磷虾蛋白对聚丙烯腈的修饰改性

doi:10.11901/1005.3093.2015.129

材料研究学报

2015, Vol. 29

Issue (9): 686-692 DOI: 10.11901/1005.3093.2015.129

本期目录 | 过刊浏览

磷虾蛋白对聚丙烯腈的修饰改性

齐善威,郭静(

),牟思阳,杨利军,张森,于跃

大连工业大学纺织与材料工程学院大连 116034

Modification and Performance of Polyacrylonitrile with Maleic Anhydride Grafted Krill Protein

Shanwei QI,Jing GUO(

),Siyang MU,Lijun YANG,Sen ZHANG,Yue YU

School of Textile and Material Engineering, Dalian Polytechnic University, Dalian 116034, China

引用本文:

齐善威,郭静,牟思阳,杨利军,张森,于跃. 磷虾蛋白对聚丙烯腈的修饰改性[J]. 材料研究学报, 2015, 29(9): 686-692.
Shanwei QI, Jing GUO, Siyang MU, Lijun YANG, Sen ZHANG, Yue YU. Modification and Performance of Polyacrylonitrile with Maleic Anhydride Grafted Krill Protein[J]. Chinese Journal of Materials Research, 2015, 29(9): 686-692.

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摘要:

以水为反应介质, 用马来酸酐对磷虾蛋白进行活化后再与丙烯腈共聚, 得到磷虾蛋白马来酸酐酯接枝聚丙烯腈共聚物(AKPM-g-PAN), 然后用湿法纺丝制备AKPM-g-PAN纤维并研究其力学性能和热性能。结果表明: 制备AKPM-g-PAN的最佳配方和条件是: AKP、马来酸酐与PAN的配比为2∶2∶12.5, 引发剂的质量为PAN质量的10%, 反应温度为60℃。按照最佳工艺条件进行接枝聚合反应, 得到的聚合物分子量为15.8万。AKPM-g-PAN纤维的断裂强度随着纺丝液浓度的增加而增大, 随着凝固浴浓度和凝固浴温度的增加先增大后减小; 而AKP的加入导致复合纤维的保水率提高, 但是影响聚丙烯腈原有的分子链规整性并失去了部分结晶能力。

关键词 ：有机高分子材料, 聚丙烯腈, 磷虾蛋白, 改性, 湿法纺丝

Abstract：

Copolymer AKPM-g-PAN was prepared by copolymerization of maleic anhydride grafted krill protein (AKP) and polyacrylonitrile (PAN), then AKPM-g-PAN composite fibers were prepared by wet spinning, whilst there mechanical and thermal properties were investigated. The results show that: the best condition for preparation of AKPM-g-PAN are: the ratio of AKP, maleic anhydride and PAN is 2: 2: 12.5, the initiator is 10% (mass fraction) PAN, and the reaction temperature is 60℃. The molecular weight of the polymer obtained after grafting polymerization by the optimal process condition was 158010. The fracture strength of AKPM-g-PAN composite fibers increased with increasing concentration of spinning solution, whilst increases first and then decreases with the increase of the concentration and temperature of the coagulation bath; and the addition of AKP leads to increase of water retention rate of composite fiber, influencing polyacrylonitrile original regularity of molecular chain, and lost of a part of crystallization ability.

Key words： organic polymer materials polyacrylonitrile krill protein modify wet spinning

收稿日期: 2015-03-17

基金资助:* 国家自然科学基金51373027资助项目。

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https://www.cjmr.org/CN/10.11901/1005.3093.2015.129 或 https://www.cjmr.org/CN/Y2015/V29/I9/686

表1 AKPM-g-PAN制备的正交实验表

图1 接枝聚合物原理图

图2 PAN, AKPM-g-PAN and AKPM的红外光谱曲线

图3 #3、#6、#9试样的TG曲线

图4 #3、#6、#9的XRD曲线

图5 #3、#6、#9试样的DSC曲线

图6 凝固浴温度与纤维断裂强度的关系曲线

图7 凝固浴浓度与纤维断裂强度的关系曲线

图8 纺丝液浓度与纤维断裂强度的关系曲线

图9 #9 试样在凝固浴温度为35℃, 纺丝液浓度为8%, 凝固浴浓度为40%条件下纺丝纤维的微观形貌

1	H. T. Chiu, J. M. Lin, T. H. Cheng, S. Y. Chou. Fabrication of electrospun polyacrylonitrile ion-exchange membranes for application in lysozym, Express Polymer Letters, 4(5), 308(2011)
2	HU Xuemin,XIAO Changfa, FENG Yan, Preparation and characterization of modified polyacrylonitrile fiber by collagen, Journal of Functional Materials, 10(44), 1414(2013)
2	(胡雪敏, 肖长发, 封严, 胶原蛋白改性聚丙烯腈纤维制备及性能表征, 功能材料, 10(44), 1414(2013))
3	DENG Huiyu,CHEN Qingchun, MA Jianguo, Development of the surface modification of polyacrylonitrile and acrylonitrile based copolymers membranes, Polymer Materials Science & Engineering, 2(24), 1(2008)
3	(邓慧宇, 陈庆春, 马建国, 聚丙烯腈及丙烯腈共聚物膜表面改性研究进展, 高分子材料科学与工程, 2(24), 1(2008))
4	Hae Rim Jung,Min-A Kim, Yong-Soo Seo, Yang-Bong Lee, Byung-Soo Chun, Seon-Bong Kim, Decreasing effect of fluoride content in Antarctic krill (Euphausia superba) by chemical treatments, International Journal of Food Science and Technology, 48, 1252(2013)
5	HUANG Hongliang,CHEN Xuezhong, FENG Chunlei, Situation analysis of Antarctic krill resources development, Fishery Modernization, 1, 48(2007))
5	(黄洪亮, 陈雪忠, 冯春雷, 南极磷虾资源开发现状分析, 渔业现代化, 1, 48(2007)
6	SUN Song,YAN Xiaojun, Active substances in the antarctic krill, Advances in Polar Science, 13(3), 213(2001)
6	(孙松, 严小军, 南极大磷虾的生物活性物质及其用途研究进展, 极地研究, 13(3), 213(2001))
7	Morales?M ?S,Ogale A A, Carbon fibers derived from UV-assisted stabilization of wet-spun polyacrylonitrile fibers,? Journal?of?Applied?Polymer Science, 16(130), 2494(2013)
8	Liu Y,Li X, Lu J C, Electrically conductive poly(3, 4-ethylenedioxythiophene) -polystyrene sulfonic acid/polyacrylonitrile composite fibers prepared by wet spinning, Journal of Applied Polymer Science, 1(130), 370(2013)
9	?Zhang Z,Jiang W, Wang?Y J, Wu Y C, Hou X, ?Synthesis of monodispersed?polyacrylonitrile microspheres, Journal?of?Applied?Polymer?Science, 5(125), 4142(2012)
10	Duan Q J,Wang B, Wang H P, Effects of stabilization temperature on structures and properties of polyacrylonitrile (PAN)-based stabilized electrospun nanofiber mats, Journal of Applied Polymer Science, 12(51), 2428(2012)
11	FEI Zhengdong,WAN Lingshu, ZHONG Mingqiang, XU Zhikang, Synthesis of acrylonitrile-n- isopropylacrylamide graft copolymers for the preparation of thermal responsive polyacrylonitrile membranaes, Acta Polymerica Sinica, 4, 404(2012)
11	(费正东, 万灵书, 钟明强, 徐志康, 丙烯腈-N-异丙基丙烯酰胺接枝共聚物的合成及其对聚丙烯腈分离膜的改性, 高分子学报, 4, 404(2012))
12	Jyotishkumar P,Pionteck J, H?u?ler L, Adam G, Thomas S, Poly(acrylonitrile-butadiene-styrene) modi?ed epoxy–amine systems analyzed by FTIR and modulated DSC, Journal of Macromolecular Science: Physics, 7(51), 1425(2012)
13	B. L. Chaudhari, Z. V. P. Murthy,Preparation, characterization, and performance of sulfated chitosan/polyacrylonitrile composite nanofiltration membranes, Journal of Dispersion Science & Technology, 3(34), 389(2013)
14	J. N.Wang, W. Qin, X. Q. Liu, H. Q.Liu,Synthesis and characterization of hydroxyapatite on hydrolyzed polyacrylonitrile nanofiber templates, RSC Advances, 3, 11132(2013)
15	?Jyotishkumar P, Pionteck J, Moldenaers Paula, Thomas Sabu, Preparation and properties of TiO2-filled poly(acrylonitrile-butadiene-styrene)/epoxy hybrid composites, Journal of Applied Polymer?Science, 4(127), 3159(2013)
16	WU Shuai,LI Ting, CUI Dongxu, XU Mulianghua, Orientation of amorphous region in polyacrylonitrile fibers, Polymer Materials Science & Engineering, 11(30), 54(2014)
16	(武帅, 李婷, 崔东旭, 徐木梁华, 聚丙烯腈纤维非晶区的取向结构, 高分子材料科学与工程, 11(30), 54(2014))
17	WANG Yongwei,ZHU Bo, CAO Weiwei, JIANG Xinbin, WANG Xihai, Thermal performances of acrylonitrile/acrylamide copolymers, Journal of Functional Materials, 11(44), 1531(2013)
17	(王永伟, 朱波, 曹伟伟, 姜新斌, 王西海, 聚丙烯腈/丙烯酰胺共聚物热性能研究, 功能材料, 11(44), 1531(2013))
18	JIAO Na, LI Long, WANG Mengfan, XU Mulianghua, CAO Weiyu, Effect of stretching on the phase transition behavior of polyacrylonitrile precursor, Polymer Materials Science & Engineering, 11(30), 103(2014
18	(焦娜, 李龙, 王梦梵, 徐木梁华, 曹维宇, 湿法纺丝过程中牵伸对聚丙烯腈原丝相转变行为的影响, 高分子材料科学与工程, 11(30), 103(2014))
19	Huang W,Wang X Q, Jia Y T, Li X Q, Zhu Z G, Li Y, Si Y , Ding B, Wang X L, Yu J Y, Highly sensitive formaldehyde sensors based on polyvinylamine modified polyacrylonitrile nanofibers, RSC Advances, 3, 22994(2013)
20	OU Yang,WU Qingyun, WAN Lingshu, YANG Haocheng, XU Zhikang, Preparation of porous polyacrylonitrile ultrathin fibers by electrospinning with nonsolvent induced phase separation, Acta Polymerica Sinica, 2, 248(2013)
20	(欧洋, 吴青芸, 万灵书, 杨皓程, 徐志康, 采用静电纺丝/非溶剂致相分离制备聚丙烯腈多孔超细纤维的研究, 高分子学报, 2, 248(2013))

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