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材料研究学报  2005, Vol. 19 Issue (3): 279-286    
  论文 本期目录 | 过刊浏览 |
新型含偶氮苯生色团聚合物的制备和性能
朱红平1;吴水珠1;佘卫龙2;罗锻斌2
1.华南理工大学2.中山大学光电材料与技术国家重点实验室
引用本文:

朱红平; 吴水珠; 佘卫龙; 罗锻斌 . 新型含偶氮苯生色团聚合物的制备和性能[J]. 材料研究学报, 2005, 19(3): 279-286.

全文: PDF(548 KB)  
摘要: 合成了含手性碳原子的新型偶氮苯生色团, 通过酰氯化反应制备出含偶氮苯生色团的单体, 将所合成的单体与丙烯酸酯类单体进行自由基共聚得到以偶氮苯生色团为侧基的高分子. 利用1H NMR、FTIR、UV-Vis吸收光谱, 对所合成的单体及聚合物进行了结构表征. 研究了所制备的聚合物的全光开关效应. 结果表明, 在激发光的照射下, 通过聚合物中偶氮苯基团的顺-反-顺异构循环在聚合物材料中可形成光致各向异性; 在较低驱动光功率(28.1mW)下这种聚合物具有良好的全光开关效应.
关键词 有机高分子材料偶氮苯生色团全光开关效    
Key words
收稿日期: 1900-01-01     
1 Yuntian Theodore Zhu,Terry C.Lowe,Observations and issues on mechanisms of grain refinement during ECAP process,Materials Science and Engineering A,291, 46(2000)
2 Zenji Horita,Takayoshi Fujinami,Terence G.Langdon, The potential for scaling ECAP-Effect of sample size on grain refinement and mechanical properties,Materials Sci- ence and Engineering A,318,34(2001)
3 V.V.Stolyarov,Y.T.Zhu,T.C.Lowe,R.K.Islamgaliev and R.Z.Valiev,Two step SPD processing of ultrafine-grained titanium,Nanostructured Materials,11,947(1999)
4 Dong Hyuk Shin,Kyung-Tae Park,Ultrafine grained steels processed by equal channel angular pressing,Ma- terials Science and Engineering A,410-411,299(2005)
5 Y.Saito,N.Tsuji,H.Utsunomiya,T.Sakai,R.G.Hong, Ultra-fine grained bulk aluminum produced by accumula- tive roll-bonding(ARB)process,Scripta Materialia,39, 1221(1998)
6 N.Tsuji,Y.Saito,H.Utsunomiya,S.Tanigawa,Ultra-fine grained bulk steel produced by accumulative roll-bonding (ARB)process,Scripta Materialia,40,795(1999)
7 N.Tsuji,R.Ueji,Y.Minamino,Y.Saito,A new and simple process to obtain nano-structured bulk low-carbon steel with superior mechanical property,Scripta Materialia,46, 305(2002)
8 R.Ueji,N.Tsuji,Y.Minamino,Y.Koizumi,Ultragrain re- finement of plain low carbon steel by cold-rolling and an- nealing of martensite,Acta Mater.,50,4177(2002)
9 Rintaro Ueji,Nobuhiro Tsuji,Yoritoshi Minamino, Yuichiro Koizumi,Effect of rolling reduction on ultrafine grained structure and mechanical properties of low-carbon steel thermomechanically processed from martensite start- ing structure,Science and Technology of Advanced Mate- rials,5,153(2004)
10 X.Zhao,T.F.Jing,Y.W.Gao,J.F.Zhou,W.Wang,Anneal- ing behavior of nano-layered steel produced by heavy cold-rolling of lath martensite,Materials Science and En- gineering A,397,117-121(2005)
11 S.Morito,H.Tanaka,R.Konishi,T.Furuhara,T.Maki,The morphology and crystallography of lath martensite in Fe- Calloys,Acta Materialia,51,1790(2003)
12 Hiromoto Kitahara,Rintaro Ueji,Nobuhiro Tsuji,Yori- toshi Minamino,Crystallographic features of lath marten- site in low-carbon steel,Acta Materialia,54,1282- 1283(2006)
13 D.Kuhlmann-Wilsdorf,Niels Hansen,Geometrically nec- essary,incidental and subgrain boundaries,Scripta Met- allurgica & Materialia,25,1557-1559(1991)
14 N.Tsuji,R.Ueji,Y.Saito,Y.Koizumi,Y.Minamino,A novel process to obtain nanostructured low-carbon bulk steel with high strength,in:Proc.of the 21st RISΦInt.Symp on Materials Science,edited by A.R.Dinesen M.Eldrup(RISΦNational Laboratory,Roskilde,2001) p.607-616
15 Rolf Sandstrom,On recovery of dislocations in subgrains and subgrain coalescene,Acta Metallurgica,25,897- 904(1997)
16 J.W.Christian,The Theory of Transformations in Metals and Alloys,third edition(Netherlands,Pergamon,2002) p.836
17 A.Belyakov,T.Sakai,H.Miura,R.Kaibyshev,K.Tsuzaki, Continuous recrystallization in austenitic stainless steel af- ter large strain deformation,Acta Mater.,50,1547(2002)
18 R.K.Davies,V.Randle,G.J.Marshall,Continuous recrystallization-related phenomena in a commercial Al-Fe-Si alloy,Acta Mater.,46,6021(1998)
19 T.Maki,Dynamic recrystallization and grain refinement of V various steels,in:The 3rd International Conference on Advanced Structural Steels(Gyeongju,2006)p.73
20 C.Zener,quoted by C.S.Smith,Grains,phases and inter- faces:An interpretation of microstructure,Trans-AIME, 175,15(1948)D
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