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材料研究学报  2011, Vol. 25 Issue (1): 51-56    
  研究论文 本期目录 | 过刊浏览 |
α/β互嵌氢氧化镍电极活性材料的结构和电化学性能
李延伟1,2, 李月晓1,  姚金环1, 刘长久1,2,朱文凤2
1.桂林理工大学化学与生物工程学院 桂林 541004 
2.桂林理工大学有色金属及材料加工新技术教育部重点实验室 桂林 541004
The Structure and Electrochemical Performance of α/β Mutually Embedded Nickel Hydroxide
LI Yanwei 1,2, LI Yuexiao1,YAO Jinhuan1,LIU Changjiu1,2,ZHU Wenfeng2
1. College of Chemistry and Bioengineering, Guilin University of Technology, Guilin 541004
2. Key Laboratory of New Processing Technology for Nonferrous Metals and Materials of Ministry of Education, Guilin University of Technology, Guilin 541004
引用本文:

李延伟 李月晓 姚金环 刘长久 朱文凤. α/β互嵌氢氧化镍电极活性材料的结构和电化学性能[J]. 材料研究学报, 2011, 25(1): 51-56.
, , , . The Structure and Electrochemical Performance of α/β Mutually Embedded Nickel Hydroxide[J]. Chin J Mater Res, 2011, 25(1): 51-56.

全文: PDF(1125 KB)  
摘要: 采用化学共沉淀法制备了具有α相和β相相互嵌套结构的氢氧化镍。用X--射线衍射(XRD), 傅里叶变换红外光谱(FT--IR)和扫描电子显微镜(SEM)分析了样品的微观结构和表面形貌。用循环伏安(CV)、交流阻抗(EIS)和充放电测试表征了样品的电化学性能。结果表明, 与纯β相氢氧化镍相比, α/β互嵌结构的氢氧化镍具有更高的电化学反应活性、更低的电化学反应阻抗和更高的放电比容量和放电电压。同时, α/β互嵌结构氢氧化镍还具有较好的循环性能。
关键词 无机非金属材料  氢氧化镍  电极活性材料  微观结构  电化学性能    
Abstract:α/β mutually embedded nickel hydroxide has been synthesized by chemical coprecipitation method. The microstructure and surface morphology of the prepared samples were analyzed by X–ray diffraction (XRD), Fourier transform infrared (FTIR), and scanning electron microscopy (SEM). The electrochemical performance of the prepared sample was characterized by cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and charge discharge tests. Compared to the pure β nickel hydroxide, the α/β mutually embedded nickel hydroxide shows a higher electrochemical reaction activity, lower electrochemical reaction impedance, higher discharge capacity, and higher discharge voltage. Moreover, α/β mutually embedded nickel hydroxide has better cyclic performance.
Key wordsinorganic non–metallic materials    nickel hydroxide    electrode active material     microstructure    electrochemical performance
收稿日期: 2010-10-08     
ZTFLH: 

TB321

 
基金资助:

国家自然科学基金20563001、中国博士后科学基金20090450188和广西自然科学基金0991247资助项目。

1 XIAO Huiming, WANG Jianming, CHEN Hui, PAN Tao, ZHANG Jianqing, Synthesis of Al–substituted alpha–nickel hydroxide in organic solvent and its electrochemical performance, Functional Materials, 34(5), 553(2003)

(肖慧明, 王建明, 陈惠, 潘滔, 张鉴清, Al取代α--Ni(OH)2的有机溶剂法合成及其电化学性能, 功能材料,  34(5), 553(2003))

2 WU Yuping, ZHANG Hanping, WU Feng, ZHANG Peng, GUAN Shiyou, Green Power Material (first edition), (Beijing, Chemical Industry Press, 2008) p.136

(吴宇平, 张汉平, 吴锋, 张鹏, 关士友, 绿色电源材料(第一版) (北京, 化学工业出版社, 2008) p.136)

3 ZHAI Haijun, WANG Xianyou, YANG Hongping, LI Jingming, Studies on the electrode characteristics of metal substituted α–Ni(OH)2, Chinese Journal of Power Source, 27, 197(2005)

(翟海军, 王先友, 杨红平, 李晶明, 掺杂α--Ni(OH)2 的电极性能研究, 电源技术,  27, 197(2005))

4 LIU Yuangang, TANG Zhiyuan, XU Qiang, ZHANG Xiaoyang, LIU Yong, Research development and prospect of α–Ni(OH)2, Progress in Chemisty, 18(7/8), 833(2006)

(刘元刚, 唐致远, 徐强, 张晓阳, 柳 勇, α--Ni(OH)2的研究进展, 化学进展,  18(7/8), 833(2006))

5 ZHANG Qian, XU Yanhui, WANG Xiaolin, HE Guorong, LIN Kezhi, Preparation of Al–doped α–Ni(OH)2 by homogeneous precipitation and its electrochemical performance, Rare Metal Materials and Engineering, 33(12), 1291(2004)

(张倩, 徐艳辉, 王晓琳, 何国荣, 林克芝, 均相沉淀法制备α--Ni(OH)2及其电化学性能研究, 稀有金属材料与工程,  33(12), 291(2004))

6 R.S.Jayashree, K.P.Vishnu, Factors governing the electrochemical synhesis of α–nickel (II) hydroxide, Journal of Applied Electrochemistry, 29(4), 449(1999)

7 S.Akiko, I.Shintaro, H.Kenzo, Preparation and characterization of Ni/Al–layered double hydroxide, Journal of The Electrochemical Society, 146(4), 1251(1999)

8 ZHANG Hongbing, PU Tan, LI Daohuo, Research on nanostructure Al3+, Zn2+ instituted Ni(OH)2 electrode materials, Journal of Power Source, 28(5), 276(2003)

(张红兵, 浦坦, 李道火, Al3+, Zn2+替代镍离子的纳米氢氧化镍电极材料, 电源技术,  28(5), 276(2003))

9 C.Nethravathi, N.Ravishankar, C.Shivakumara, M.Rajamathi, Nanocomposites of α–hydroxides of nickel and cobalt by delamination and co–stacking: Enhanced stability of α–motifs in alkaline medium and electrochemical behaviour, Journal of Power Sources, 172(2), 970(2007)

10 A.B.B´el´ek´e, M.Mizuhata, Electrochemical properties of nickel | aluminum layered double hydroxide/carbon composite fabricated by liquid phase deposition, Journal of Power Sources, 22(195), 7669(2010)

11 J.Qi, P.Xu, Z.Lv, X.Liu, A.Wen, Effect of crystallinity on the electrochemical performance of nanometer Al–stabilizedα–nickel hydroxide, Journal of Alloys and Compounds, 462(1/2), 164(2008)

12 M.E.P´erez–Bernal, R.J.Ruano–Casero, F.Benitoa, V.Rives, Nickel | aluminum layered double hydroxides prepared via inverse micelles formation, Solid State Chemistry, 182(6), 1593(2009)

13 H.Wang, Z.Tang, Y.Liu, H.Lee, Synthesis and behavior of Al–stabilized α–Ni(OH)2, Transactions of Nonferrous Metals Society of China, 19(1), 170(2009)

14 X.Kong, X.Liu, Y.He, D.Zhang, X.Wang, Y.Li, Hydrothermal synthesis of β–nickel hydroxide microspheres with flakelike nanostructures and their electrochemical properties, Materials Chemistry and Physics, 106(2/3), 375(2007)

15 Q.Jiao, Z.Tian, Y.Zhao, Preparation of nickel hydroxide nanorods/nanotubes and microscopic nanorings under hydrothermal conditions, Journal of Nanoparticle Research, 9(3), 519(2007)

16 R.S.Jayashree, P.V.Kamath, Layered double hydroxide of Ni with Cr and Mn as candidate electrode materials for alkaline secondary cells, Journal of Power Sources, 107(1), 120(2003)

17 T.Pan, J.M.Wang, Y.L.Zhao, H.Chen, H.M.Xiao, J.Q.Zhang, Al–stabilized α–nickel hydroxide prepared by electrochemical impregnation, Materials Chemistry and Physics, 78(3), 711(2003)

18 ZHANG Qian, XU Yanhui, WANG Xiaolin, The preparation and electrochemical performance of α–Ni(OH)2 with different Al contents, Rare Metal Materials and Engineering, 35(5), 690(2006)

(张倩, 徐艳辉, 王晓琳, 不同Al含量α--Ni(OH)2 的制备及电化学性能研究, 稀有金属材料与工程,  35(5), 690(2006))

19 H.Zhang, H.Liu, X.Cao, S.S.Li, C.Sun, Preparation and properties of the aluminum–substituted α–Ni(OH)2, Materials Chemistry and Physics, 79(1), 37(2003)

20 ZHANG Qian,XU Yanhui, WANG Xiaolin, The structure and electrochemical performance of Al–doped α–Ni(OH)2, Rare Metal Materials and Engineering, 32(10), 825(2003)

(张倩, 徐艳辉, 王晓琳, Al代α--Ni(OH)2的结构与电化学性能, 稀有金属材料与工程,  32(10), 825(2003))

21 L.J.Yang, X.P.Gao, Q.D.Wu, H.Y.Zhu, and G.L.Pan, Phase distribution and electrochemical properties of Al–substituted nickel hydroxides, The Journal of Physical Chemistry C, 111(12), 4614(2007)

22 ZHANG Wenkui, HUANG Na, HUANG Hui, GAN Yongping, Preparation of flaky α–Ni(OH)2 by coprecipitation method, The Chinese Journal of Nonferrous Metals, 17(1), 166(2007)

(张文魁, 黄娜, 黄辉, 甘永平, 均匀沉淀法制备片状结构a--Ni(OH)2, 中国有色金属学报, 17(1), 166(2007))

23 B.Liu, H.Yuan, Y.Zhang, Impedance of Al–substituted α–nickel hydroxide electrodes, International Journal of Hydrogen Energy, 29(5), 453(2004)

24 H.Li, J.Ma, Molecular dynamics modeling of the structure andbinding energies of a–nickel hydroxides and nickel–aluminum layered double hydroxides containing various interlayer guest anions, Chemistry of Materials, 18, 4405(2006)

25 Y.W.Li, J.H.Yao, C.J.Liu, W.M.Zhao, W.X.Deng, S.K.Zhong, Effect of interlayer anions on the electrochemical performance of Al–substituted α–type nickel hydroxide electrodes, International Journal of Hydrogen Energy, 35(6), 2539(2010)
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