细粒径SiO<sub>2</sub>基棕榈醇-棕榈酸-月桂酸微胶囊相变调湿材料的制备与性能*

doi:10.11901/1005.3093.2015.599

材料研究学报

2016, Vol. 30

Issue (6): 418-426 DOI: 10.11901/1005.3093.2015.599

研究论文

本期目录 | 过刊浏览

细粒径SiO₂基棕榈醇-棕榈酸-月桂酸微胶囊相变调湿材料的制备与性能*

张浩(

), 黄新杰, 宗志芳, 刘秀玉

安徽工业大学建筑工程学院马鞍山 243032

Preparation and Properties of SiO₂ Based Hexadecanol-Palmitic Acid-Lauric Acid Microencapsulated Phase Change and Humidity Controlling Materials with Fine Particle Size

ZHANG Hao^**(

), HUANG Xinjie, ZONG Zhifang, LIU Xiuyu

School of Civil Engineering and Architecture, Anhui University of Technology, Ma’anshan 243032, China

引用本文:

张浩, 黄新杰, 宗志芳, 刘秀玉. 细粒径SiO₂基棕榈醇-棕榈酸-月桂酸微胶囊相变调湿材料的制备与性能*[J]. 材料研究学报, 2016, 30(6): 418-426.
Hao ZHANG, Xinjie HUANG, Zhifang ZONG, Xiuyu LIU. Preparation and Properties of SiO₂ Based Hexadecanol-Palmitic Acid-Lauric Acid Microencapsulated Phase Change and Humidity Controlling Materials with Fine Particle Size[J]. Chinese Journal of Materials Research, 2016, 30(6): 418-426.

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摘要:

采用硅烷偶联剂, 通过溶胶-凝胶法制备以SiO₂为壁材、棕榈醇-棕榈酸-月桂酸为芯材的细粒径SiO₂基棕榈醇-棕榈酸-月桂酸微胶囊相变调湿材料。采用等温吸放湿法、步冷曲线法、激光粒度分析仪(LPSA)、扫描电子显微镜(SEM)、傅里叶变换红外光谱(FT-IR)和差示扫描量热(DSC)分析表征了SiO₂基棕榈醇-棕榈酸-月桂酸微胶囊相变调湿材料的调湿性能、调温性能、粒度分布、组成结构、表面形貌和热性能。结果表明, 去离子水用量、无水乙醇用量、硅烷偶联剂用量和棕榈醇-棕榈酸-月桂酸用量对SiO₂基棕榈醇-棕榈酸-月桂酸微胶囊相变调湿材料有重要的影响。当去离子水与正硅酸乙酯的物质的量比为9、无水乙醇与正硅酸乙酯的物质的量比为5、棕榈醇-棕榈酸-月桂酸与正硅酸乙酯的物质的量比为0.5和硅烷偶联剂与正硅酸乙酯的物质的量比为0.1时, SiO₂基棕榈醇-棕榈酸-月桂酸微胶囊相变调湿材料呈球形且表面光滑紧凑, 尺寸仅为1680.60~1735.35 nm, 粒径分布均匀, 分散性较好, 具有良好的相变储湿性能。

关键词 ：复合材料, 棕榈醇-棕榈酸-月桂酸, SiO2, 相变调湿, 细粒径, 微胶囊

Abstract：

Microcapsules of phase change- and humidity-controlling material were synthesized by sol-gel method with hexadecanol-palmitic acid-lauric acid as core, SiO₂as shell and silaneas coupling agent. Then their performance of humidity controlling and temperature controlling, particle size distribution, composition and structure, surface morphology and thermal properties were characterized by isothermal sorption method, cooling curve measurement, laser particle analyzer (LPSA), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR) and differential scanning calorimetry (DSC) respectively. The results show that the amount of deionizedwater, absolute alcohol, hexadecanol-palmitic acid-lauric acid and silane coupling agent had great effect on the properties of the prepared phase change- and humidity-controlling materials. The phase change- and humidity-controlling material of good performance as spherical particles with smooth surface, homogeneous size distribution in a range of 1680.60~1735.35 nm and excellent dispersibility may be synthesized by the following optimal processing parameters: the mole ratio of deionized water totetraethyl orthosilicateis 9, the mole ratio of absolute alcohol totetraethyl orthosilicate 5, the mole ratio of hexadecanol-palmitic acid-lauric acid to tetraethyl orthosilicate 0.5, and the mole ratio of silane coupling agent totetraethyl orthosilicate 0.1.

Key words： composite materials hexadecanol-palmitic acid-lauric acid SiO2 phase change and humidity controlling fine particle size microencapsulates

收稿日期: 2015-10-22

ZTFLH:

TU522.1

基金资助:* 国家自然科学基金资助项目51206002

作者简介: 本文联系人: 张浩

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https://www.cjmr.org/CN/10.11901/1005.3093.2015.599 或 https://www.cjmr.org/CN/Y2016/V30/I6/418

表1 SiO2基棕榈醇-棕榈酸-月桂酸微胶囊相变调湿材料的配方

图1 样品1(A), 样品2(B)和样品3(C)的LPSA图

图2 样品4(A), 样品2(B)和样品5(C)的LPSA图

图3 样品6(A), 样品7(B), 样品2(C)和样品8(D)的形貌SEM像

图4 改性SiO2(A), 棕榈醇-棕榈酸-月桂酸(B), 样品9(C), 样品2(D)和样品10(E)的FT-IR图

图5 样品9(A), 样品2(B), 样品10(C)和样品6(D)的平衡含湿量

图6 各试样的步冷曲线

表2 SiO2基棕榈醇-棕榈酸-月桂酸微胶囊相变调湿材料的热性能

表3 样品2的平衡含湿量

图7 样品2的步冷曲线

1	A. Sharma, V. V. Tyagi, C. R. Chen, Review on thermal energy storage with phase change materials and applications, Renewable and Sustainable Energy Reviews, 13(2), 318(2009) doi: 10.1016/j.rser.2007.10.005
2	S. H. Lee, S. J. Yoon, Y. G. Kim, J. G. Lee, The utilization of micro- encapsulated phase change material wallboards for energy saving, Korean Journal of Chemical Engineering, 28(11), 2206(2011) doi: 10.1007/s11814-011-0099-0
3	F. He, X. D. Wang, D. Z. Wu, New approach for sol-gel synthesis of microencapsulated n-octadecane phase change material with silica wall using sodium silicate precursor , Energy, 67, 223(2014)
4	B. X. Li, T. X. Liu, L. Y. Hu, L. N. Gao, Fabrication and properties of microencapsulated paraffin@SiO2 phase change composite for thermal energy storage, ACS Sustainable Chemistry & Energy, 1(3), 374(2013) doi: 10.1021/sc300082m
5	C. M. Chen, Z. H. Chen, X. R. Zeng, X. M. Fang, Z. G. Zhang, Z. H. Chen, Fabrication and characterization of nanocapsules containing n-dodecanol by miniemulsion polymerization using interfacial redox initiation, Colloid & Polymer Science, 290(4), 307(2012)
6	M. Hunger, A. G. Entrop, I. Mandilaras, H. J. H.Brouwers, M. Founti, The behavior of self-compacting concrete containing micro-encapsulated phase change materials, Cement & Concrete Composites, 31(10), 731(2009)
7	G. Y. Fang, Z. Chen, H. Li, Synthesis and properties of microencapsulated paraffin composites with SiO2 shell as thermal energy storage materials, Chemical Engineering Journal, 163(1-2), 154(2010) doi: 10.1016/j.cej.2010.07.054
8	MENG Duo, WANG Lijiu, Preparation and thermal properties of fatty acid/inorganic nano-particle form-stable phase change material, Journal of Building Materials, 16(1), 91(2013)
8	(孟多, 王立久, 脂肪酸/无机纳米颗粒基定形相变材料的制备与热性能, 建筑材料学报, 16(1), 91(2013)) doi: 10.3969/j.issn.1007-9629.2013.01.017
9	SHANG Jianli, LI Qianming, WANG Zhengjun, Preparation and thermal performance tests of microencapsulated gypsum-based phase change building material, Acta Energiae Solaris Sinica, 33(12), 2140(2012)
9	(尚建丽, 李乔明, 王争军, 微胶囊相变储能石膏基建筑材料制备及性能研究, 太阳能学报, 33(12), 2140(2012))
10	A. M. Borreguero, M. Carmona, M. L. Sanchez, L. V. José, F. R. Juan, Improvement of the thermal behaviour of gypsum blocks by the incorporation of microcapsules containing PCMS obtained by suspension polymerization with an optimal core/coating mass ratio, Applied Thermal Engineering, 30(10), 1164(2010) doi: 10.1016/j.applthermaleng.2010.01.032
11	SHANG Jianli, WANG Si, DONG Li, Prepared of PAR/POL/SOD-composite-wall microencapsulated and research of energy storage and humidity-control performance, Journal of Functional Materials, 44(8), 1141(2013)
11	(尚建丽, 王思, 董莉, PAR/POL/SOD复合微胶囊的制备及热湿性能研究, 功能材料, 44(8), 1(2013)) doi: 10.3969/j.issn.1001-9731.2013.08.019
12	ZHANG Hao, HUANG Kai, HUANG Xinjie, Study on degradation effect of Ce-TiO2photocatalyst coating on formaldehyde solution and its prediction model, Chinese Rare Earths, 35(4), 18(2014)
12	(张浩, 黄凯, 黄新杰, Ce-TiO2光催化涂料降解甲醛溶液的性能研究及预测模型, 稀土, 35(4), 18(2014))
13	SHANG Jianli, ZHANG Hao, XIONG lei, MA Xianglong, Preparation and texture of phase change materials of fatty acid/SiO2 composite, Chinese Journal of Material Research, 29(10), 757(2015)
13	(尚建丽, 张浩, 熊磊, 麻向龙, 脂肪酸/SiO2复合相变材料的制备及其对织构的影响因素, 材料研究学报, 29(10), 757(2015))
14	ZHANG Hao, HUANG Xinjie, LIU Xiuyu, TANG Gang, Optimization for preparation of phase change and humidity control composite materials of hexadecanol-palmitic acid-lauric acid/SiO2, Chinese Journal of Material Research, 29(9), 671(2015)
14	(张浩, 黄新杰, 刘秀玉, 唐刚, 优化制备棕榈醇-棕榈酸-月桂酸/SiO2复合相变调湿材料, 材料研究学报, 29(9), 671(2015))
15	HUANG Zishuo, YU Hang, ZHANG Meiling, Humidity-control materials and their humidity absorption and desorpttion rate variation, Journal of Tongji University(Natural Science), 42(2), 310(2014)
15	(黄子硕, 于航, 张美玲, 建筑调湿材料吸放湿速度变化规律, 同济大学学报(自然科学版), 42(2), 310(2014)) doi: 10.3969/j.issn.0253-374x.2014.02.023
16	YU Yongsheng, JING Qiangshan, SONG Fangfang, Study on the ternary phase change system of H/PA/LA, Journal of Building Materials, 16(1), 97(2013)
16	(于永生, 井强山, 宋方方, 十六醇/十六酸/十二酸三元复合相变体系研究, 建筑材料学报, 16(1), 97(2013)) doi: 10.3969/j.issn.1007-9629.2013.01.018
17	S. Pal, M. R. Hajj, W. P. Wong, I. K. Puri, Thermal energy storage in porous materials with adsorption and desorption of moisture, International Journal of Heat and Mass Transfer, 69, 285(2014) doi: 10.1016/j.ijheatmasstransfer.2013.10.023

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