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Chin J Mater Res  2009, Vol. 23 Issue (5): 500-507    DOI:
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Electrochemical preparation of hydroxyapatite/TiO2 composite coatings on titanium alloy under magnetic field
TIAN Ang; LIN Caixia; XUE Xiangxin; GAO Peng
School of Materials and Metallurgy; Northeastern University; Shenyang 110004)
Cite this article: 

TIAN Ang LIN Caixia XUE Xiangxin GAO Peng. Electrochemical preparation of hydroxyapatite/TiO2 composite coatings on titanium alloy under magnetic field. Chin J Mater Res, 2009, 23(5): 500-507.

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Abstract  

Using sulfuric acid and phosphoric acid as electrolyte respectively, TiO2 coatings of different pore size and physical properties were prepared on titanium alloy matrix by potentiostatic anodic oxidation method. On the TiO2 coating, nano–hydroxyapatite (nHA) grain coatings was prepared by electro–deposition under the external magnetic field. When the magnetic field was applied perpendicular
to the current density, rod–like nHA crystals with a length scale of about 200 nm and an average diameter of about 50 nm were obtained. But when the magnetic field was parallel to the electric field, the hydroxyapatite grain presented as granular grain was about 50–70 nm in diameter. It was found that the matching degree between nano–hydroxyapatite and TiO2 coatings directly affected the bonding strength
between composite coatings and Ti alloy substrate. When the TiO2 coating with a pore diameter of 100 nm was implaned by rod–like nHA crystals, the combination between the two layers was stronger.

Key words:  surface and interface in the materials      hydroxyapatite      electrodeposition      TiO2 porous coating      static magnetic field     
Received:  19 January 2009     
ZTFLH: 

TB321

 
  R318

 
Fund: 

Supported by National Nature Science Foundation of China No.50872019.

URL: 

https://www.cjmr.org/EN/     OR     https://www.cjmr.org/EN/Y2009/V23/I5/500

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