菇娘果外皮衍生多孔碳的制备及其应用

doi:10.11901/1005.3093.2024.448

材料研究学报

2025, Vol. 39

Issue (10): 755-764 DOI: 10.11901/1005.3093.2024.448

研究论文

本期目录 | 过刊浏览

菇娘果外皮衍生多孔碳的制备及其应用

王园园(

), 夏莹京, 董省身, 王雪芹, 柳艳修, 宋华, 刘社田(

)

东北石油大学化学化工学院大庆 163318

Preparation and Performance of Porous Carbon Materials Derived from Physalis Peruviana L. Calyx Husk

WANG Yuanyuan(

), XIA Yingjing, DONG Xingshen, WANG Xueqin, LIU Yanxiu, SONG Hua, LIU Shetian(

)

College of Chemistry and Chemical Engineering, Northeast Petroleum University, Daqing 163318, China

引用本文:

王园园, 夏莹京, 董省身, 王雪芹, 柳艳修, 宋华, 刘社田. 菇娘果外皮衍生多孔碳的制备及其应用[J]. 材料研究学报, 2025, 39(10): 755-764.
Yuanyuan WANG, Yingjing XIA, Xingshen DONG, Xueqin WANG, Yanxiu LIU, Hua SONG, Shetian LIU. Preparation and Performance of Porous Carbon Materials Derived from Physalis Peruviana L. Calyx Husk[J]. Chinese Journal of Materials Research, 2025, 39(10): 755-764.

全文: PDF(9808 KB) HTML

摘要:

将菇娘果外皮(PLC)在400 ℃预碳化后用不同浓度的KOH溶液(活化剂)活化，制备出电极材料PLCPC-x (x为KOH与预碳化材料的质量比)。使用扫描电子显微镜(SEM)、透射电镜(TEM)、比表面积分析仪、X射线衍射仪(XRD)、Raman光谱仪、能谱仪(EDS)以及X射线光电子能谱仪(XPS)等手段对其表征，研究了活化剂的添加量对PLCPC-x材料的形貌、孔道结构以及电化学性能的影响。结果表明，PLCPC-3具有发达的多孔级3D孔道结构，其比表面积高达2703.75 m²·g^-1。在三电极体系中，电流密度为0.5 A·g^-1时PLCPC-3的质量比电容为349.7 F·g^-1 (6 mol·L^-1 KOH)，电流密度为20 A·g^-1时电容保持率为78.9%。在两电极体系中构建的对称超级电容器(PLCPC-3//PLCPC-3)功率密度为250 W·kg^-1时能量密度约为9.0 Wh·kg^-1。经历12000次循环后，其比电容为初始值的96.7%。

关键词 ：复合材料, 超级电容器, 多孔碳材料, 电化学性能

Abstract：

The calyx husk of Physalis Peruviana L. was firstly pre-carburized at 400 ^oC to acquire carbon, and then porous carbon materials PLCPC-x (the ratio x represents the mass ratio of KOH to the pre-carbonized material) were prepared with the pre-carburized calyx husk as raw material and KOH solution as activating agent. The results showed that PLCPC-3 possessed a well-developed hierarchical 3D porous structure and a high specific surface area of up to 2703.75 m²·g^-¹. By means of testing in a three-electrode set with electrolyte of 6 mol·L^-1 KOH solution, it exhibited a high specific capacitance of 349.7 F·g^-1 at 0.5 A·g^-1 and a high capacitance retention rate of 78.9% at 20 A·g^-¹. In a two-electrode system, the constructed symmetric supercapacitor achieved an energy density of approximately 9.0 Wh·kg^-1 at a power density of 250 W·kg^-1, retaining 96.7% of its initial capacitance after 12000 cycles.

Key words： composite supercapacitor porous carbon material electrochemical performance

收稿日期: 2024-11-05

ZTFLH:

TB332

基金资助:国家自然科学基金(22278068)

通讯作者: 王园园，教授，wangyuanyuan2016@126.com，研究方向为电化学储能及器件
刘社田，教授，Shetian_liu@nepu.edu.cn，研究方向为环境污染物资源化处理

Corresponding author: WANG Yuanyuan, Tel: (0459)6504035, E-mail: wangyuanyuan2016@126.com
LIU Shetian, Tel: (0459)6503167, E-mail: Shetian_liu@nepu.edu.cn

作者简介: 王园园，女，1983年生，博士

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https://www.cjmr.org/CN/10.11901/1005.3093.2024.448 或 https://www.cjmr.org/CN/Y2025/V39/I10/755

图1 制备PLCPC-x衍生多孔碳材料的示意图

图2 PLCPC-x的SEM照片和EDS图

图3 PLCPC-3的TEM照片

图4 PLCPC-x的N2吸附/解吸等温曲线和孔径分布曲线

表1 PLCPC-x的比表面积与孔隙参数

图5 PLCPC-x的XRD谱和Raman谱

图6 PLCPC-3的XPS总谱以及C 1s和O 1s的高分辨XPS谱

图7 PLCPC-x 在扫描速率为50 mV·s-1时的CV曲线、电流密度为0.5 A·g-1时的GCD曲线以及在不同电流密度下的比电容、PLCPC-3 在不同扫描速率下的CV曲线和在不同电流密度下的GCD曲线、PLCPC-x的Nyquist图和Bode图、PLCPC-0和PLCPC-3在50 mV·s-1扫描速率下的总电荷存储的组成，以及在不同扫描速率下总电荷存储的组成

图8 PLCPC-3//PLCPC-3在6 mol·L-1 KOH电解质溶液中的电化学性能

表2 部分碳材料的电化学性能[45~52]

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