材料研究学报  2011, Vol. 25 Issue (2): 179-182

研究论文 本期目录 | 过刊浏览 |

钴掺杂对氧化镍薄膜电致变色性能的影响

王景, 苏革, 曹立新, 柳伟, 董征, 赵莉丽, 宋美芹

中国海洋大学材料科学与工程研究院 青岛 266100

Effect of Co on the Electrochromic Properties of NiO Film

WANG Jing, SU Ge, CAO Lixin, LIU Wei, DONG Zheng, ZHAO Lili, SONG Meiqin

Institute. of Materials Science and Engineering, Ocean University of China, Qingdao 266100

王景 苏革 曹立新 柳伟 董征 赵莉丽 宋美芹. 钴掺杂对氧化镍薄膜电致变色性能的影响[J]. 材料研究学报, 2011, 25(2): 179-182.
. Effect of Co on the Electrochromic Properties of NiO Film[J]. Chin J Mater Res, 2011, 25(2): 179-182.

摘要 参考文献 相关文章 Metrics 全文: PDF(948 KB)   摘要: 采用恒电位法在FTO玻璃上沉积Co与Ni摩尔比为0.16:1的薄膜, 用X射线衍射仪、扫描电镜和能谱仪分析了膜的成分、结构和形貌, 用紫外--可见分光光度计表征了膜的透光性能, 用循环伏安法表征了膜的电化学稳定性和可逆性, 用双电位阶跃法表征了膜的开关响应时间, 研究了钴掺杂对氧化镍薄膜电致变色性能的影响。结果表明, 钴掺杂使NiO薄膜颗粒更加细小和均匀, 提高了薄膜在可见光波段着色态与消色态之间的透光率差值, 降低了电致变色反应的工作电压, 有利于薄膜在电致变色过程的可逆性, 缩短了着色响应时间。 关键词 ： 无机非金属材料,  电致变色,  钴掺杂氧化镍薄膜,  可逆性     Abstract：The film of Co/Ni molar ratio of 0.16:1 was electrode posited on FTO glass by potentiostatic technique. XRD, SEM and EDS were employed to analyze the morphology composition, structure of the film; Uhraviolet-visible transmission spectroscopy was applied to measure transmittance of the films. Cyclic voltammetry was used to characterize the electrochemical stability and reversibility of the film. And switch response time was measured by double potential step technique. The Effect of Co on the electrochromic properties of NiO film was investigated. The results show that Co can make the particles of NiO film tiny and even, raise visible light transmittance difference between bleached and colored states, lower the working voltage of eleetroehromic reaction, improve eleetroehromic reversibility and shorten the time of colored processes. Key words： inorganic non-metallic materials    electrochromic    Co-doped NiO film    reversibility 收稿日期: 2010-07-22      ZTFLH:  O484   基金资助: 山东省自然科学基金ZR2010EM027。 服务 把本文推荐给朋友 加入引用管理器 E-mail Alert RSS 作者相关文章 王景 44.8K 链接本文: https://www.cjmr.org/CN/      或      https://www.cjmr.org/CN/Y2011/V25/I2/179 1 Walter Estrada, Anne M, Andersson, Electrochromic nickel-oxide-based coatings made by reactive dc magnetron sputtering : preparation and optical properties, Appl. Phys, 64(7), 3678(1988) 2 Yu P C, Lampert C M, In-situ spectroscopic studies of electrochromic hydrated nickel oxide films, SPIE, 823(2), 113(1987) 3 Richardson T J, Slack J L, Armitage R D, Switchable mirrors based on nickel–magnesium films, Applied Physics Letters, 78(20), 3047(2001) 4 Slack J L, Locke J C, Song SW,Metal hydride switchable mirrors : factors influencing dynamic range and stability, Solar Energy Materials Solar Cells, 90(4), 485(2005) 5 Kazuki Yoshimura, Takeshi Miki, Sakae Tanemura, Nickel oxide electrochromic thin films prepared by reactive DC mangetron sputtering, Appl. Phys., 34(5A), 2440(1995) 6 Hutchins M G, Mcmeeking G, Hu Xingfang, The nickel oxide electrochromic films deposited by rf reactive sputtering, SPIE, 1(272), 139(1990) 7 Cao Xiaoyan, Zhang Wenhu, Yuan Huatang, Some effects of Co on the electrochromic properties of NiOxHy film, Electrochemistry, 5(1), 59(1999) 8 K Provazi, M J Giz, L H Dall’Antonia, S I Co’rdoba de Torresi, The effect of Cd, Co, and Zn as additives on nickel hydroxide opto-electrochemical behavior, Journal of Power Sources, 102(1), 224(2001) 9 ZHAO Li, HAN Xijiang, LIN Jianbin, MA Yaqi, Preparation of nano-scale β-Ni(OH)2 doped Co and its cyclic voltammogram behavior, Journal of functional Materials, 8(36), 1276(2006) (赵力, 韩喜江, 林剑斌, 马亚旗, 掺杂Co纳米β-Ni(OH)2的制备及其循环伏安行为, 功能材料,  8(36), 1276(2006)) 10 YU Weiping, YANG Xiaoping, MENG Lingkuan, LIU Zhaozhe, Electrodeposition of Co doped NiOH electrode material and its capacity characteristics, Transactions of materials and heat treatment, 26(6), 30(2005) 11 SUN Wuzhu, Su Ge, CAO Linxin, LIU Wei, JIA Bo, WANG Jing, DONG Zheng, Electrodeposition and properties of NiO electrochromic films, Science & Technology Review, 27(18), 66(2009) [1] 宋莉芳, 闫佳豪, 张佃康, 薛程, 夏慧芸, 牛艳辉. 碱金属掺杂MIL125的CO2 吸附性能[J]. 材料研究学报, 2023, 37(9): 649-654. [2] 邵鸿媚, 崔勇, 徐文迪, 张伟, 申晓毅, 翟玉春. 空心球形AlOOH的无模板水热制备和吸附性能[J]. 材料研究学报, 2023, 37(9): 675-684. [3] 任富彦, 欧阳二明. g-C3N4 改性Bi2O3 对盐酸四环素的光催化降解[J]. 材料研究学报, 2023, 37(8): 633-640. [4] 刘明珠, 樊娆, 张萧宇, 马泽元, 梁城洋, 曹颖, 耿仕通, 李玲. SnO2 作散射层的光阳极膜厚对量子点染料敏化太阳能电池光电性能的影响[J]. 材料研究学报, 2023, 37(7): 554-560. [5] 李延伟, 罗康, 姚金环. Ni(OH)2 负极材料的十二烷基硫酸钠辅助制备及其储锂性能[J]. 材料研究学报, 2023, 37(6): 453-462. [6] 余谟鑫, 张书海, 朱博文, 张晨, 王晓婷, 鲍佳敏, 邬翔. N掺杂生物炭的制备及其对Co2+ 的吸附性能[J]. 材料研究学报, 2023, 37(4): 291-300. [7] 朱明星, 戴中华. SrSc0.5Nb0.5O3 改性BNT基无铅陶瓷的储能特性研究[J]. 材料研究学报, 2023, 37(3): 228-234. [8] 刘志华, 岳远超, 丘一帆, 卜湘, 阳涛. g-C3N4/Ag/BiOBr复合材料的制备及其光催化还原硝酸盐氮[J]. 材料研究学报, 2023, 37(10): 781-790. [9] 周毅, 涂强, 米忠华. 制备方法对磷酸盐微晶玻璃结构和性能的影响[J]. 材料研究学报, 2023, 37(10): 739-746. [10] 谢锋, 郭建峰, 王海涛, 常娜. ZnO/CdS/Ag复合光催化剂的制备及其催化和抗菌性能[J]. 材料研究学报, 2023, 37(1): 10-20. [11] 余超, 邢广超, 吴郑敏, 董博, 丁军, 邸敬慧, 祝洪喜, 邓承继. 亚微米Al2O3 对重结晶碳化硅的作用机制[J]. 材料研究学报, 2022, 36(9): 679-686. [12] 方向明, 任帅, 容萍, 刘烁, 高世勇. 自供能Ag/SnSe纳米管红外探测器的制备和性能研究[J]. 材料研究学报, 2022, 36(8): 591-596. [13] 李福禄, 韩春淼, 高嘉望, 蒋健, 许卉, 李冰. 氧化石墨烯的变温发光[J]. 材料研究学报, 2022, 36(8): 597-601. [14] 朱晓东, 夏杨雯, 喻强, 杨代雄, 何莉莉, 冯威. Cu掺杂金红石型TiO2 的制备及其光催化性能[J]. 材料研究学报, 2022, 36(8): 635-640. [15] 熊庭辉, 蔡文汉, 苗雨, 陈晨龙. ZnO纳米棒阵列和薄膜的同步外延生长及其光电化学性能[J]. 材料研究学报, 2022, 36(7): 481-488. Viewed Full text Abstract Cited   Shared      Discussed