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Chinese Journal of Materials Research  2017, Vol. 31 Issue (8): 585-590    DOI: 10.11901/1005.3093.2016.547
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Performance of Silver-deposited Aramid Fibers
Fan YU, Cuiqing TENG(), Minglin QIN, Baihua LIU, Kang ZHANG, Jiaqi NI, Muhuo YU
College of Materials Science & Engineering, Donghua University, Shanghai 201620, China
Cite this article: 

Fan YU, Cuiqing TENG, Minglin QIN, Baihua LIU, Kang ZHANG, Jiaqi NI, Muhuo YU. Performance of Silver-deposited Aramid Fibers. Chinese Journal of Materials Research, 2017, 31(8): 585-590.

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Abstract  

Silver nano-particles were deposited on the surface of aramid fibers by a two-step process i.e. firstly coarsening the surface of aramid fibers with sodium hydroxide and then Ag electroless plating. The Ag-plated aramid fibers were characterized by scanning electron microscope (SEM), atomic force microscope (AFM), X-ray photoelectron spectrometer (XPS) and X-ray diffractometer (XRD). The mechanical properties, thermal stability, and electrical resistance of the Ag-plated aramid fibers were examined by thermogravimetric analyzer (TG) and digital multimeter. The results show that the plated Ag is homogeneous and compact; The plating process had little impact on the mechanical properties of the aramid fiber, while the Ag-plating could enhance its thermal stability; The electrical resistivity is as low as 0.52 Ω/cm. And the Ag-layer exhibits good stability in hot- and cold-water cyclic test or in salt solution.

Key words:  surface and interface in the materials      Ag-plated aramid fiber      electroless plating      sodium hydroxide     
Received:  18 September 2016     
ZTFLH:  TB333  
Fund: Supported by National Basic Research Program of China (No.2011CB606100)

URL: 

https://www.cjmr.org/EN/10.11901/1005.3093.2016.547     OR     https://www.cjmr.org/EN/Y2017/V31/I8/585

Materials Molecular formula Content Role
Silver nitrate AgNO3 0.15 mol/L silver salt
Sodium hydride NaOH 6 g/L pH adjuster
Ammonia NH3H2O right amount complexing agents
Glucose C6H12O6 0.15 mol/L reducers
Potassium sodium tartrate C4H4O6KNa6H2O 2.5 g/L complexing agent
Polyethylene glycol PEG2000 75 mg/L wetter
Ethanol C2H5OH 40 mL/L stabilizer
Table 1  Composition of the silver plating bath
Fig.1  SEM and AFM images of before (a,b,e) and after (c,d,f) Ag-plated aramid fiber
Fig.2  XPS wide-scan spectrum (a) and Ag 3d core-level spectrum (b) of Ag-plated aramid fiber
Fig.3  XRD patterns of (a) pristine and (b) Ag-plated aramid fiber
Fig.4  TG curves of pristine (a) and Ag-plated aramid fiber (b) under N2 condition
Fig.5  Strength and breaking elongation of aramid fiber (a-pristine, b-after roughening, c-after sensitization and activation, d-after Ag-plated aramid fiber)
Test Ag-plated aramid fiber Thermal cycling treatment 10%NaCl (mass fraction) 10%NaOH (mass fraction) 10%HCl (mass fraction)
Resistance/Ωcm-1 0.52 0.65 0.63 1.03 24.06
CV/% 4.92 4.81 7.36 5.01 2.37
Table 2  Resistance of Ag-plated aramid fiber and under different process conditions (Standard: Q/320000WY007-2008)
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