相对运动速度对柔性摩擦辅助电沉积镍镀层结构的影响<sup>*</sup>

doi:10.11901/1005.3093.2013.616

材料研究学报

2014, Vol. 28

Issue (4): 255-261 DOI: 10.11901/1005.3093.2013.616

本期目录 | 过刊浏览

相对运动速度对柔性摩擦辅助电沉积镍镀层结构的影响^*

吕镖^1,²,胡振峰³(

),汪笑鹤²,徐滨士²

1. 东北大学材料与冶金学院沈阳 110819
2. 装甲兵工程学院再制造技术国防科技重点实验室北京 100072
3. 装甲兵工程学院机械产品再制造国家工程研究中心北京 100072

Effect of Relative Moving Speed on Microstructure of Flexible Friction Assisted Electrodeposited Ni Coating

Biao LV^1,²,Zhenfeng HU^3,^**(

),Xiaohe WANG²,Binshi XU²

1. School of Materials and Metallurgy, Northeastern University, Shenyang 110819
2. National Key Laboratory for Remanufacturing, Academy of Armored Forces Engineering, Beijing 100072
3. National Engineering Research Center of Mechanical Products Remanufacturing, Academy of Armored Forces Engineering, Beijing 100072

引用本文:

吕镖,胡振峰,汪笑鹤,徐滨士. 相对运动速度对柔性摩擦辅助电沉积镍镀层结构的影响^*[J]. 材料研究学报, 2014, 28(4): 255-261.
Biao LV, Zhenfeng HU, Xiaohe WANG, Binshi XU. Effect of Relative Moving Speed on Microstructure of Flexible Friction Assisted Electrodeposited Ni Coating[J]. Chinese Journal of Materials Research, 2014, 28(4): 255-261.

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摘要:

在相对运动速度不同的条件下, 采用新型的柔性摩擦辅助电沉积技术在不含任何添加剂的Watts镀液中制备镍镀层, 用SEM、AFM、XRD、TEM、X射线应力衍射仪以及硬度计等手段分别对镀层的形貌、结构、残余应力和硬度进行了表征。结果表明: 相对运动速度对镍镀层的组织结构具有重要影响。相对运动速度在4.8-14.4 m/min范围内, 电沉积的镍镀层均为面心立方结构, 并呈现强(311)晶面择优取向; 随着相对运动速度的增加, 镀层表面的针状镍逐渐变得均匀、细小和致密, 拉应力先降低后增大, 而硬度从406 HV增加到471 HV。当相对运动速度为12 m/min时, 镍镀层的平均晶粒尺寸约为100 nm, 具有较高的硬度460 HV和最低的拉应力约100 MPa。

关键词 ：金属材料, 相对运动速度, 柔性摩擦, 电沉积, 纳米晶镍, 组织结构

Abstract：

Ni coatings were prepared by a novel flexible friction assisted electroplating technology from an additive-free Watts bath at different relative moving speed. The morphology, microstructure, residual stress and microhardness of deposits were characterized by SEM, AFM, XRD, TEM, X-ray stress tester and microhardness tester, respectively. The results show that relative moving speed has important effect on the microstructure of Ni coating. At a relative moving speed range of 4.8-14.4 m/min, electrodeposited Ni coatings have face center cubic crystallography structure with a strong preferred orientation of (311). With the increase of the relative moving speed, the needle-like Ni crystallites gradually becomes uniformity, fine and compact on the surface of coatings; Tensile stress of the coatings firstly decrease then increase, but the microhardness gradually increase from 406 HV to 471 HV. When the relative moving speed achieves 12 m/min, the electrodeposited Ni coating shows much higher microhardness of 460 HV, a lowest tensile stress of about 100 MPa, and the average grain size of about 100 nm.

Key words： metallic materials relative moving speed flexible friction electrodeposition nanocrystalline Ni microstructure

收稿日期: 2013-08-25

基金资助:* 国家自然科学基金51005244 和国家重点基础研究发展计划2011CB013403 资助项目。

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https://www.cjmr.org/CN/10.11901/1005.3093.2013.616 或 https://www.cjmr.org/CN/Y2014/V28/I4/255

图1 柔性摩擦辅助电沉积装置的示意图

图2 相对运动速度对柔性摩擦辅助电沉积镍镀层表面形貌的影响

图3 相对运动速度为12 m/min时柔性摩擦辅助电沉积镍镀层的截面形貌

图4 相对运动速度为12 m/min时柔性摩擦辅助电沉积镍镀层的AFM形貌

图5 不同相对运动速度下柔性摩擦辅助电沉积镍镀层的XRD谱及其织构系数

图6 相对运动速度为12 m/min时柔性摩擦辅助电沉积镍镀层的明场、暗场TEM像和选区电子衍射

图7 相对运动速度对柔性摩擦辅助电沉积镍镀层残余应力和硬度的影响

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