Mn对熔融Zn-Mn合金与X80钢润湿行为的影响

doi:10.11901/1005.3093.2020.426

材料研究学报

2021, Vol. 35

Issue (10): 785-794 DOI: 10.11901/1005.3093.2020.426

研究论文

本期目录 | 过刊浏览

Mn对熔融Zn-Mn合金与X80钢润湿行为的影响

彭浩平¹^,²^,³, 席世亨², 崔德荣², 刘亚¹^,³, 邓嵩², 苏旭平¹^,³, 阮睿文²(

)

^1.常州大学江苏省材料表面科学与技术重点实验室常州 213164
^2.常州大学江苏省油气储运技术重点实验室常州 213164
^3.常州大学江苏省光伏科学与工程协同创新中心常州 213164

Effect of Mn on Wetting Behavior of X80 Steel in Molten Zn-Mn Alloy

PENG Haoping¹^,²^,³, XI Shiheng², CUI Derong², LIU Ya¹^,³, DENG Song², SU Xuping¹^,³, RUAN Ruiwen²(

)

^1.Jiangsu Key Laboratory of Material Surface Science and Technology, Changzhou University, Changzhou 213164, China
^2.Jiangsu Key Laboratory of Oil & Gas Storage and Transportation Technology, Changzhou University, Changzhou 213164, China
^3.Jiangsu Collaborative Innovation Center of Photovoltaic Science and Engineering, Changzhou University, Changzhou 213164, China

引用本文:

彭浩平, 席世亨, 崔德荣, 刘亚, 邓嵩, 苏旭平, 阮睿文. Mn对熔融Zn-Mn合金与X80钢润湿行为的影响[J]. 材料研究学报, 2021, 35(10): 785-794.
Haoping PENG, Shiheng XI, Derong CUI, Ya LIU, Song DENG, Xuping SU, Ruiwen RUAN. Effect of Mn on Wetting Behavior of X80 Steel in Molten Zn-Mn Alloy[J]. Chinese Journal of Materials Research, 2021, 35(10): 785-794.

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摘要:

研究了锌液中0.1%~0.5%(质量分数)Mn对X80钢表面润湿行为的影响。采用改良座滴法获得了450℃时Zn-Mn合金的接触角，通过SEM/EDS观察分析样品表面及界面的组织结构，研究了Zn-χMn(χ=0.1~0.5)合金与X80钢基板的润湿行为和界面反应。结果表明：锰元素对锌合金与钢基体间的润湿性反应起到正吸附作用。在450℃时，当熔体中的锰含量为0.1~0.5时，Zn-χMn合金与钢基间的润湿接触角从85°减小到62°。锌合金熔体/X80钢属于反应性润湿体系，生成的界面产物由FeZn₁₀(δ)、FeZn₁₃(ζ)和Fe₃Zn₁₀(Γ)/Fe₅Zn₂₁(Γ₁)相组成，润湿行为受锌合金界面反应影响。在铺展三相线前沿存在前驱膜，前驱膜的出现能够促进润湿。

关键词 ：材料表面与界面, 润湿行为, 热浸镀锌, 接触角

Abstract：

The effect of the addition of Mn in the range of 0.1%~0.5% (mass fraction) in molten Zn-Mn alloys at 450℃on the surface wetting behavior of X80 steel was studied by means of contact angle measurement with an improved sessile drop method and microstructure observation with SEM-EDS in terms especially of the interaction at interface molten Zn-χMn(χ=0.1~0.5) alloys/X80 steel substrate. The results show that Mn can play a positive role in the wettability between the molten Zn alloy and the steel. At 450℃, with the increasing Mn content from 0.1 to 0.5, the wetting contact angle between the molten Zn-χMn alloy and the steel decreases from 85° to 62°. The molten Zn alloy/X80 steel belongs to the reactive wetting system, correspondingly, the interface reaction may result in interface products composed of FeZn₁₀(δ), FeZn₁₃(ζ) and Fe₃Zn₁₀(Γ)/Fe₅Zn₂₁(Γ1) phases. Therefore, the wetting behavior is affected by the interface reaction. There is a precursor film emerged at the front of the three-phase line, which can enhance the wettability of the molten Zn alloy to X80 steel.

Key words： surface and interface in the materials wetting behavior hot dip galvanizing contact angle

收稿日期: 2020-10-14

ZTFLH:

TG178

基金资助:国家自然科学基金(51671037);江苏省高等学校自然科学研究项目(19KJA530001);江苏省研究生科研与实践创新计划项目(KYCX20-2574);江苏高校“青蓝工程”

作者简介: 彭浩平，男，1982年生，博士

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https://www.cjmr.org/CN/10.11901/1005.3093.2020.426 或 https://www.cjmr.org/CN/Y2021/V35/I10/785

表1 X80钢基板化学成分(质量分数，%)

图1 450℃下Zn-Mn合金/X80钢接触角随Mn含量的变化

图2 Zn-xMn合金熔体与X80钢的润湿表面

表2 前驱膜化学成分

图3 不同Zn-xMn合金的前驱膜形貌

图4 Zn-xMn合金/X80钢界面微观结构

表3 图4中标识点处的化学成分

图5 Zn-0.5% Mn(质量分数)/X80钢界面微观结构

图6 润湿铺展各个阶段示意图

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