Ni-Fe-Ga磁致形状记忆合金的马氏体相变和晶体结构的研究*

doi:10.11901/1005.3093.2014.432

材料研究学报

2014, Vol. 28

Issue (12): 881-886 DOI: 10.11901/1005.3093.2014.432

本期目录 | 过刊浏览

Ni-Fe-Ga磁致形状记忆合金的马氏体相变和晶体结构的研究*

白静^1,^2,^**(

),王新丽¹,顾江龙¹,李艳波¹,赵骧¹,左良¹

1. 东北大学材料各向异性与织构教育部重点实验室沈阳 110819
2. 东北大学秦皇岛分校河北省电介质与电解质材料实验室秦皇岛 066004

Martensitic Transformation and Crystal Structure of Ni-Fe-Ga Ferromagnetic Shape Memory Alloys

Jing BAI^1,^2,^**(

),Xinli WANG¹,Jianglong GU¹,Yanbo LI¹,Xiang ZHAO¹,Liang ZUO¹

1. Key Laboratory for Anisotropy and Texture of Materials, Northeastern University, Shenyang 110819
2. Hebei Provincial Laboratory for Dielectric and Electrolyte Materials, Northeastern University at Qinhuangdao Branch, Qinhuangdao 066004

引用本文:

白静,王新丽,顾江龙,李艳波,赵骧,左良. Ni-Fe-Ga磁致形状记忆合金的马氏体相变和晶体结构的研究*[J]. 材料研究学报, 2014, 28(12): 881-886.
Jing BAI, Xinli WANG, Jianglong GU, Yanbo LI, Xiang ZHAO, Liang ZUO. Martensitic Transformation and Crystal Structure of Ni-Fe-Ga Ferromagnetic Shape Memory Alloys[J]. Chinese Journal of Materials Research, 2014, 28(12): 881-886.

全文: PDF(3579 KB) HTML

摘要:

使用DSC、XRD、SEM和TEM等分析测试手段, 对Ni₅₀₊_xFe_25-_xGa₂₅(x =3, 4.5, 6)合金的马氏体相变温度、精细显微结构以及复杂马氏体晶体结构进行了系统研究。结果表明, Ni₅₀₊_xFe_25-_xGa₂₅合金的马氏体相变温度T_m随Ni含量增加而升高。Ni₅₆Fe₁₉Ga₂₅合金的马氏体板条非常清晰细密, 且存在着多种不同取向的变体; 该种合金由6M+14M混合马氏体和γ相组成。Ni₅₆Fe₁₉Ga₂₅合金既具有适合实际应用的马氏体相变温度, 又具有有利于磁致应变的晶体结构。

关键词 ：金属材料, 功能材料, Ni-Fe-Ga, 磁致形状记忆合金, 晶体结构, 显微组织, 马氏体相变

Abstract：

A moderate amount of g-phase precipitates in Ni-Fe-Ga ferromagnetic shape memory alloy can drastically improve its toughness. The martensitic transformation temperature, the microstructure and the crystal structure of the complicated alloys Ni₅₀₊_xFe_25-_xGa₂₅(x=3, 4.5, 6) were investigated by DSC, XRD, SEM and TEM techniques. The results showed that the martensitic transformation temperature T_m went up along with the increasing Ni content; the Ni₅₆Fe₁₉Ga₂₅alloy exhibited a microstructure composed of fine and clear martensite lathes of several martensitic variants in different orientation. The 6M+14M mixed martensite and g-phases were detected in the Ni₅₆Fe₁₉Ga₂₅alloy by XRD and TEM. Among the investigated alloys, the Ni₅₆Fe₁₉Ga₂₅alloy had not only the most appropriate martensitic transformation temperature for practical application, but also the suitable crystal structure for facilitating the magnetostrictive strain.

Key words： metallic materials functional material Ni-Fe-Ga ferromagnetic shape memory alloys crystal structure microstructure martensitic transformation

收稿日期: 2014-08-19

基金资助:*国家自然科学基金51301036, 河北省自然科学基金项目E2013501089, 高等学校博士学科点专项科研基金20120042110021, 中央高校基本业务费N130523001项目资助。

	服务

	把本文推荐给朋友
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	白静
	王新丽
	顾江龙
	李艳波
	赵骧
	左良
44.8K

链接本文:

https://www.cjmr.org/CN/10.11901/1005.3093.2014.432 或 https://www.cjmr.org/CN/Y2014/V28/I12/881

表1 Ni50+xFe25-xGa25(x=3, 4.5, 6)合金马氏体相变的特征温度及相变潜热

表2 Ni50+xFe25-xGa25(x=3, 4.5, 6)合金的相组成

图1 Ni50+xFe25-xGa25(x=3, 4.5, 6)合金组织

图2 Ni56Fe19Ga25合金的SEM像

图3 Ni56Fe19Ga25的XRD谱

图4 Ni56Fe19Ga25合金6M马氏体的TEM像

图5 Ni56Fe19Ga25合金14M马氏体的TEM像

1	A. Sozinov, A. A. Likhachev, N. Lanska, K. Ullakko,Giant magnetic-field-induced strain in NiMnGa seven-layered martensitic phase, Applied Physics Letters, 80, 1746(2002)
2	K. Oikawa, T. Ota, T. Ohmori, Y. Tanaka, H. Morito, A. Fujita, R. Kainuma, K. Fukamichi, K. Ishida,Magnetic and martensitic phase transitions in ferromagnetic Ni-Ga-Fe shape memory alloys, Applied Physics Letters, 81, 5201(2002)
3	Y. Li, C. B. Jiang, T. Liang, Y. Q. Ma,Martensitic transformation and magnetization of Ni-Fe-Ga ferromagnetic shape memory Alloys, Scripta Materialia, 48, 1255(2003)
4	Z. H. Liu, M. Zhang, Y. T. Cui, Y. Q. Zhou, W. H. Wang, G. H. Wu, X. X. Zhang, G. Xiao,Martensitic transformation and shape memory effect in ferromagnetic Heusler alloy Ni2FeGa, Applied Physics Letters, 82(3), 424(2003)
5	K. Oikawa, T. Ota, Y. Sutou, T. Ohmori,Magnetic and martensitic phase transformation in a Ni54Ga27Fe19 alloy, Materials Transaction, 3(9), 2360(2002)
6	T. Omori, N. Kamiya, Y. Sutou, K. Oikawa,Phase transformation in Ni-Ga-Fe ferromagnetic shape memory alloys, Materials Science and Engineering A, 378, 403(2004)
7	J. Q. Li, Z. H. Liu, H. C. Yu, M. Zhang,Martensitic transition and structural modulations in the Heusler alloy Ni2FeGa, Solid State Communications, 126, 323(2003)
8	H. X. Zheng. M. X. Xia, J. Liu, J. G. Li,Martensitic transformation of highly undercooled Ni-Fe-Ga magnetic shape memory alloys, Journal of Alloys and Compounds, 388(2), 173(2005)
9	P. J. Brown, J. Crangle, T. Kanomata, M. Matsumoto, K.-U. Neumann, B. Ouladdiaf, K. R. A. Ziebeck,The crystal structure and phase transitions of the magnetic shape memory compound Ni2MnGa, Journal of Physics: Condensed Matter, 14, 10159(2002)
10	Y. Sutou, N. Kamiya, T. Omori, R. Kainuma,Stress-strain characteristics in Ni-Ga-Fe ferromagnetic shape memory alloys, Applied Physics Letter, 84(8), 1275(2004)
11	K. Oikawa, T. Ota, T. Ohmori, Y. Tanaka, H. Morito, A. Fujita, R. Kainuma, K. Fukamichi, K. Ishida,Magnetic and martensitic phase transitions in ferromagnetic Ni-Ga-Fe shape memory alloys, Applied Physics Letters, 81, 5201(2002)
12	T. M. Heil, M. A. Willard, W. T. Reynolds Jr,The effects of composition and aging on the martensite and magnetic transformations in Ni-Fe-Ga ferromagnetic shape memory alloys, Metallurgical and materials transactions. A, 38(4), 752(2007)
13	Z. H. Liu, H. Liu, X. X. Zhang, M. Zhang,Martensitic transformation and magnetic properties of Heusler alloy Ni-Fe-Ga ribbon, Physics Letters A, 329, 214(2004)
14	ZHU Zhiyong,Study on phase transition and magnetization of ferromagnetic shape memory alloys Ni51.5Mn25Ga23.5 and Ni2FeGa, Master degree thesis (Jilin University, 2005)
14	(朱志永, 铁磁性形状记忆合金Ni51.5Mn25Ga23.5和Ni2FeGa的相变和磁性研究, 硕士学位论文 (吉林大学, 2005))
15	J. Pons, V. A. Chernenko, R. Santamarta, E. Cesari,Crystal structure of martensitic phases in Ni-Mn-Ga shape memory alloys, Acta Materialia, 48, 3027(2000)
16	H. Morito, A. Fujita, K. Fukamichi, R. Kainuma, K. Ishida,Magnetic-field-induced strain of Fe–Ni–Ga in single-variant state, Applied Physics Letters, 83, 4993(2003)

[1]	潘新元, 蒋津, 任云飞, 刘莉, 李景辉, 张明亚. 热挤压钛/钢复合管的微观组织和性能[J]. 材料研究学报, 2023, 37(9): 713-720.
[2]	毛建军, 富童, 潘虎成, 滕常青, 张伟, 谢东升, 吴璐. AlNbMoZrB系难熔高熵合金的Kr离子辐照损伤行为[J]. 材料研究学报, 2023, 37(9): 641-648.
[3]	宋莉芳, 闫佳豪, 张佃康, 薛程, 夏慧芸, 牛艳辉. 碱金属掺杂MIL125的CO₂ 吸附性能[J]. 材料研究学报, 2023, 37(9): 649-654.
[4]	赵政翔, 廖露海, 徐芳泓, 张威, 李静媛. 超级奥氏体不锈钢24Cr-22Ni-7Mo-0.4N的热变形行为及其组织演变[J]. 材料研究学报, 2023, 37(9): 655-667.
[5]	邵鸿媚, 崔勇, 徐文迪, 张伟, 申晓毅, 翟玉春. 空心球形AlOOH的无模板水热制备和吸附性能[J]. 材料研究学报, 2023, 37(9): 675-684.
[6]	幸定琴, 涂坚, 罗森, 周志明. C含量对VCoNi中熵合金微观组织和性能的影响[J]. 材料研究学报, 2023, 37(9): 685-696.
[7]	欧阳康昕, 周达, 杨宇帆, 张磊. 含LPSO相Mg-Y-Er-Ni合金的组织和拉伸性能[J]. 材料研究学报, 2023, 37(9): 697-705.
[8]	徐利君, 郑策, 冯小辉, 黄秋燕, 李应举, 杨院生. 定向再结晶对热轧态Cu71Al18Mn11合金的组织和超弹性性能的影响[J]. 材料研究学报, 2023, 37(8): 571-580.
[9]	熊诗琪, 刘恩泽, 谭政, 宁礼奎, 佟健, 郑志, 李海英. 固溶处理对一种低偏析高温合金组织的影响[J]. 材料研究学报, 2023, 37(8): 603-613.
[10]	刘继浩, 迟宏宵, 武会宾, 马党参, 周健, 徐辉霞. 喷射成形M3高速钢热处理过程中组织的演变和硬度偏低问题[J]. 材料研究学报, 2023, 37(8): 625-632.
[11]	由宝栋, 朱明伟, 杨鹏举, 何杰. 合金相分离制备多孔金属材料的研究进展[J]. 材料研究学报, 2023, 37(8): 561-570.
[12]	任富彦, 欧阳二明. g-C₃N₄ 改性Bi₂O₃ 对盐酸四环素的光催化降解[J]. 材料研究学报, 2023, 37(8): 633-640.
[13]	王昊, 崔君军, 赵明久. 镍基高温合金GH3536带箔材的再结晶与晶粒长大行为[J]. 材料研究学报, 2023, 37(7): 535-542.
[14]	刘明珠, 樊娆, 张萧宇, 马泽元, 梁城洋, 曹颖, 耿仕通, 李玲. SnO₂ 作散射层的光阳极膜厚对量子点染料敏化太阳能电池光电性能的影响[J]. 材料研究学报, 2023, 37(7): 554-560.
[15]	秦鹤勇, 李振团, 赵光普, 张文云, 张晓敏. 固溶温度对GH4742合金力学性能及γ' 相的影响[J]. 材料研究学报, 2023, 37(7): 502-510.

Viewed

Full text

Abstract

Cited

Shared

Discussed