Please wait a minute...
材料研究学报  2009, Vol. 23 Issue (1): 108-112    
  研究论文 本期目录 | 过刊浏览 |
电泳沉积制备氧化钇稳定的二氧化锆薄膜
王振华1; 孙克宁2; 沈哲敏1; 沈水云1; 张乃庆2
1.哈尔滨工业大学应用化学系 哈尔滨 150001
2.哈尔滨工业大学基础与交叉科学研究院 哈尔滨 150001
Preparation of yttria-stabilized zirconia (YSZ) films by an electrophoretic deposition method
WANG Zhenhua1; SUN Kening2; SHEN Zhemin1; SHEN Shuiyun1; ZHANG Naiqing2
1.Department of Applied Chemistry; Harbin Institute of Technology; Harbin 50001
2.Academy of Fundamental and Interdisciplinary Sciences; Harbin Institute of Technology; Harbin 150001
引用本文:

王振华 孙克宁 沈哲敏 沈水云 张乃庆. 电泳沉积制备氧化钇稳定的二氧化锆薄膜[J]. 材料研究学报, 2009, 23(1): 108-112.
, , , . Preparation of yttria-stabilized zirconia (YSZ) films by an electrophoretic deposition method[J]. Chin J Mater Res, 2009, 23(1): 108-112.

全文: PDF(743 KB)  
摘要: 

采用恒压电泳沉积方法在Ni-YSZ(氧化钇稳定的氧化锆)阳极基体上制备YSZ电解质膜, 研究了悬浮体系YSZ含量、外加电压、沉积时间对电泳过程及YSZ膜层质量的影响. 结果表明, YSZ含量为20 g/L, 沉积电压为10 V, 沉积时间\linebreak 5 min时, 恒压电泳一次即可得到均匀致密的YSZ膜. 膜层与基体结合紧密, 厚度约为10 μm.

关键词 无机非金属材料电泳沉积薄膜钇稳定的二氧化锆    
Abstract

Yttria-stabilized zirconia (YSZ) films on Ni/YSZ substrates were prepared by electrophoretic deposition under constant voltage. Effects of YSZ content, applied voltage and deposition time on electrophoretic processes and YSZ film properties were investigated. Results showed that dense YSZ films can be obtained when 20 g/L YSZ suspension was used and a deposition voltage of 10 V was applied for 5 min. YSZ film contacts with anode substrate compactly with a thickness of 10 μm.

Key wordsinorganic non-metallic materials    electrophoretic deposition    film    yttria-stabilized zirconia (YSZ)
收稿日期: 2008-04-16     
ZTFLH: 

TB321

 
基金资助:

国家自然科学基金90510006及黑龙江省自然科学基金ZJG0703资助项目.

1 HAN Minfang, PENG Suping, Solid Oxide Fuel Cell Components and Manufacture Processes (Beijing, Chinese Science Press, 2004) p.19
(韩敏芳, 彭苏萍,  固体氧化物燃料电池材料及制备 (北京, 科学出版社, 2004) p.19))
2 B.Uday, Electrochemical vapor deposition of solid oxide films, Solid State Ionics, 52, 227(2002)
3 J.Will, A.Mitterdorfer, C.Kleinlogel, D.Perednis, L.J.Gauckler, Fabrication of thin electrolytes for  secondgeneration solid oxide fuel cells, Solid State Ionics, 131(1-2), 79(2000)
4 Changjiu Li , Chengxin Li, Influence of YSZ electrolyte thickness on the characteristics of plasma-sprayed cermet supported tubular SOFC, Solid State Ionics, 177, 2065(2006)
5 Changrong Xia, Huaqiang Cao, Hong Wang, Pinghua Yang, Guangyao Meng and Dingkun Peng, Sol-gel synthesis of yttria stabilized zirconia membranes through controlled hydrolysis of zirconium alkoxide, Journal of Membrane Science, 162(1-2), 181 (1999)
6 Yaohui Zhang, Xiqiang Huang, Zhe Lu, Xiaodong Ge, Jiahua Xu, Xianshuang Xin, Xueqing Sha, Wenhui Su, Effect of starting powder on screen-printing YSZ film used as electrolyte in SOFCs, Solid State Ionics, 177, 281 (2006)
7 LI Jigang, SUN Kening, KONG Jiangrong, Fabrication of Ni-YSZ/YSZ compound substrate membranes using tape casting method and performance measurements, Chemical Industry and Engineering Progress, 27(1), 135(2008)
(李吉刚, 孙克宁, 孔江榕, 流延法制备Ni-YSZ/YSZ复合基膜及性能测试, 化工进展,  27(1), 135(2008))
8 H.Negishi, N.Sakai, K.Yamaji, Application of electrophoretic deposition technique to solid oxide fuel cells, J. Electrochem. Soc., 147, 1682(2000)
9 J.Will, M.Hrushka, L.Gubler, Electrophoretic deposition of zirconia and porous anodic substrates, J. Am. Ceram. Soc., 84, 328 (2001)
10 T.Ishishara, K.Sato, Y.Takita, Electrophoretic deposition of Y2O3 stabilized ZrO2 electrolyte films in solid oxide fuel cells, J. Am. Ceram. Soc., 79, 913(1996)
11 I.Zhitomirsky, A.Petric, Electrophoretic deposition of ceramic materials for fuel cell applications, J. Eur. Ceram. Soc., 20, 2055(2000)
12 H.Negishi, K.Yamaji, Electrophoretic deposition of YSZ powders for SOFC, Journal of Materials Science, 39, 833(2004)
13 ZHANG Heng, DONG Xinfa, LIN Weiming, The application of electrophoretic deposition technique for preparing SOFC electrolyte films, Chinese Journal of Power Sources, 29(12), 837(2005)
(张恒, 董新法, 林维明, 电泳沉积在制备SOFC电解质膜中的应用, 电源技术,  29(12), 837(2005))
14 LU Lizhu, HU Husheng, XIE Huiqin, LI Lingchuan, Mechanism and kinetics of electrophoretic deposition (EPD) of yttria-stabilized zirconia (YSZ) film, Engineering Chemistry & Metallurgy, 19(2), 97(1998)
(卢立柱, 胡湖生, 谢慧琴, 李陵川, 电泳沉积法制备固体电解质薄膜的沉积速率和沉积机理, 化工冶金,   19(2), 97(1998))
15 LU Lizhu, DIAN Hongwei, XIE Huiqin, Fabrication of yttria-stabilized zirconia (YSZ) film by combined operation of electrophoretic deposition and electrochemical deposition, Chinese Journal of Materials Research, 15(5), 525(2001)
(卢立柱, 赁泓威, 谢慧琴, 用电泳沉积-电沉积联合法制备二氧化锆(YSZ)薄膜, 材料研究学报,  15(5), 525(2001))
16 I.Zhitomirsky, L.Galor, Electrophoretic deposition of hydroxyapatite, Journal of Material Science: Material in medicine, 8(4), 213(1997)
17 I.Zhitomirsky, A.Petric, Electrophoretic deposition of electrolyte materials for solid oxide fuel cells, Journal of Material Science, 39, 825 (2004)
18 Y.H.Lee, C.W.Kuo, C.J.Shih, I.M.Hung, K.Z.Fung, S.B.Wen, M.C.Wang, Characterization on the electrophoretic deposition of the 8 mol% yttria-stabilized zirconia nanocrystallites prepared by a sol-gel process, Materials Science and Engineering A, 445-446, 347(2007)

[1] 宋莉芳, 闫佳豪, 张佃康, 薛程, 夏慧芸, 牛艳辉. 碱金属掺杂MIL125CO2 吸附性能[J]. 材料研究学报, 2023, 37(9): 649-654.
[2] 邵鸿媚, 崔勇, 徐文迪, 张伟, 申晓毅, 翟玉春. 空心球形AlOOH的无模板水热制备和吸附性能[J]. 材料研究学报, 2023, 37(9): 675-684.
[3] 任富彦, 欧阳二明. g-C3N4 改性Bi2O3 对盐酸四环素的光催化降解[J]. 材料研究学报, 2023, 37(8): 633-640.
[4] 刘明珠, 樊娆, 张萧宇, 马泽元, 梁城洋, 曹颖, 耿仕通, 李玲. SnO2 作散射层的光阳极膜厚对量子点染料敏化太阳能电池光电性能的影响[J]. 材料研究学报, 2023, 37(7): 554-560.
[5] 李延伟, 罗康, 姚金环. Ni(OH)2 负极材料的十二烷基硫酸钠辅助制备及其储锂性能[J]. 材料研究学报, 2023, 37(6): 453-462.
[6] 余谟鑫, 张书海, 朱博文, 张晨, 王晓婷, 鲍佳敏, 邬翔. N掺杂生物炭的制备及其对Co2+ 的吸附性能[J]. 材料研究学报, 2023, 37(4): 291-300.
[7] 朱明星, 戴中华. SrSc0.5Nb0.5O3 改性BNT基无铅陶瓷的储能特性研究[J]. 材料研究学报, 2023, 37(3): 228-234.
[8] 刘志华, 岳远超, 丘一帆, 卜湘, 阳涛. g-C3N4/Ag/BiOBr复合材料的制备及其光催化还原硝酸盐氮[J]. 材料研究学报, 2023, 37(10): 781-790.
[9] 周毅, 涂强, 米忠华. 制备方法对磷酸盐微晶玻璃结构和性能的影响[J]. 材料研究学报, 2023, 37(10): 739-746.
[10] 谢锋, 郭建峰, 王海涛, 常娜. ZnO/CdS/Ag复合光催化剂的制备及其催化和抗菌性能[J]. 材料研究学报, 2023, 37(1): 10-20.
[11] 余超, 邢广超, 吴郑敏, 董博, 丁军, 邸敬慧, 祝洪喜, 邓承继. 亚微米Al2O3 对重结晶碳化硅的作用机制[J]. 材料研究学报, 2022, 36(9): 679-686.
[12] 方向明, 任帅, 容萍, 刘烁, 高世勇. 自供能Ag/SnSe纳米管红外探测器的制备和性能研究[J]. 材料研究学报, 2022, 36(8): 591-596.
[13] 李福禄, 韩春淼, 高嘉望, 蒋健, 许卉, 李冰. 氧化石墨烯的变温发光[J]. 材料研究学报, 2022, 36(8): 597-601.
[14] 朱晓东, 夏杨雯, 喻强, 杨代雄, 何莉莉, 冯威. Cu掺杂金红石型TiO2 的制备及其光催化性能[J]. 材料研究学报, 2022, 36(8): 635-640.
[15] 熊庭辉, 蔡文汉, 苗雨, 陈晨龙. ZnO纳米棒阵列和薄膜的同步外延生长及其光电化学性能[J]. 材料研究学报, 2022, 36(7): 481-488.