X90管线钢表面CuO超疏水涂层的制备和性能

doi:10.11901/1005.3093.2016.416

材料研究学报

2017, Vol. 31

Issue (9): 672-678 DOI: 10.11901/1005.3093.2016.416

研究论文

本期目录 | 过刊浏览

X90管线钢表面CuO超疏水涂层的制备和性能

韩祥祥, 于思荣(

), 李好, 胡锦辉

中国石油大学(华东)机电工程学院青岛 266580

Preparation and Properties of CuO Superhydrophobic Coating on X90 Pipeline Steel

Xiangxiang HAN, Sirong YU(

), Hao LI, Jinhui HU

College of Mechanical and Electronic Engineering,China University of Petroleum,Qingdao 266580,China

引用本文:

韩祥祥, 于思荣, 李好, 胡锦辉. X90管线钢表面CuO超疏水涂层的制备和性能[J]. 材料研究学报, 2017, 31(9): 672-678.
Xiangxiang HAN, Sirong YU, Hao LI, Jinhui HU. Preparation and Properties of CuO Superhydrophobic Coating on X90 Pipeline Steel[J]. Chinese Journal of Materials Research, 2017, 31(9): 672-678.

全文: PDF(1106 KB) HTML

摘要:

用电沉积方法在X90管线钢表面制备Cu保护层,经水热反应及全氟辛酸修饰后制备出CuO超疏水涂层。使用X射线衍射仪、扫描电子显微镜、红外光谱仪和接触角测量仪等手段对涂层表面的相组成、微观形貌、化学成分及润湿性进行表征,研究了涂层的机械稳定性、防粘附性和耐腐蚀性。结果表明,具有疏水性的全氟辛酸成功嫁接到了由“花瓣”状CuO组成的微纳米混合结构上,使涂层表面与水滴的接触角约为161.24°,滚动角为3°左右;这种涂层表面表现出良好的机械稳定性、防粘附性和耐腐蚀性。

关键词 ：金属材料, 超疏水, 机械稳定性, 防粘附, 耐腐蚀

Abstract：

Superhydrophobic coating of CuO was prepared on X90 pipeline steel substrate by a three step process, i.e. first a Cu protective layer was electrodeposited on the substrate, which then was treated by hydrothermal reaction and finally modified with perfluorooctanoic solution. The phase constitution, microstructure, chemical composition, and wettability of the coating were investigated by X-ray diffractometer, scanning electron microscope, Fourier transform infrared spectrometer, and contact angle tester. Its mechanical stability, anti-adhesion behavior and corrosion resistance were also examined. The results show that the perfluorooctanoic was successfully grafted on the surface of coating consisted of petal-like CuO with micro-nano hybrid structure. The contact angle of water to the coating surface was 161.24°, and the sliding angle was about 3°. Meanwhile, the as-prepared coating surface exhibits excellent mechanical stability, anti-adhesion behavior and corrosion resistance.

Key words： metallic materials superhydrophobic mechanical stability anti-adhesion corrosion resistance

收稿日期: 2016-07-19

ZTFLH:

TB34

基金资助:国家自然科学基金(51075184)

作者简介:

作者简介韩祥祥,男,1991年生,硕士

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https://www.cjmr.org/CN/10.11901/1005.3093.2016.416 或 https://www.cjmr.org/CN/Y2017/V31/I9/672

图1 不同处理阶段涂层的表面形貌和润湿性

图2 水热反应前后涂层表面的XRD图谱

图3 全氟辛酸及修饰后涂层表面的FT-IR图谱

图4 磨损测试的示意图以及CuO超疏水涂层表面接触角和滚动角与磨损距离的关系

图5 磨损1000 mm后CuO超疏水涂层的表面形貌

图6 3 μL水滴与CuO超疏水涂层表面接触、挤压和离开的过程

图7 CuO超疏水涂层表面的自清洁过程

图8 水滴吸附并带走CuO超疏水涂层表面的污染物颗粒

图9 X90管线钢、Cu涂层、CuO涂层以及CuO超疏水涂层的动电位极化曲线

表1 不同阶段表面动电位极化曲线的相关电化学参数

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