Study on Energy Storage Properties of SrSC0.5Nb0.5O3 Modified BNT-based Lead-free Ceramics

doi:10.11901/1005.3093.2021.671

Chinese Journal of Materials Research

2023, Vol. 37

Issue (3): 228-234 DOI: 10.11901/1005.3093.2021.671

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Study on Energy Storage Properties of SrSC_0.5Nb_0.5O₃ Modified BNT-based Lead-free Ceramics

ZHU Mingxing¹, DAI Zhonghua²(

)

^1.Tongling Polytechnic Department of Mechanical Engineering, Tongling 244000, China
^2.School of Optoelectronic Engineering, Xi'an Technological University, Xi'an 710021, China

Cite this article:

ZHU Mingxing, DAI Zhonghua. Study on Energy Storage Properties of SrSC_0.5Nb_0.5O₃ Modified BNT-based Lead-free Ceramics. Chinese Journal of Materials Research, 2023, 37(3): 228-234.

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Abstract

A new lead-free ceramic system (1-x)(Bi_0.5Na_0.5Ti_0.95Al_0.025Nb_0.025O₃)-x(SrSc_0.5Nb_0.5O₃) [(1-x)BNTA-xSSN, x=0.05、0.1、0.15、0.2] was prepared by solid-state method. The effects of the introduction of SrSc_0.5Nb_0.5O₃ on the structure, phase transformation, energy storage and dielectric properties were studied. The results showed that (1-x)BNTA-xSSN owns perovskite structure at room temperature. The T_mdecreases with the increase of SSN content, and the phase structure changes from tetragonal phase to pseudo-cubic phase. The ferroelectric properties of the ceramics were weakened and the relaxation ferroelectric properties were enhanced. When x=10%, the maximum effective energy storage density (W_rec) of BNTA-SSN ceramics is 2.7 J/cm³. The maximum energy storage efficiency (η) of BNTA-SSN ceramics is 85% at x=15%.

Key words: inorganic non-metallic materials phase structure ceramics relaxor ferroelectrics energy storage density

Received: 06 December 2021

ZTFLH:

TQ174

Fund: National Natural Science Foundation of China(51062014);the Key Research and Development Program of Shaanxi Province(2023-YBGY-423);Xi'an Key Laboratory of Intelligence(2019220514SYS020CG042)

Corresponding Authors: DAI Zhonghua, Tel: 18092679085, E-mail: zhdai@mail.xjtu.edu.cn

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https://www.cjmr.org/EN/10.11901/1005.3093.2021.671 OR https://www.cjmr.org/EN/Y2023/V37/I3/228

Fig.1 XRD patterns of (1-x)BNTA-xSSN ceramics

Fig.2 SEM images of (1-x)BNTA-xSSN ceramics

Fig.3 Temperature-dependence of ɛ' and tanδ for (1-x)BNTA-xSSN ceramics x=5%; (b) x=10%; (c) x=15%; (d) x=20%

Fig.4 relationship between ln(1/ε-1/ε_m) and ln (T-T_c) and relationship between dispersion factor γ and SSN content for (1-x)BNTA-xSSN ceramics (x=5%, 10%, 15%, 20%)

Table 1 T_m and T_d for (1-x)(BNTA)-xSSN ceramics

Fig.5 (a) P-E curves of ceramics; (b) P-E curves of (1-x)(BNTA)-xSSN at 10Hz; (c) P-E curves of 0.90(BNTA)-0.10SSN ceramics under different electric fields; (d) P-E curves of 0.90(BNTA)-0.10SSN ceramics at different frequency

Fig 6 (a) Relationship between W and W_rec;_{(b) η and W_loss; (c) P_max, P_r and P_max-P_r; (d) the curves of P_max-P_rvsE for (1-x)(BNTA) -xSSN ceramics}

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