3纳米片的Raman谱

图4 TiH1.924和TiS3的SEM和TEM照片

图5 TiS3纳米片的TEM、AFM照片以及厚度示意图

图6 TiS3纳米粉体的充放电曲线和倍率性能曲线

图7 TiS3电极片循环前和循环500圈后的SEM照片

图8 TiS3纳米粉体的充放电曲线和CV曲线

图9 TiS3电极片在充放电过程中的非原位XRD谱

图10 TiS3电极循环不同次数后的电化学阻抗谱

图11 TiS3电极材料循环前和循环后电化学阻抗谱的等效电路模拟

表1 TiS3纳米片电极的模拟电路参数

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