Preparation and Supercapacitor Performance of Few-Layered Ti3C2 with High Specific Capacitance

doi:10.11901/1005.3093.2021.441

Chinese Journal of Materials Research

2022, Vol. 36

Issue (3): 183-190 DOI: 10.11901/1005.3093.2021.441

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Preparation and Supercapacitor Performance of Few-Layered Ti₃C₂with High Specific Capacitance

WANG Yihao¹, WU Qiong¹(

), LI Pengfei¹, YANG Zhanxin¹, ZHANG Hongtao²

^1.School of Materials Science and Engineering, Liaoning University of Technology, Jinzhou 121001, China
^2.Liaoning Zhongse Xincai Technology Co. , Ltd, Jinzhou 121000, China

Cite this article:

WANG Yihao, WU Qiong, LI Pengfei, YANG Zhanxin, ZHANG Hongtao. Preparation and Supercapacitor Performance of Few-Layered Ti₃C₂with High Specific Capacitance. Chinese Journal of Materials Research, 2022, 36(3): 183-190.

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Abstract

Microwaves assisted selective etching technique was used to prepare few-layered Ti₃C₂ with atomic layer spacing of 1.28 nm. The mass specific capacitance is 377.64 F/g, which is 154.27% higher than that of multilayer Ti₃C₂. The kinetic analysis of two kinds of Ti₃C₂ electrochemical storage processes shows that the charge storage of few-layered Ti₃C₂ is mainly contributed by surface capacitance, which is 76.28%.

Key words: inorganic non-metallic materials microwave assisted etching few-layered Ti₃C₂ specific capacitance

Received: 13 August 2021

ZTFLH:

TQ152

Fund: National Natural Science Foundation of China(51971106)

About author: WU Qiong, E-mail: wuqiong9918@126.com

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	Yihao WANG
	Qiong WU
	Pengfei LI
	Zhanxin YANG
	Hongtao ZHANG

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https://www.cjmr.org/EN/10.11901/1005.3093.2021.441 OR https://www.cjmr.org/EN/Y2022/V36/I3/183

Fig.1 Schematic diagram and structure of few-layered Ti₃C₂ prepared by microwave assisted etching of hexagonal Ti₃AlC₂ (a) schematic diagram of microwave assisted etching device and reaction in cavity; (b, c) XRD of two kinds of Ti₃C₂

Fig.2 Morphology of Ti₃C₂ after microwave assisted etching

Fig.3 Microstructure of multilayer Ti₃C₂ and few-layered Ti₃C₂ (a, c, d, e) TEM and SAED images of multilayer Ti₃C₂ along the [110] crystal axis; (f, h, i, j) TEM and SAED images of multilayer Ti₃C₂ along the [0001] crystal axis; (b, g) molecular models of the two kinds of Ti₃C₂

Fig.4 Supercapacitor performance graph of multilayer Ti₃C₂ and few-layered Ti₃C₂ (a, b) CV curves; (c, d) GCD curves; (e) Long cycle charge-discharge cycle performance

Fig.5 Kinetic analysis of electrochemical energy storage process of multilayer Ti₃C₂ and few-layered Ti₃C₂ (a) current response plotted against scan rate at different voltages; (b, c) surface capacitance contribution to the total charge of multilayer Ti₃C₂ and few-layerd Ti₃C₂; (d) percentage of surface capacitance contribution at different scan rates

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