有机<strong>-</strong>无机杂化改性磷酸盐<strong>/</strong>石墨润滑涂层的高温摩擦学性能

doi:10.11901/1005.3093.2024.437

材料研究学报

2025, Vol. 39

Issue (9): 661-672 DOI: 10.11901/1005.3093.2024.437

研究论文

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有机-无机杂化改性磷酸盐/石墨润滑涂层的高温摩擦学性能

张若云¹, 王伟¹(

), 宫鹏辉², 丁士杰¹, 刘显昊¹, 孙壮¹, 吕凡凡¹, 高原¹, 王快社¹

^1.西安建筑科技大学冶金工程学院西安 710055
^2.西安建筑科技大学机电工程学院西安 710055

High-temperature Tribological Performance of Organic-inorganic Hybrid Modified Phosphate/Graphite Lubricating Coatings

ZHANG Ruoyun¹, WANG Wei¹(

), GONG Penghui², DING Shijie¹, LIU Xianhao¹, SUN Zhuang¹, LV Fanfan¹, GAO Yuan¹, WANG Kuaishe¹

^1.School of Metallurgical Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, China
^2.School of Mechanical and Electrical Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, China

引用本文:

张若云, 王伟, 宫鹏辉, 丁士杰, 刘显昊, 孙壮, 吕凡凡, 高原, 王快社. 有机-无机杂化改性磷酸盐/石墨润滑涂层的高温摩擦学性能[J]. 材料研究学报, 2025, 39(9): 661-672.
Ruoyun ZHANG, Wei WANG, Penghui GONG, Shijie DING, Xianhao LIU, Zhuang SUN, Fanfan LV, Yuan GAO, Kuaishe WANG. High-temperature Tribological Performance of Organic-inorganic Hybrid Modified Phosphate/Graphite Lubricating Coatings[J]. Chinese Journal of Materials Research, 2025, 39(9): 661-672.

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摘要:

用有机-无机原位杂化将磷酸二氢铝(AP)改性，再以AP和杂化AP为粘结剂在TA1纯钛表面制备了石墨基粘结润滑涂层。使用红外光谱仪、X射线光电子能谱仪和X射线衍射仪等手段表征杂化AP粘结剂的结构和性能，用扫描电子显微镜和三维白光轮廓干涉仪表征固体润滑涂层的磨损表面，并用多功能摩擦磨损实验机测试了不同涂层的高温(700~900 ℃)摩擦学性能。结果表明，AP与苯基三甲氧基硅烷(PTMS)杂化生成了以P-O-Si为骨架的化学结构。PTMS含量为10%的杂化AP涂层其高温润滑性能最佳，温度为850 ℃的摩擦系数(0.1219)和磨损率(0.57 × 10^-3 mm³·N^-1·m^-1)比杂化前分别降低了77%和82%。在杂化AP粘结剂中生成的网状物质提高了层状石墨的粘结固体润滑涂层的高温摩擦学性能。同时，网状物质填充涂层内部的孔洞和裂纹使涂层的磨损率降低。

关键词 ：复合材料, 石墨, 高温固体润滑涂层, 摩擦性能, 润滑机制

Abstract：

The phosphoric acid dihydrogen aluminum (AP) was modified by in situ organic-inorganic hybridization technique, and then the graphite-based lubrication coatings were applied on TA1 pure titanium surfaces by taking AP and hybridized AP as binding agent respectively. The prepared hybridized AP was characterized by means of infrared spectroscopy, X-ray photoelectron spectroscopy, and X-ray diffraction. The high-temperature tribological performance of different coatings was assessed via RTEC MFT-5000 multifunctional friction and wear tester at 700 ^oC to 900 ^oC, which then were characterized by means of scanning electron microscopy and three-dimensional white light contour interferometry. The results indicated that AP was successfully hybridized with phenyltrimethoxysilane (PTMS), forming a chemical structure with P-O-Si as the skeleton. The coating with hybridized AP exhibited optimal lubrication performance at high temperatures when the PTMS content was 10%. Specifically, by tribological test at 850 ^oC, the coating with hybridized AP presented coefficient of friction 0.1219 and wear rate 0.57 × 10^-3 mm³·N^-1·m^-1, which were reduced by 77% and 82%, respectively, compared to those with simple AP. It follows that the reticulated material generated in the hybridized AP binder can enhanced the high-temperature tribological properties of the lubricated coatings containing laminated graphite. Furthermore, this reticulated material can fill the holes and cracks within the coating, thereby reducing the wear rate and improving wear resistance of coatings.

Key words： composite graphite high-temperature solid lubricant coating tribological properties lubrication mechanism

收稿日期: 2024-10-25

ZTFLH:

TB332

基金资助:国家自然科学基金(51975450);陕西省科技新星基金(2021KJXX-32);西安市创新能力强基计划-先进制造技术攻关项目(21XJZZ0031);陕西省教育厅服务地方专项(22JC047);国家自然科学基金(52305438);陕西省重点研发计划项目(2023-YBGY-383);陕西省重点研发计划项目(2023GXLH-063)

通讯作者: 王伟，教授，gackmol@163.com，研究方向为材料加工中的摩擦与润滑

Corresponding author: WANG Wei, Tel: 13609264618, E-mail: gackmol@163.com

作者简介: 张若云，女，2000年生，硕士

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	张若云
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	丁士杰
	刘显昊
	孙壮
	吕凡凡
	高原
	王快社
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https://www.cjmr.org/CN/10.11901/1005.3093.2024.437 或 https://www.cjmr.org/CN/Y2025/V39/I9/661

图1 涂层制备过程的示意图

图2 杂化AP粘结剂的化学结构和杂化合成路径

图3 AP涂层和杂化AP涂层在不同温度下的SEM图像

表1 涂层表面点扫描原子质量比

图4 AP粘结涂层在不同温度下的摩擦曲线、平均摩擦系数和磨损率

图5 在不同温度下TA1盘AP粘结涂层磨痕表面的磨损轨道、三维轮廓图以及二维高度轮廓曲线

图6 AP涂层TA1盘磨痕、磨屑表面在850 ℃下的SEM和EDS照片

图7 不同含量PTMS的涂层在800 ℃下的摩擦曲线、平均摩擦系数和磨损率

图8 10%杂化AP作为粘结剂在不同温度下的摩擦曲线、平均摩擦系数和磨损率

图9 在不同温度下10%杂化AP粘结涂层TA1盘磨痕表面的磨损轨道、三维轮廓图以及二维高度轮廓曲线

图10 在不同温度下10%杂化AP粘结涂层Si3N4小球的磨损轨道、三维轮廓图像和对应的二维高度轮廓曲线

图11 在850 °C下10%杂化AP粘结涂层TA1盘磨痕处的SEM和EDS照片

图12 10%杂化AP粘结涂层在850和900 ℃的XRD谱

图13 10%杂化AP粘结涂层在850 °C的TA1盘磨痕处XPS谱

图14 有机-无机杂化AP粘结剂的润滑机理

[1]	Zhen Y, Chen M H, Yu C T, et al. High temperature self-lubricating Ti-Mo-Ag composites with exceptional high mechanical strength and wear resistance [J]. J. Mater. Sci. Technol., 2024, 180: 80 doi: 10.1016/j.jmst.2023.09.012
[2]	Zhao S T, Zhang R P, Yu Q, et al. Cryoforged nanotwinned titanium with ultrahigh strength and ductility [J]. Science, 2021, 373(6561): 1363 doi: 10.1126/science.abe7252 pmid: 34529490
[3]	Pollock T M. Alloy design for aircraft engines [J]. Nat. Mater., 2016, 15(8): 809 doi: 10.1038/nmat4709 pmid: 27443900
[4]	Li L X, Rao K P, Lou Y, et al. A study on hot extrusion of Ti-6Al-4V using simulations and experiments [J]. Int. J. Mech. Sci., 2002, 44(12): 2415
[5]	Reeves C J, Menezes P L, Lovell M R, et al. Tribology of solid lubricants [A]. MenezesP L, NosonovskyM, IngoleS P, et al. Tribology for Scientists and Engineers: from Basics to Advanced Concepts [M]. New York: Springer, 2013: 447
[6]	Wan H Q, Jia Y L, Ye Y P, et al. Tribological behavior of polyimide/epoxy resin-polytetrafluoroethylene bonded solid lubricant coatings filled with in situ-synthesized silver nanoparticles [J]. Prog. Org. Coat., 2017, 106: 111
[7]	Gong H J, Yu C C, Zhang L, et al. Intelligent lubricating materials: A review [J]. Composites, 2020, 202B: 108450
[8]	Liu Y F, Ge X Y, Li J J. Graphene lubrication [J]. Appl. Mater. Today, 2020, 20: 100662
[9]	Bian J J, Nicola L. On the lubrication of rough copper surfaces with graphene [J]. Tribol. Int., 2021, 156: 106837
[10]	Watanabe S, Miyake S, Murakawa M. Tribological properties of cubic, amorphous and hexagonal boron nitride films [J]. Surf. Coat. Technol., 1991, 49(1-3): 406
[11]	Zhang G L, Liu Y, Guo F, et al. Friction characteristics of impregnated and non-impregnated graphite against cemented carbide under water lubrication [J]. J. Mater. Sci. Technol., 2017, 10(33): 1203
[12]	Berman D, Erdemir A, Sumant A V. Graphene: A new emerging lubricant [J]. Mater. Today, 2014, 17(1): 31
[13]	Holmberg K, Andersson P, Erdemir A. Global energy consumption due to friction in passenger cars [J]. Tribol. Int., 2012, 47: 221
[14]	Berman D, Erdemir A, Sumant A V. Few layer graphene to reduce wear and friction on sliding steel surfaces [J]. Carbon, 2013, 54: 454
[15]	Bhowmick S, Banerji A, Alpas A T. Role of humidity in reducing sliding friction of multilayered graphene [J]. Carbon, 2015, 87: 374
[16]	Allam I M. Solid lubricants for applications at elevated temperatures [J]. J. Mater. Sci., 1991, 26: 3977
[17]	Cheng H, Gao S Y, Duan D L, et al. Study on the tribological behavior and the interaction between friction and oxidation of graphite reinforced by impregnated phosphate at high temperatures [J]. Materials (Basel), 2023, 16(9): 3517
[18]	Huai W J, Zhang C H, Wen S Z. Graphite-based solid lubricant for high-temperature lubrication [J]. Friction, 2021, 9(6): 1660
[19]	Jia Y L, Chen L, Feng X Z, et al. Tribological behavior of molybdenum disulfide bonded solid lubricating coatings cured with organosiloxane-modified phosphate binder [J]. RSC Adv., 2015, 5: 69606
[20]	Li Y Z, Chen G C, Zhu S Z, et al. Preparation of an aluminium phosphate binder and its influence on the bonding strength of coating [J]. Bull. Mater. Sci., 2019, 42: 200
[21]	Huang H W, Wang H H, Xie Y H, et al. Incorporation of boron nitride nanosheets in zinc phosphate coatings on mild steel to enhance corrosion resistance [J]. Surf. Coat. Technol., 2019, 374: 935
[22]	Vippola M, Ahmaniemi S, Keränen J, et al. Aluminum phosphate sealed alumina coating: characterization of microstructure [J]. Mat. Sci. Eng., 2002, 323A(1-2) : 1
[23]	Chen Z Y, Gudo X P, Zhang L Q, et al. Anticorrosion mechanism of Al-modified phosphate ceramic coating in the high-temperature marine atmosphere [J]. Surf. Coat. Technol., 2022, 441: 128572
[24]	Madhusudhana A M, Mohana K N. Synthesis of self-healing inhibitor releasing nanocapsules blended phenol novolac resin for high performance anticorrosion coating [J]. Colloid Surf., 2022, 643A: 128762
[25]	Yang J, Chen J R, Song J H. Studies of the surface wettability and hydrothermal stability of methyl-modified silica films by FT-IR and Raman spectra [J]. Vib. Spectrosc., 2009, 50: 178
[26]	Massiot P, Centeno M A, Carrizosa I, et al. Thermal evolution of sol-gel-obtained phosphosilicate solids (SiPO) [J]. J. Non-Cryst. Solids, 2001, 292: 158
[27]	Yin J, Wu H B, Shu X D. Shape-property synergistic control in closed die forging of large-diameter copper alloy valve body [J]. Int. J. Adv. Manuf. Technol., 2023, 128(5): 2137
[28]	Wang W, Peng Y Q, Ding S J, et al. Tribological properties of graphite-based solid lubricating coatings for Ti-6Al-4V alloy at 500~800 ^oC [J]. Chin. J. Mater. Res., 2023, 37(6): 432
[28]	王伟, 彭怡晴, 丁士杰等. Ti-6Al-4V合金表面石墨基粘结固体润滑涂层的高温摩擦学性能 [J]. 材料研究学报, 2023, 37(6): 432
[29]	Fan K, Chen X Y, Wang X, et al. Toward excellent tribological performance as oil-based lubricant additive: particular tribological behavior of fluorinated graphene [J]. ACS Appl. Mater. Interfaces, 2018, 10(34): 28828
[30]	Mo Y H, Pang L Y, Liu Q L, et al. Preparation and performance characterization of modified phosphate adhesives [J]. Mater. Rep., 2023, 37(14): 54
[30]	默玉海, 庞凌燕, 刘千龙等. 改性磷酸盐胶黏剂的制备及性能表征 [J]. 材料导报, 2023, 37(14): 54
[31]	Yan H, Fan X Q, Cai M, et al. Amino-functionalized Ti₃C₂T _x loading ZIF-8 nanocontainer@ benzotriazole as multifunctional composite filler towards self-healing epoxy coating [J]. J. Colloid Interface Sci., 2021, 602: 131

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