碳化钨/钢基复合材料的界面重熔<sup>*</sup>

doi:10.11901/1005.3093.2013.790

材料研究学报

2014, Vol. 28

Issue (3): 191-196 DOI: 10.11901/1005.3093.2013.790

本期目录 | 过刊浏览

碳化钨/钢基复合材料的界面重熔^*

黄浩科,李祖来(

),山泉,蒋业华,侯占东

昆明理工大学材料科学与工程学院昆明 600093

Interface Remelting of Tungsten Carbide Particles Reinforced Steel Composite

Haoke HUANG,Zulai LI(

),Quan SHAN,Yehua JIANG,Zhandong HOU

School of Material Science and Engineering, Kunming University of Science and Technology, Kunming 650093

引用本文:

黄浩科,李祖来,山泉,蒋业华,侯占东. 碳化钨/钢基复合材料的界面重熔^*[J]. 材料研究学报, 2014, 28(3): 191-196.
Haoke HUANG, Zulai LI, Quan SHAN, Yehua JIANG, Zhandong HOU. Interface Remelting of Tungsten Carbide Particles Reinforced Steel Composite[J]. Chinese Journal of Materials Research, 2014, 28(3): 191-196.

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摘要:

用等离子快速烧结(SPS)法烧结制备碳化钨/钢基复合材料, 然后用真空管式炉对其进行界面重熔, 研究了重熔温度对界面反应的影响以及界面反应区的生成机制。结果表明, 界面反应可在固态条件下发生, 且随着重熔温度的提高界面反应区的宽度呈增大的趋势。界面反应的产物为Fe₃W₃C, 其形成过程为: 在约1314℃碳化钨颗粒内部发生反应2WC→W₂C+C, 然后在约1341℃发生W₂C与基体的反应生成Fe₃W₃C。

关键词 ：复合材料, 界面反应, SPS, Fe₃W₃C, 重熔

Abstract：

A tungsten carbide particles reinforced steel matrix composite was fabricated by spark plasma sintering (SPS) technique, and then the composite was remelted in a vacuum tube furnace. The effect of remelting temperature on interface reaction was investigated meticulously. The results show that the interface reaction could occur when the matrix was still in solid state, the thickness of interface reaction layer increased with the increasing temperature. The interface reaction product, Fe₃W₃C, was resulted from the following two step reactions: firstly the reaction 2WC→W2C+C would occur within tungsten carbide particles at 1314℃, then the W₂C would react with Fe to produce Fe₃W₃C at temperatures above 1341℃.

Key words： composites interface reaction SPS Fe₃W₃C remelting

收稿日期: 2013-10-20

基金资助:* 国家自然科学基金51241002 和51361019 资助项目。

作者简介:

本文联系人: 李祖来

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表1 粉末的化学成分

表2 SPS烧结参数

图1 管式炉温度变化曲线

图2 重熔温度不同的试样和未重熔试样的XRD

图3 重熔和未重熔试样的光学金相照片

图4 重熔温度不同的试样和未重熔试样的电镜照片

表3 复合材料中各处的EDS能谱分析(质量分数, %)

图5 铸渗法制备复合材料试样的XRD

图6 铸渗法制备的复合材料试样的电镜照片

表4 复合材料中各处的EDS能谱分析(质量分数, %)

图7 Fe粉、碳化钨颗粒及其混合粉末的DSC曲线

图8 碳化钨颗粒可能发生反应的ΔG随温度的变化

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