含硅苯并噁嗪的制备及其对双马来酰亚胺树脂固化反应动力学的影响

doi:10.11901/1005.3093.2019.475

材料研究学报

2020, Vol. 34

Issue (6): 459-465 DOI: 10.11901/1005.3093.2019.475

研究论文

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含硅苯并噁嗪的制备及其对双马来酰亚胺树脂固化反应动力学的影响

贾园¹, 张黎英¹, 马明阳¹(

), 师瑞峰²

1.西安文理学院化学工程学院陕西省表面工程与再制造重点实验室西安 710075
2.西安科技大学化学与化工学院西安 710054

Preparation of Si-containing Benzoxazine and Its Influence on Curing Reaction Kinetics of Bismaleimide Ester Resin

JIA Yuan¹, ZHANG Liying¹, MA Mingyang¹(

), SHI Ruifeng²

1.College of Chemical Engineering, Xi'an University, Key Laboratory for Surface Engineering and Remanufacturing in Shaanxi Province, Xi’an 710065，China
2.School of Chemistry and Chemical Engineering, Xi'an University of Science and Technology, Xi 'an 710054, China

引用本文:

贾园, 张黎英, 马明阳, 师瑞峰. 含硅苯并噁嗪的制备及其对双马来酰亚胺树脂固化反应动力学的影响[J]. 材料研究学报, 2020, 34(6): 459-465.
Yuan JIA, Liying ZHANG, Mingyang MA, Ruifeng SHI. Preparation of Si-containing Benzoxazine and Its Influence on Curing Reaction Kinetics of Bismaleimide Ester Resin[J]. Chinese Journal of Materials Research, 2020, 34(6): 459-465.

全文: PDF(2496 KB) HTML

摘要:

通过溶剂法设计合成出了结构中含有硅元素的新型苯并噁嗪单体(Si-BOZ)，以其作为改性体系对双马来酰亚胺树脂(BMI)进行共混改性，在降低BMI预聚物粘度的同时优化其固化工艺，改善其综合性能。选用平板小刀法测定了Si-BOZ、BMI、Si-BOZ/BMI等树脂体系的凝胶时间，红外光谱(FTIR)跟踪研究了Si-BOZ和BMI在固化过程中所发生的化学反应，非等温差示扫描量热法(DSC)研究了Si-BOZ/BMI树脂体系的固化反应动力学特征，并通过Kissinger法和Ozawa法对两者固化过程中的各参数进行了讨论。

关键词 ：复合材料, 双马来酰亚胺树脂, 树脂共混, 苯并噁嗪树脂, 固化动力学

Abstract：

A new Si-containing BOZ resin monomer (Si-BOZ) was prepared via chemical synthesis method, which was then used as the modifier to blend with BMI, so that to yield the BMI prepolymer with lower viscosity, and the modified BMI resin can also exhibits excellent heat resistance, radiation resistance and mechanical properties. The gelation time of Si-BOZ, BMI, Si-BOZ/BMI resin was studied by plate small knife method, the chemical reactions of Si-BOZ and BMI during curing process were studied by FTIR, and the effect of the addition of Si-BOZ on the curing reaction kinetics of BMI was studied by non-isothermal scanning calorimetry (DSC). The role of parameters in the curing process was also discussed by Kissinger method and Ozawa method.

Key words： composite bismaleimide polymer blends benzoxazine resin curing kinetics

收稿日期: 2019-10-15

ZTFLH:

O631

基金资助:陕西省教育厅科研计划(19JK0741);陕西省大学生创新创业项目(S201911080053)

作者简介: 贾园，女，1988年生，博士

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https://www.cjmr.org/CN/10.11901/1005.3093.2019.475 或 https://www.cjmr.org/CN/Y2020/V34/I6/459

图1 Si-BOZ的合成路线

图2 Si-BOZ/BMI的红外谱图

图3 两种BOZ体系的凝胶时间随温度变化关系图

图4 Si-BOZ/BMI的红外跟踪谱图

图5 BMI和Si-BOZ/BMI体系的凝胶时间与温度关系图

图6 BMI和Si-BOZ/BMI体系的非等温DSC曲线

表1 BMI的DSC固化曲线上放热峰的峰值温度

表2 Si-BOZ/BMI的DSC固化曲线上放热峰的峰值温度

图7 BMI和Si-BOZ/BMI树脂体系峰值温度的线性回归直线

图8 BMI和Si-BOZ/BMI树脂体系Kissinger线性拟合

图9 BMI和Si-BOZ/BMI树脂体系Ozawa线性拟合

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