碳纳米管膜表面金属化用于高电流输出柔性锂离子电池

doi:10.11901/1005.3093.2021.110

材料研究学报

2022, Vol. 36

Issue (5): 373-380 DOI: 10.11901/1005.3093.2021.110

研究论文

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碳纳米管膜表面金属化用于高电流输出柔性锂离子电池

赵超锋, 郑小燕, 李凯瑞, 贾世奎, 张明, 黎业生(

), 吴子平

江西理工大学材料冶金化学学部赣州 341000

Surface Metallization of Carbon Nanotube Film for Flexible Lithium-ion Batteries with High Output Current

ZHAO Chaofeng, ZHENG Xiaoyan, LI Kairui, JIA Shikui, ZHANG Ming, LI Yesheng(

), WU Ziping

Faculty of Materials Metallurgy and Chemistry, Jiangxi University of Science and Technology, Ganzhou 341000, China

引用本文:

赵超锋, 郑小燕, 李凯瑞, 贾世奎, 张明, 黎业生, 吴子平. 碳纳米管膜表面金属化用于高电流输出柔性锂离子电池[J]. 材料研究学报, 2022, 36(5): 373-380.
Chaofeng ZHAO, Xiaoyan ZHENG, Kairui LI, Shikui JIA, Ming ZHANG, Yesheng LI, Ziping WU. Surface Metallization of Carbon Nanotube Film for Flexible Lithium-ion Batteries with High Output Current[J]. Chinese Journal of Materials Research, 2022, 36(5): 373-380.

全文: PDF(13155 KB) HTML

摘要:

采用磁控溅射技术对碳纳米管膜进行表面金属化处理,制备了导电性能优异的碳纳米管/金属复合薄膜,其电导率为纯碳纳米管膜的10倍(碳纳米管膜电导率为300 S·cm^-1)。以这种复合薄膜为集流体组装的柔性锂离子电池,具有比以纯碳纳米管膜作为集流体更优异的倍率性能(5 C倍率下比容量仍可保持132.6 mAh·g^-1)、大倍率循环性能(5 C倍率200圈循环后仍具有74.4%的容量保持率)和更大的输出电流(0.4 A)。

关键词 ：复合材料, 柔性锂离子电池, 高输出电流, 表面金属化, 碳纳米管

Abstract：

The CNTs/metal composite film with excellent electrical conductivity was prepared by magnetron sputtering technique. the electrical conductivity of the CNTs/metal composite film can reach 10 times than that of the as-prepared CNT macrofilm (CMF, 300 S·cm^-1). In addition, a flexible LIBs with this film as the current collector was prepared, which, in comparison with the flexible LIBs with the simple CNTs film, presents higher rate capability. Moreover, its specific capacity can still be maintained at 132.6 mAh·g^-1 at a rate of 5 C, high-rate cycling performance i.e. 74.4% capacity retention rate after 200 cycles at 5 C rate, and larger output current up to 0.4 A.

Key words： composite flexible lithium-ion batteries high output current surface metallization carbon nanotube

收稿日期: 2021-01-22

ZTFLH:

TQ131

基金资助:国家自然科学基金(51861009);江西省教育厅科技重点项目(GJJ160596)

作者简介: 赵超锋,男,1995年生,硕士生

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https://www.cjmr.org/CN/10.11901/1005.3093.2021.110 或 https://www.cjmr.org/CN/Y2022/V36/I5/373

图1 制备CMF@Al复合薄膜的示意图、CMF和CMF@Al复合薄膜的宏观形貌、柔性和轻量展示以及结合性测试

图2 CMF@Al复合薄膜和CMF@Cu复合薄膜的表面和断面形貌、基于CMF@Al复合薄膜的正极极片和基于Al箔的正极极片的断面形貌、CMF@Al、CMF@Cu复合薄膜的导电性能与镀层厚度的关系以及不同集流体方块电阻

图3 全电池的化成曲线、倍率性能测试、基于复合薄膜的全电池在不同倍率下的放电曲线、基于金属箔的全电池在不同倍率下放电曲线以及5 C倍率下的长循环测试结果

图4 基于CMF@Al-CMF@Cu的软包电池的开路电压和输出电压、输出电流、基于CMF-CMF的软包电池的开路电压和输出电压、输出电流

图5 机理解释图、循环伏安曲线、交流阻抗图谱以及5 C倍率下200圈循环极化曲线

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