新型水性上浆剂对碳纤维及其复合材料界面性能的影响

doi:10.11901/1005.3093.2018.441

材料研究学报

2019, Vol. 33

Issue (4): 284-290 DOI: 10.11901/1005.3093.2018.441

本期目录 | 过刊浏览

新型水性上浆剂对碳纤维及其复合材料界面性能的影响

郑帼^1,^2,³(

),胡允杰^1,³,周存^2,³,吴波^2,³,强永勤^1,³

1. 天津工业大学环境与化学工程学院天津 300387
2. 天津工业大学纺织学院天津 300387
3. 天津市纺织纤维界面处理技术工程中心天津 300270

Effect of a New Water-based Sizing Agent on Properties of Carbon Fibers and Their Composites

Guo ZHENG^1,^2,³(

),Yunjie HU^1,³,Cun ZHOU^2,³,Bo WU^2,³,Yongqin QIANG^1,³

1. Department of Environmental and Chemical Engineering，Tianjin Polytechnic University，Tianjin 300387，China
2. School of Textiles，Tianjin Polytechnic University，Tianjin 300387，China
3. Tianjin Engineering Research Center of Textile Fiber Interface Treatment Technology，Tianjin 300270，China

引用本文:

郑帼,胡允杰,周存,吴波,强永勤. 新型水性上浆剂对碳纤维及其复合材料界面性能的影响[J]. 材料研究学报, 2019, 33(4): 284-290.
Guo ZHENG, Yunjie HU, Cun ZHOU, Bo WU, Yongqin QIANG. Effect of a New Water-based Sizing Agent on Properties of Carbon Fibers and Their Composites[J]. Chinese Journal of Materials Research, 2019, 33(4): 284-290.

全文: PDF(4925 KB) HTML

摘要:

使用新型水性上浆剂O3PPA对碳纤维表面进行改性处理，使用聚己内酰胺树脂为基体制备碳纤维/聚己内酰胺树脂复合材料，使用X射线光电子能谱仪(XPS)、扫描电镜(SEM)、纤维强伸度仪(XQ-1A)、万能材料试验机等手段表征改性后的碳纤维和碳纤维/聚己内酰胺树脂复合材料。结果表明，O3PPA的最佳上浆质量分数和吸附量分别为1%和5 mg/g。经O3PPA处理的碳纤维单丝的断裂强度提高了12%，碳纤维短丝在聚己内酰胺树脂中的分散性明显提高。而经O3PPA处理的碳纤维/聚己内酰胺树脂复合材料，其弯曲强度和层间剪切强度比未处理分别提高了35%和46%。

关键词 ：无机非金属材料, 纤维材料, 水性上浆剂, 聚己内酰胺基复合材料, 力学性能

Abstract：

The surface of carbon fibers was firstly modified with a new water borne sizing agent O3PPA, and then composites of the modified carbon fibers/ polycaprolactam resin were prepared with polycaprolactam resin as matrix. The above prepared products were characterized by means of X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), fiber strength extensometer and universal material testing machine. The results show that the optimum mass fraction and adsorption capacity of O3PPA were 1% and 5mg·g^-1 respectively. The fracture strength of the O3PPA modified carbon fiber monofilament increased by 12% and the dispersibility of short carbon fibers in polycaprolactam resin was significantly improved. Furthermore, the flexural strength and interlaminar shear strength of the modified carbon fibers/polycaprolactam resin composite increased by 35% and 46% respectively compared with those of plain carbon fibers/polycaprolactam resin composite.

Key words： inorganic non-metallic materials fiber material water sizing agent polycaprolactam matrix composites mechanical property

收稿日期: 2018-07-10

ZTFLH:

TQ323.6

基金资助:国家重点研发计划(2016YFB0303200);中石化项目(217010-2);中石化项目(217010-4)

作者简介: 郑帼，女，1957年生，教授

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链接本文:

https://www.cjmr.org/CN/10.11901/1005.3093.2018.441 或 https://www.cjmr.org/CN/Y2019/V33/I4/284

图1 乳液浓度对O3PPA乳液表面张力及碳纤维接触角的影响

表1 改性前后碳纤维表面的元素组成

图2 改性前后碳纤维的XPS C1s峰谱图

图3 O3PPA改性前后碳纤维表面的FE-SEM图

图4 O3PPA改性前后碳纤维的的接触角

图5 碳纤维与聚己内酰胺树脂接触角的简化计算模型

图6 O3PPA上浆剂施覆量对碳纤维分散系数的影响

图7 改性前后碳纤维的单丝断裂强度

图8 改性前后碳纤维短丝/聚己内酰胺树脂的弯曲强度

图9 改性前后碳纤维布/聚己内酰胺树脂的剪切强度

[1]	WuB. Surface Modification and Composite Properties of Polyacrylonitrile Based Carbon Fibers [D]. Tianjin: Tianjin Polytechnic University, 2017
[1]	(吴波. 聚丙烯腈基碳纤维的表面修饰及复合性能研究 [D]. 天津: 天津工业大学, 2017)
[2]	ShuiX Y. Preparation and properties of carbon fibre waterborne sizing agent applied to thermoplastic matrix [D]. Hangzhou: Zhejiang Sci-Tech University, 2016
[2]	(水兴瑶. 应用于热塑性基体的碳纤维水性上浆剂的制备及性能研究 [D]. 杭州: 浙江理工大学, 2016)
[3]	CarrilloJ. G., GamboaR. A., Flores-JohnsonE. A., et al. Ballistic performance of thermoplastic composite laminates made from aramid woven fabric and polypropylene matrix [J]. Polymer Testing, 2012, 31(4)
[4]	DuS Y. Advanced composite materialsand Aeronautics andAstronautics [J]. Acta Materiae Compositae Sinica, 2007(01): 1
[4]	(杜善义. 先进复合材料与航空航天 [J]. 复合材料学报, 2007(01): 1)
[5]	ZhiweiXu, YudongHuang, ChunhuaZhang, et al. Effect of γ-ray irradiation grafting on the carbon fibers and interfacial adhesion of epoxy composites [J]. Composites Science and Technology, 2007, 67(15)
[6]	SooJ P, ByungJ K. Roles of acidic functional groups of carbon fiber surfaces in enhancing interfacial adhesion behavior [J]. Materials Science & Engineering A, 2005, 408(1)
7	MaK, WangB, ChenP, et al. Plasma treatment of carbon fibers: Non-equilibrium dynamic adsorption and its effect on the mechanical properties of RTM fabricated composites [J]. Applied Surface Science, 2011, 257(9)
[8]	YangH B, WangJ, WuH M, et al. Effect of silica sol modificationon tensile properties of carbon fiber /Epoxy Composites [J]. Chinese Journal of Materials Research, 2013, 27(01): 108
[8]	(杨洪斌, 王靖, 吴惠敏等. 硅溶胶改性处理对碳纤维/环氧树脂复合材料拉伸性能的影响 [J]. 材料研究学报, 2013, 27(01): 108)
[9]	ZhangX Q, FanX Y, YanC, et al. Interfacial microstructure and properties of carbon fiber composites modified with graphene oxide. [J]. ACS Applied Materials and Interfaces, 2012, 4(3)
[10]	LiuZ Q. Synthesis of epoxy modified waterborne polyurethane and its application in sizing agent of carbon fibre [D]. Beijing University of Chemical Technology, 2012
[10]	(刘占清. 环氧改性水性聚胺酯的合成及其在碳纤维上浆剂中的应用 [D]. 北京化工大学, 2012)
[11]	LiJ L, TianY H, ZhangX J. Carbon fiber adhesive acrylic-epoxycomposite emulsion and itsapplication [J]. Acta Materiae Compositae Sinica, 2014, 31(02): 518
[11]	(李金亮, 田艳红, 张学军. 碳纤维上胶剂丙烯酸酯-环氧复合乳液及应用 [J]. 复合材料学报, 2014, 31(02): 518)
[12]	KMimura, HIto. Characteristics of epoxy resin cured with in situ polymerized curing agent [J]. Polymer, 2002, 43(26)
[13]	RenH, SunJ Z, WuB J, et al. Synthesis and characterization of a novel epoxy resin containing naphthyl/dicyclopentadiene moieties and its cured polymer [J]. Polymer, 2006, 47(25)
[14]	ZhangR L, HuangY D, SuD, et al. Influence of sizing molecular weight on the properties of carbon fibers and its composites [J]. Materials and Design, 2011, 34
[15]	YiY, YeF, HuangC, et al. Study on synthesis of polyurethane‐epoxy composite emulsion [J]. Journal of Applied Polymer Science, 2010, 115(1)
[16]	NerinaA. Camino, OscarE. Pérez, Cecilio CarreraSanchez, et al. Hydroxypropylmethylcellulose surface activity at equilibrium and adsorption dynamics at the air-water and oil-water interfaces [J]. Food Hydrocolloids, 2009, 23(8)
[17]	GorenS L. The shape of a thread of liquid undergoing break-up [J]. Journal of Colloid Science, 1964, 19(1): 81
[18]	CarrollB J. The accurate measurement of contact angle,plase contact areas, drop volume,and Laplace excess pressure in drop-on -fibre systems [J]. Journal of Colloid and Interface Science, 1976, 57(3): 488
[19]	VautardF, FiouxP, VidalL, et al.Influence of the carbon fiber surface properties on interfacial adhesion in carbon fiber-acrylate composites cured by electron beam[J]. Composites Part A Applied Science & Manufacturing, 2011, 42(7): 859
[20]	WeiS, GuA, LiangG, et al. Effect of the surface roughness on interfacial properties of carbon fibers reinforced epoxy resin composites [J]. Applied Surface Science, 2011, 257(257): 4069
[21]	SunH, GuoG, MemonS A, et al. Recycling of carbon fibers from carbon fiber reinforced polymer using electrochemical method [J]. Composites Part A Applied Science & Manufacturing, 2015, 78: 10
[22]	WangC, LiK Z, LiH J, et al. Effect of carbon fiber dispersion on the mechanical properties of carbon fiber-reinforced cement-based composites [J]. Materials Science & Engineering A, 2007, 487(1)
[23]	ArmandaViksne, LigitaRence, MartinsKalnins, et al. The effect of paraffin on fiber dispersion and mechanical properties of polyolefin-sawdust composites [J]. Journal of Applied Polymer Science, 2004, 93(5)

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