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材料研究学报  2010, Vol. 24 Issue (5): 530-534    
  研究论文 本期目录 | 过刊浏览 |
稀土掺杂荧光材料BaMoO4:Eu3+的制备和发光性能
陈雪冰1, 邵忠宝2, 田彦文1, 李鹏2,
1.东北大学材料与冶金学院 沈阳 110014
2.东北大学理学院 沈阳 110014
Preparation and Luminescence of Luminescent Lanthanide Materials BaMoO4∶Eu3+
CHEN Xuebing1,  SHAO Zhongbao2,  TIAN Yanwen1,  LI Peng2
College of Material and Metallurgy, College of Sciences, Northeastern University, Shenyang 110014
引用本文:

陈雪冰 邵忠宝 田彦文 李 鹏. 稀土掺杂荧光材料BaMoO4:Eu3+的制备和发光性能[J]. 材料研究学报, 2010, 24(5): 530-534.
. Preparation and Luminescence of Luminescent Lanthanide Materials BaMoO4∶Eu3+[J]. Chin J Mater Res, 2010, 24(5): 530-534.

全文: PDF(1020 KB)  
摘要: 以钼酸铵、硝酸钡和三氧化二铕为原料, 通过化学沉淀法制备稀土掺杂的发红光材料BaMoO4:Eu3+, 并用X射线衍射和激发发射光谱对粉体的结构和发光性能进行了表征。结果表明, 获得最强发光BaMoO4:Eu3+粉体的最佳合成条件是: 反应溶液的pH值为6、烧结温度为1000℃以及Eu3+掺杂量(mol分数)为8%。BaMoO4:Eu3+粉可被394 nm的紫外光和465 nm的可见光有效激发, 其发射光谱在616 nm处发光强度最大, 是以电偶极跃迁5D0→7F2为主导地位的红光发射。
关键词 无机非金属材料 BaMoO4∶Eu3+ 化学沉淀法  稀土掺杂  红色荧光粉    
Abstract:Luminescent lanthanide materials BaMoO4:Eu3+ powders were prepared by chemical precipitation method using ammonium molybdate, barium nitrate and europium oxide as raw materials. Different BaMoO4:Eu3+ powders were prepared by controlling the pH value of solution, changing the sintering temperature and the doping concentration of Eu3+. The BaMoO4:Eu3+ powders were characterized by X-ray diffraction (XRD) and excitation-emission spectra. Experimental results show that a single phase of BaMoO4:Eu3+ can be obtained at solution pH~6, sintering temperature 1000℃ and 8% Eu3+ dopped concentration. The BaMoO4:Eu3+ powders have considerable luminescent intensity, and their excitations take on a double peak structure which locates at ultraviolet (394 nm) and visible blue light (465 nm). The emission is a line spectrum and the main peak located at visible red light (616 nm).
Key wordsinorganic non-metallic materials    BaMoO4∶Eu3+    chemical precipitation method    luminescent lanthanide materials    red phosphors
收稿日期: 2010-02-02     
ZTFLH: 

TB34

 
1J.Kovac, L.Peternai, O.Lengyel, Advanced light emitting diodes structures for optoelectronic applications, Thin Solid Films, 433, 22(2003) 2 ZANG Jingcun, QI Yang, LIU Yanhang, Solid state lighting and rare earths phosphors for LED, Materials Review, 20(7), 6(2006) (臧竞存, 祁 阳, 刘燕行, 固体白光照明和稀土发光材料, 材料导报, 20(7), 6(2006)) 3XU Shiqing, JIN Shangzhong, WANG Baoling, ZHANG Liyan, ZHAO Shilong, LI Chenxia, Solid state lighting-recent progress in research of white light emitting diodes, Journal of China Jiliang University,  17(3), 188(2006) (徐时清, 金尚忠, 王宝玲, 张丽艳, 赵士龙, 李晨霞, 固体照明光源--白光LED的研究进展, 中国计量学院学报,  17(3), 188(2006)) 4 CHENG Lihong, ZHONG Haiyang, SUN Jiashi, ZHAO Xiaoxia, Synthesis and characterization of Eu(3+)doped Gd2(MoO4)3 phosphor for white LED applications,Journal of the Chinese Rare Earth Society, 26(2), 229(2008) (程丽红, 仲海洋, 孙佳石, 赵晓霞, 白光LED用红色发射荧光粉Ga2(MoO4)3:Eu(3+)制备与表征, 中国稀土学报, 26(2), 229(2008)) 5LI Xu, YANG Yong, YANG Zhiping, GUAN Li, LIU Chong, Fabrication and properties of Eu(3+) doped La2Mo2O9 red phosphor, Chinese Journal of Luminescence,  29(1), 93(2008) (李 旭, 杨勇, 杨志平, 关 丽, 刘冲, Eu(3+)激活的La2Mo2O9红色荧光粉的制备与性能, 发光学报,  29(1), 93(2008)) 6LIAO Yong, ZHU Wei, LI Xueming, MO Yunqi, HAO Xiaoguang, MA Xiaoqiang, Preparation of Li(2-x)(MoO4)2 : Eux phosphors by sol--gel process and their characterization, Materials Review,  21(8), 321(2007) (廖勇, 朱伟, 黎学明, 莫芸绮, 郝小光, 马小强, 溶胶--凝胶法制备Li(MoO4)2 : Eu及表征, 材料导报,  21(8), 321(2007)) 7ZHOU Liya, WANG Lei, WEI Jianshe, GONG Fuzhong, HE Xipu, MA Zhen, Synthesis and photoluminescence of CaMoO4:Eu3+ phosphor for white LEDs, Chemical Research and Application,  20(8), 952(2008) (周立亚, 王雷, 魏建设, 龚福忠, 何熙璞, 马 震, 白光LED用红色荧光粉CaMoO4 : Eu3+的制备及发光性能研究, 化学研究与应用,  20(8), 952(2008)) 8 J.H.Ryu, J.W.Yoon, K.B.Shim, Microwave-assisted synthesis of BaMoO4 nanocrystallites by a citrate complex method and their anisotropic aggregation, Journal of Alloys and Compounds,  413, 144(2006) 9 Ana Paula Azevedo Marques A, Dulce M.A. de Melo, lson Longo, Carlos A. Paskocimas, Paulo S. Pizani, Edson R. Leite, hotoluminescence properties of BaMoO4 amorphous thin films, Journal of Solid State Chemistry,  178, 2346(2005) 10 Y.S.Hu, W.D.Zhuang, H.Q.Ye, D.H.Wang, S.S.Zhang, X.W.Huang,   A novel red phosphor for white light emitting diodes, Journal of Alloys and Compounds,  390, 226(2005) 11 Q.M.Wang, B.Yan, Hydrothermal mild synthesis of microrod crystalline YxGd2-x(MoO4)3 : Eu3+ phosphors derived from facile co-precipitation precursors, Materials Chemistry and Physics, 94, 241(2005) 12 FU ShiLiu, YIN Tao, CHAI Fei, Solid state reaction mechanism and luminescence of Eu3+ doped Ca2SnO4 phosphor, Journal of Inorganic Materials,  22(4), 647(2007) (符史流, 尹涛, 柴飞, Ca2SnO4 : Eu3+固相反应形成机理及发光性质研究, 无机材料学报,  22(4), 647(2007)) 13GAO Shaokang, WANG Guimei, JIANG Yixiong, ZHAO Bin, CHEN Jianzhong, Studies on the nucleation of supersaturated ammonium tetramolybclate solution, Journal of Fuzhou University (Natural Science),  34(1), 137(2006) (高绍康, 王桂美, 蒋奕雄, 赵斌, 陈建中, 硝酸酸沉四钼酸铵过饱和溶液的成核研究, 福州大学学报(自然科学版), 34(1), 137(2006)) 14ZHANG Shiying, WEI kun, Study on luminescence property of nanocrystalline Y2O3 : Eu3+ red phosphor, Spectroscopy and Spectral Analysis,  24(4), 407(2004) (张世英, 魏坤, 纳米晶Y2O3 : Eu3+红色荧光体的发光性质研究, 光谱学与光谱分析,  24(4), 407(2004))
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