在900℃添加CeO2 对SiO2-Al2O3-ZnO-CaO搪瓷析晶和热震行为的影响

doi:10.11901/1005.3093.2021.568

材料研究学报

2022, Vol. 36

Issue (2): 90-98 DOI: 10.11901/1005.3093.2021.568

研究论文

本期目录 | 过刊浏览

在900℃添加CeO₂ 对SiO₂-Al₂O₃-ZnO-CaO搪瓷析晶和热震行为的影响

丰敏¹, 廖依敏¹, 陈明辉¹(

), 朱圣龙², 王福会¹

^1.东北大学沈阳材料科学国家研究中心东北大学联合研究分部沈阳 110819
^2.中国科学院金属研究所沈阳 110016

Crystallization and Thermal Shock Behaviors of SiO₂-Al₂O₃-ZnO-CaO-based Glass with Added Different Contents of CeO₂ at 900℃

FENG Min¹, LIAO Yimin¹, CHEN Minghui¹(

), ZHU Shenglong², WANG Fuhui¹

^1.Shenyang National Laboratory for Materials Science, Northeastern University, Shenyang 110819, China
^2.Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China

引用本文:

丰敏, 廖依敏, 陈明辉, 朱圣龙, 王福会. 在900℃添加CeO₂ 对SiO₂-Al₂O₃-ZnO-CaO搪瓷析晶和热震行为的影响[J]. 材料研究学报, 2022, 36(2): 90-98.
Min FENG, Yimin LIAO, Minghui CHEN, Shenglong ZHU, Fuhui WANG. Crystallization and Thermal Shock Behaviors of SiO₂-Al₂O₃-ZnO-CaO-based Glass with Added Different Contents of CeO₂ at 900℃[J]. Chinese Journal of Materials Research, 2022, 36(2): 90-98.

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摘要:

在SiO₂-Al₂O₃-ZnO-CaO-ZrO₂-TiO₂搪瓷中加入10%~20%(质量分数)粒径为20~50 nm的CeO₂颗粒，制备出SiO₂-Al₂O₃-ZnO-CaO搪瓷，用扫描电子显微镜(SEM)/能谱仪(EDS)、X射线衍射仪(XRD)和透射电镜(TEM)研究其在900℃空气中的析晶行为和相演变。结果表明：添加20%的CeO₂颗粒可阻碍针状ZrSiO₄和羽毛状CaTiSiO₅晶体的析出，随着CeO₂颗粒添加量的提高阻碍作用增强；CeO₂与搪瓷中的ZrO₂结合生成固溶体促进初生晶体CaZrTi₂O₇析出，而CaZrTi₂O₇随着烧结时间的延长几乎不转变为ZrSiO₄。同时，在生成CaZrTi₂O₇晶体的过程中Ca和Ti的消耗也抑制了CaTiSiO₅晶体的析出。这表明，添加20%的CeO₂可使这种搪瓷体系在900℃保持较高的稳定性和优异的抗热震性能，从而延长搪瓷的使用寿命。

关键词 ：无机非金属材料, 搪瓷, 添加CeO₂, 析晶, 相变, 热震

Abstract：

SiO₂-Al₂O₃-ZnO-CaO enamels were prepared by adding 10%~20% (mass fraction, %) CeO₂ particles with a diameter of 20~50 nm into SiO₂-Al₂O₃-ZnO-CaO-ZrO₂-TiO₂ enamels, and the crystal evolution behavior and phase evolution at 900℃ were investigated by scanning electron microscopy (SEM)/ energy dispersive spectroscopy (EDS), X-ray diffraction (XRD) and transmission electron microscopy (TEM). The results show that: The addition of 20% CeO₂ particles can inhibit the precipitation of needle-like ZrSiO₄ and feather CaTiSiO₅ crystals, With the increase of CeO₂ particle addition level, this hindering effect is enhanced. CeO₂ combines with ZrO₂ in enamel to form solid solution can promote the precipitation of primary crystal CaZrTi₂O₇, while CaZrTi₂O₇ hardly transforms into ZrSiO₄ with the extension of sintering time. Meanwhile, the consumption of Ca and Ti also inhibited the precipitation of CaTiSiO₅crystals during the formation of CaZrTi₂O₇ crystals. These results show that the addition of 20% CeO₂ can make the enamel system maintain high stability and excellent thermal shock resistance at 900℃, and thus prolong the service life of the enamel.

Key words： inorganic non-metallic materials enamel additional CeO₂ crystallization phase transformation thermal shock

收稿日期: 2021-09-30

ZTFLH:

TG174.4

基金资助:国家自然科学基金(51871051)

作者简介: 丰敏，女，1991年生，博士生

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https://www.cjmr.org/CN/10.11901/1005.3093.2021.568 或 https://www.cjmr.org/CN/Y2022/V36/I2/90

表1 搪瓷釉的化学成分

图1 E10C在900℃晶化不同时间后的XRD谱

图2 E10C在900℃晶化不同时间后的背散射扫描电镜照片

图3 E15C在900 oC晶化不同时间后的XRD谱

图4 E15C在900℃晶化不同时间后的背散射扫描电镜照片

图5 E20C在900℃晶化不同时间后的XRD谱

图6 E20C在900℃晶化不同时间后的背散射扫描电镜照片

图7 E20C在900℃晶化0.5 h后的TEM微观结构和元素分布

图8 涂覆有E10C、E15C和E20C搪瓷涂层的样品在900℃的热震动力学曲线

图9 E20C搪瓷涂层制备态的表面和截面微观形貌

图10 E10C、E15C和E20C搪瓷涂层在900℃热震30次后截面微观形貌

1	Goward G W . Progress in coatings for gas turbine airfoils [J]. Surf. Coat. Technol., 1998, 73: 108
2	Sivaqumar R , Mordike B L . High temperature coatings for gas turbine blades: A review [J]. Surf. Coat. Technol., 1989, 37(2): 139
3	Jiang C Y , Yang Y F , Zhang Z Y , et al . Preparation and enhanced hot corrosion resistance of a Zr-doped PtAl₂+(Ni, Pt)Al dual-phase coating [J]. Acta. Metall. Sin., 2018,54: 581
3	蒋成洋, 阳颖飞, 张正义等 . 一种Zr改性双相PtAl₂+(Ni, Pt)Al涂层的制备及热腐蚀行为研究 [J]. 金属学报, 2018, 54: 581
4	Teixeira V . Residual stress and cracking in thin PVD coatings [J]. Vacuum, 2002, 64(3): 393
5	Kingery W D . Factors affecting thermal stress resistance of ceramic materials [J]. J. Am. Ceram. Soc., 1955, 38(1): 3
6	Guo H B , Cui Y J , Peng H , et al . Improved cyclic oxidation resistance of electron beam physical vapor deposited nano-oxide dispersed β-NiAl coatings for Hf- containing superalloy [J]. Corros. Sci., 2010, 52: 1440
7	García Ferré F , Oemellese M , Di Fonzo F , et al . Advanced Al₂O₃ coatings for high temperature operation of steels in heavy liquid metals: a preliminary study [J]. Corros. Sci., 2013, 77: 375
8	Malecka J . Effect of an Al₂O₃ coating on the oxidation process of a γ-TiAl phase based alloy [J]. Corros. Sci., 2012, 63: 287
9	Donald I W , Metcalfe B L , Wood D J , et al . The preparation and properties of some lithium zinc silicate glass-ceramics [J]. J. Mater. Sci., 1989, 24(11): 3892
10	Donald I W . Preparation, properties and chemistry of glass-and glass-ceramic-to-metal seals and coatings [J]. J. Mater. Sci., 1993, 28(11): 2841
11	Donald I W , Metcalfe B L , Gerrard L A . Interfacial reactions in glass-ceramic-to-metal seals [J]. J. Am. Ceram. Soc., 2008, 91(3): 715
12	Bengisu M , Brow R K , White J E . Interfacial reactions between lithium silicate glass-ceramics and Ni-based superalloys and the effect of heat treatment at elevated temperatures [J]. J. Mater. Sci., 2004, 39(2): 605
13	Arvind A , Kumar R , Deo M N , et al . Preparation, structural and thermo-mechanical properties of lithium aluminum silicate glass-ceramics [J]. Ceram. Int., 2009, 35(4): 1661
14	Datta S , Das S S . A new high temperature resistant glass-ceramic coating for gas turbine engine components [J]. B. Mater. Sci., 2005, 28(7): 689
15	Das S , Datta S , Basu D , et al . Glass-ceramics as oxidation resistant bond coat in thermal barrier coating system [J]. Ceram. Int., 2009, 35(4): 1403
16	Das S , Mukhopadhyay A K , Datta S , et al . Hard glass-ceramic coating by microwave processing [J]. J. Eur. Ceram. Soc., 2008, 28(4): 729
17	Das S , Datta S , Basu D , et al . Hot corrosion of glass coating on nickel base superalloy [J]. Ceram. Int., 2008, 34(5): 1215
18	Sarkar S , Datta S , Das S , et al . Oxidation protection of gamma-titanium aluminide using glass-ceramic coatings [J]. Surf. Coat. Technol., 2009, 203(13): 1797
19	Das S , Datta S , Basu D , et al . Thermal cyclic behavior of glass-ceramic bonded thermal barrier coating on nimonic alloy substrate [J]. Ceram. Int., 2009, 35(6): 2123
20	Chen M , Li W , Shen M , et al . Glass-ceramic coatings on titanium alloys for high temperature oxidation protection: Oxidation kinetics and microstructure [J]. Corros. Sci., 2013, 74: 178
21	Li W , Zhu S , Wang C , et al . SiO₂-Al₂O₃-glass composite coating on Ti-6Al-4V alloy: Oxidation and interfacial reaction behavior [J]. Corros. Sci., 2013, 74: 367
22	Tang Z , Wang F , Wu W . Effect of Al₂O₃ and enamel coatings on 900℃ oxidation and hot corrosion behaviors of gamma-TiAl [J]. Mat. Sci. and Eng. A., 2000, 276(1): 70
23	Shen M , Zhu S , Chen M , et al . The oxidation and oxygen permeation resistance of quartz particle-reinforced aluminosilicate glass coating on titanium alloy [J]. J. Am. Ceram. Soc., 2011, 94(8): 2436
24	Chen M , Shen M , Zhu S , et al . Preparation and thermal shock behavior at 1000℃ of a glass-alumina-NiCrAlY tri-composite coating on K38G superalloy [J]. Surf. Coat. Technol., 2012, 206(8): 2566
25	Shen M , Zhu S , Wang F . Cyclic oxidation behavior of glass-ceramic composite coatings on superalloy K38G at 1100℃ [J]. Thin Solid Films, 2011, 519(15): 4884
26	Feng M , Chen M H , Yu Z D , et al . Comparative study of thermal shock behavior of the arc ion plating NiCrAlY and the enamel based composite coatings [J]. Acta. Metall. Sin., 2017, 53(12): 1636
26	丰敏, 陈明辉, 余中狄等 . 多弧离子镀NiCrAlY涂层与搪瓷基复合涂层的抗热震行为对比研究 [J]. 金属学报, 2017, 53(12): 1636
27	Liao Y M , Feng M , Chen M H , et al . Comparative study of hot corrosion behavior of the enamel based composite coatings and the arc ion plating NiCrAlY on TiAl alloy [J]. Acta. Metall. Sin., 2019, 55(2): 229
27	廖依敏, 丰敏, 陈明辉等 . TiAl合金表面搪瓷基复合涂层与多弧离子镀NiCrAlY涂层的抗热腐蚀行为对比研究 [J]. 金属学报, 2019, 55(2): 229
28	Chen M , Zhu S , Wang F . Crystallization behavior of SiO₂-Al₂O₃-ZnO-CaO glass system at 1123-1273 K [J]. J. Am. Ceram. Soc., 2010, 93(10): 3230
29	Wang X , Chen M , Zhu S , et al . Phase evolution of SiO₂-Al₂O₃-ZnO-CaO-ZrO₂-TiO₂-Based glass with added Y-PSZ particles [J]. J. Am. Ceram. Soc., 2013, 96(5): 1456

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