材料研究学报  2013, Vol. 27 Issue (5): 477-482

研究论文 本期目录 | 过刊浏览 |

侧链含环金属铱配合物的芴-咔唑有机磷光聚合物的合成和光电性能*

邓继勇1, 2 刘 煜2 谭 华2 黄先威1 黄赛金1 朱卫国2

1. 湖南工程学院化学化工学院 湘潭 411104 2. 湘潭大学化学学院 环境友好化学与应用教育部重点实验室 湘潭 411105

Synthesis and Optoelectronic Properties of Flourene-Carbazole Organic Phosphorescent Polymers Pending Cyclomatlated Iridium Complex Moiety

DENG Jiyong1, 2** LIU Yu2 TAN Hua2 HUANG Xianwei1 HUANG Saijin1 ZHU Weiguo2

1. Department of Chemistry and Engineering, Hunan Institute of Engineering, Xiangtan 411104 2. College of Chemistry, Key Lab of Envirornment-Friendly Chemistry and Application of Ministry of Education, Xiangtan University, Xiangtan 411105

邓继勇, 刘 煜, 谭华, 黄先威, 黄赛金, 朱卫国. 侧链含环金属铱配合物的芴-咔唑有机磷光聚合物的合成和光电性能*[J]. 材料研究学报, 2013, 27(5): 477-482.
DENG Jiyong, LIU Yu, TAN Hua, HUANG Xianwei, HUANG Saijin, ZHU Weiguo. Synthesis and Optoelectronic Properties of Flourene-Carbazole Organic Phosphorescent Polymers Pending Cyclomatlated Iridium Complex Moiety[J]. Chinese Journal of Materials Research, 2013, 27(5): 477-482.

摘要 相关文章 Metrics 全文: PDF(2359 KB)   摘要: 以聚芴为主链, 通过Suzuki偶联反应合成了一类新型侧链含环金属铱配合物的芴-咔唑有机磷光聚合物PFCzIrpiq, 通过凝胶渗透色谱仪测定其分子量, 通过核磁共振氢谱表征化学结构, 研究了聚合物的光电性能。以该聚合物为发光层制备结构为ITO/PEDOT: PSS (50 nm)/PFCzIrpiq (45 nm)/LiF(0.5 nm)/Al (150 nm)的器件, 测试了器件的电致发光性能。结果表明, 在聚合物单体中铱配合物单元摩尔投料比对聚合物的发光颜色影响较大: 当铱配合物单元摩尔投料比为1%时聚合物器件的色坐标为(0.22, 0.22), 位于蓝光区域; 当增大到5%时聚合物器件色坐标为(0.65, 0.35), 位于红光区域; 随着铱配合物单元摩尔投料比的增大, 器件的启亮电压变化较小, 而器件的电流密度逐渐减小, 器件的最大发光亮度逐渐增大。当铱配合物单元摩尔投料比为5%时, 器件的最大发光亮度为48 cd/m2。 关键词 ： 有机高分子材料,  有机磷光聚合物,  合成,  聚合物电致发光器件,  光电性能     Abstract：A novel flourene-alt-karbazole organic phosphorescenct polymers (PFCzIrpiq) containing a pendent phosphor chromophore of the (Piq)2Ir(Pic) were synthesized via Suzuki coupling reaction. Their molecular mass was measured by gel permeation chromatograph, chemical structure was characterized by 1H NMR, and the photophysical property, thermal stability and electrochemical property of these polymers were investigated by UV absorption spectra, fluorescence spectra, thermogravimetric analysis and cyclic voltammetry. Using the polymers as emitting layer, the devices were made with a configuration of ITO/PEDOT: PSS (50 nm)/ PFCzIrpiq (45 nm)/LiF(0.5 nm)/Al (150 nm), and their electroluminescent properties were measured. The results show that the molar percentage of (Piq)2Ir(Pic) in these polymers has great influence on light-emitting color of these polymers. When the molar percentage was 1%, the device exhibited blue emission with a CIE coordinate of (0.22, 0.22); when the percentage was increased to 5%, the device emitted saturated red light with a CIE coordinate(0.65, 0.35). Furthermore, with the increasing of molar percentage of (Piq)2Ir(Pic), the current density decreased and the maximum brightness increased gradually. When the molar percentage was 5%, the maximum brightness of 48 cd/m2 was achieved. Key words： organic polymer materials    organic phosphorescent polymers    synthesis    polymeric electroluminescent devices    optoelectronic properties      ZTFLH:  TB324   服务 把本文推荐给朋友 加入引用管理器 E-mail Alert RSS 作者相关文章 邓继勇 刘 煜 谭华 黄先威 黄赛金 朱卫国 44.8K 链接本文: https://www.cjmr.org/CN/      或      https://www.cjmr.org/CN/Y2013/V27/I5/477 [1] 叶姣凤, 王飞, 左洋, 张钧翔, 罗晓晓, 冯利邦. 兼具高强度、高韧性和自修复性能的环氧树脂改性热可逆聚氨酯[J]. 材料研究学报, 2023, 37(4): 257-263. [2] 李瀚楼, 焦晓光, 朱欢欢, 赵晓欢, 矫庆泽, 冯彩虹, 赵芸. 支链含氟聚酯的合成和性能[J]. 材料研究学报, 2023, 37(4): 315-320. [3] 马逸舟, 赵秋莹, 杨路, 裘进浩. 热塑型聚酰亚胺/聚偏氟乙烯全有机复合薄膜的制备及其介电储能[J]. 材料研究学报, 2023, 37(2): 89-94. [4] 周海涛, 侯湘武, 汪彦博, 肖旅, 袁勇, 孙京丽. 高Nb-TiAl合金的高温变形行为及其板材的性能[J]. 材料研究学报, 2022, 36(6): 471-480. [5] 闫福照, 李静, 熊良银, 刘实. FeCr-ODS铁素体合金的氧化+粉锻工艺制备及其微观结构[J]. 材料研究学报, 2022, 36(6): 461-470. [6] 殷洁, 胡云涛, 刘慧, 杨逸霏, 王艺峰. 基于电沉积技术构建聚苯胺/海藻酸膜及电化学性能研究[J]. 材料研究学报, 2022, 36(4): 314-320. [7] 申延龙, 李北罡. 磁性氨基酸功能化海藻酸铝凝胶聚合物的制备及对偶氮染料的超强吸附[J]. 材料研究学报, 2022, 36(3): 220-230. [8] 龙庆, 王传洋. 不同碳黑含量PMMA的热降解行为和动力学分析[J]. 材料研究学报, 2022, 36(11): 837-844. [9] 蒋平, 吴丽华, 吕太勇, José Pérez-Rigueiro, 王安萍. 蜘蛛大壶状腺丝的反复拉伸力学行为和性能[J]. 材料研究学报, 2022, 36(10): 747-759. [10] 鄢俊, 杨进, 王涛, 徐桂龙, 李朝晖. 有机硅油改性水性酚醛的制备及其性能[J]. 材料研究学报, 2021, 35(9): 651-656. [11] 赵万里, 索红莉, 刘敏, 马麟, 戴银明, 张子立. 用扩散法制备MgB2块材的研究进展[J]. 材料研究学报, 2021, 35(6): 411-418. [12] 张昊, 李帆, 常娜, 王海涛, 程博闻, 王攀磊. 羧酸型接枝淀粉吸附树脂的制备和对染料的去除性能[J]. 材料研究学报, 2021, 35(6): 419-432. [13] 孙丽颖, 钱建华, 赵永芳. AgNWs-TPU/PVDF柔性薄膜电容传感器的制备和性能[J]. 材料研究学报, 2021, 35(6): 441-448. [14] 唐开元, 黄洋, 黄湘舟, 葛颖, 李娉婷, 袁凡舒, 张威威, 孙东平. 碳化细菌纤维素的理化性质及其在甲醇电催化中的应用[J]. 材料研究学报, 2021, 35(4): 259-270. [15] 胡满银, 欧阳德来, 崔霞, 杜海明, 徐勇. 微波烧结原位合成TiC增强钛复合材料的性能[J]. 材料研究学报, 2021, 35(4): 277-283. Viewed Full text Abstract Cited   Shared      Discussed