不同微观结构Zr55Al10Ni5Cu30块体非晶合金的晶化过程*

doi:10.11901/1005.3093.2014.069

材料研究学报

2014, Vol. 28

Issue (6): 427-432 DOI: 10.11901/1005.3093.2014.069

本期目录 | 过刊浏览

不同微观结构Zr₅₅Al₁₀Ni₅Cu₃₀块体非晶合金的晶化过程^*

闫红红,胡勇(

),李永堂,闫志杰,赵达文,郭一娜

太原科技大学材料科学与工程学院金属材料成形理论与技术山西省重点实验室太原 030024

Crystallization Process of Zr₅₅Al₁₀Ni₅Cu₃₀ Bulk Metallic Glasses with Different Microstructure

Honghong YAN,Yong HU(

),Yongtang LI,Zhijie YAN,Dawen ZHAO,Yina GUO

Shanxi Key Laboratory of Metallic Materials Forming Theory and Technology, School of Materials Science and Engineering, Taiyuan University of Science and Technology, Taiyuan 030024

引用本文:

闫红红,胡勇,李永堂,闫志杰,赵达文,郭一娜. 不同微观结构Zr₅₅Al₁₀Ni₅Cu₃₀块体非晶合金的晶化过程^*[J]. 材料研究学报, 2014, 28(6): 427-432.
Honghong YAN, Yong HU, Yongtang LI, Zhijie YAN, Dawen ZHAO, Yina GUO. Crystallization Process of Zr₅₅Al₁₀Ni₅Cu₃₀ Bulk Metallic Glasses with Different Microstructure[J]. Chinese Journal of Materials Research, 2014, 28(6): 427-432.

全文: PDF(1943 KB) HTML

摘要:

用差示扫描量热仪分别对具有相似晶体体积分数和晶化激活能的Zr₅₅Al₁₀Ni₅Cu₃₀块体非晶合金铸态、轧制态试样进行等温和连续升温实验, 研究了不同微观结构块体非晶合金的晶化过程。结果表明, 在晶化初期(小于30 min), 两个试样具有相似的晶化速率; 晶化后期(大于30 min), 轧制态试样表现出较快的晶化速率。这在一定程度上表明, 用JMA公式和晶化开始温度T_x及峰值温度T_p计算出的晶化激活能不能全面反映非晶合金的热稳定性。另外, 剪切带中原子之间相互联接的减弱以及短程有序的强化, 使轧制态试样热稳定性降低和晶化过程变快。

关键词 ：金属材料, 非晶合金, 晶化过程, 微观结构

Abstract：

The crystallization process of the as-cast and as-rolled Zr₅₅Al₁₀Ni₅Cu₃₀ bulk metallic glasses, which have similar crystallization fraction and crystallization activation energy but different microstructure, was inverstigated by means of differential scanning calorimeter (DSC) with isothermal and continuous heating. The results show that the two metallic glasses exhibit similar crystallization rate in the initial stage of crystallization (until 30 min), while the crystallization rate of the as-rolled one is faster than that of the as-cast one in the later stage of crystallization (after 30 min); however, according to JMA equation, the crystallization activation energy deduced from crystallization onset temperature T_x and crystallization peak temperature T_p can not give a comprehensive explanation on the thermal stability of metallic glasses. In addition, the weakening of atomic binding forces and strengthening of short range order in the shear bands may decrease the thermal stability and therewith enhance the crystallization rate of the as-rolled Zr₅₅Al₁₀Ni₅Cu₃₀ metallic glass.

Key words： metallic materials metallic glass crystallization process microstructure

收稿日期: 2014-02-11

基金资助:* 国家自然科学基金51204118, 山西省高等学校青年学术带头人支持计划(2013), 山西省回国留学人员科研资助项目2013-094, 山西省自然科学基金2011021020-1和2012021018-3资助项目。

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https://www.cjmr.org/CN/10.11901/1005.3093.2014.069 或 https://www.cjmr.org/CN/Y2014/V28/I6/427

图1 铸态和变形量为95%的轧制态Zr55Al10Ni5Cu30试样的XRD谱

图2 铸态和变形量为95%的轧制态Zr55Al10Ni5Cu30试样的HRTEM图像

图3 铸态和变形量为95%的轧制态Zr55Al10Ni5Cu30试样在20 K/min加热速率下的DSC曲线和局部放大图

表1 铸态和变形量为95%的轧制态Zr55Al10Ni5Cu30试样在20 K/min加热速率下的热力学参数[13]

图4 铸态和变形量为95%的轧制态Zr55Al10Ni5Cu30试样在715 K等温不同时间后再进行连续升温的DSC曲线(加热速率为20 K/min), 以及晶化峰面积与退火时间的关系

表2 铸态和变形量为95%的轧制态Zr55Al10Ni5Cu30试样在715 K退火不同时间后的晶体体积分数

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