Please wait a minute...
Chin J Mater Res  2010, Vol. 24 Issue (4): 368-372    DOI:
论文 Current Issue | Archive | Adv Search |
Thermal Stability of Ti3AlC2 at Static High Pressure
LI Ziyang, KOU Zili,  AN Pei,  QIN Jiaqian
Institute of Atomic and Molecular Physics, Sichuan University, Chengdu 610065
Cite this article: 

LI Ziyang KOU Zili AN Pei QIN Jiaqian. Thermal Stability of Ti3AlC2 at Static High Pressure. Chin J Mater Res, 2010, 24(4): 368-372.

Download:  PDF(771KB) 
Export:  BibTeX | EndNote (RIS)      
Abstract  

Thermal stability of Ti3AlC2 at static high pressure was dealt with in this paper. It was found that the lowest reaction temperatures of Ti3AlC2 were all between 700 and 800oC at pressures of 2, 3, 4 and 5 GPa, respectively, and the final products mostly were Al3Ti and TiC. The decomposition reaction processes depended on the pressure.

Key words:  inorganic non-metallic materials        thermal stability        static high pressure       Ti3AlC2        reaction process     
Received:  07 April 2010     
ZTFLH: 

O521

 
Fund: 

Supported by National Natural Science Foundation of China Nos.50572067 and 10772126.

URL: 

https://www.cjmr.org/EN/     OR     https://www.cjmr.org/EN/Y2010/V24/I4/368

1 M.A.Pietzka, J.C.Schuster, Summary of constitutional data on the aluminum-carbon-titanium system, Journal of Phase Equilibria, 15(4), 392(1994) 2 M.W.Barsoum, The Mn+1AXn phases: a new class of solids: thermodynamically stable nanolaminates, Progress Solid State Chemistry, 28(1-4), 201(2000) 3 Y.C.Zhou, X.H.Wang, Z.M.Sun, S.Q.Chen, Electronic and structural properties of layered ternary carbide Ti3AlC2, Journal of Materials Chemistry, 11(9), 2335(2001) 4 X.H.Wang, Y.C.Zhou, Microstructure and properties of Ti3AlC2 prepared by the solid-liquid reaction synthesis and simultaneous in-situ hot pressing process, Acta Materialia, 50(12), 3141(2002) 5 X.H.Wang, Y.C.Zhou, Oxidation behavior of Ti3AlC2 at 1000–1400?C in air, Corrosion Science, 45(5), 891(2003) 6 CHEN Xiujuan, LI Jianwei, Progress in research of synthesize Ti3AlC2 ceramics, Powder Metallurgy Industry, 18(4), 40(2008) (陈秀娟, 李建伟, Ti3AlC2陶瓷材料研究进展, 粉末冶金工业,  18(4), 40(2008)) 7 X.H.Wang, Y.C.Zhou, Stability and selective oxidation of aluminum in nano-laminate Ti3AlC2 upon heating in argon, Chemistry of Materials, 15, 3716(2003) 8 Z.M.Sun, Y.C.Zhou, M.S.Li, Oxidation behaviour of Ti3SiC2-based ceramic at 900–1300oC in air, Corrosion Science, 43(6), 1095(2001) 9 Z.M.Sun, Y.C.Zhou, M.Li, Cyclic-Oxidation behavior of Ti3SiC2-based material at 1100 , Oxidation of Metals, 57, 379(2002) 10 J.Zhang, J.Y.Wang, Y.C.Zhou, Structure stability of Ti3AlC2 in Cu and microstructure evolution of Cu- Ti3AlC2 composites, Acta Materialia, 55, 4381(2007) 11 J.X.Chen, Y.C.Zhou, H.B.Zhang, D.T.Wan, M.Y.Liu, Thermal stability of Ti3AlC2/Al2O3 composites in high vacuum, Materials Chemistry and Physics, 104, 109(2007) 12 P.W.Mirwald, I.C.Getting, G.C.Kennedy, Low friction cell for pistoncylinder high-pressure apparatus, Journal of Geophysical Research Solid Earth, 80, 1519(1975) 13 J.Y.Wang, Y.C.Zhou, T.Liao, J.Zhang, Z.J.Lin, Phase stability of Ti2AlC suffering Al vacancy by first-principles investigations, Scripta Materialia, 58(3), 227(2008) 14 J.Emmerlich, D.Music, P.Ekund, O.Wilhelmssonc, U.Janssonc, J.M.Schneiderb, H.H¨ogberga, L.Hultmana, Thermal stability of Ti3SiC2 thin films, Acta Materialia, 55, 1479(2007) 15 M.W.Barsoum, T.El-Raghy, L.Farber, M.Amer, R.Christini, A.Adams, The topotaxial transformation of Ti3SiC2 to form a partially ordered cubic TiC0.67 phase by the diffusion of Si into molten cryolite, Journal of the Electrochemical Society, 146, 3919(1999) 16 X.H.Wang, Y.C.Zhou, High-temperature oxidation behavior of Ti2AlC in air, Oxidation of Metals, 59, 303(2003) 17 M.Beckers, N.R.Schell, M.S.Martins, A.M¨ucklich, W.M¨oller, Phase stability of epitaxially grown Ti2AlN thin films. Applied Physics Letters, 89, 074101(2006)
[1] SONG Lifang, YAN Jiahao, ZHANG Diankang, XUE Cheng, XIA Huiyun, NIU Yanhui. Carbon Dioxide Adsorption Capacity of Alkali-metal Cation Dopped MIL125[J]. 材料研究学报, 2023, 37(9): 649-654.
[2] SHAO Hongmei, CUI Yong, XU Wendi, ZHANG Wei, SHEN Xiaoyi, ZHAI Yuchun. Template-free Hydrothermal Preparation and Adsorption Capacity of Hollow Spherical AlOOH[J]. 材料研究学报, 2023, 37(9): 675-684.
[3] REN Fuyan, OUYANG Erming. Photocatalytic Degradation of Tetracycline Hydrochloride by g-C3N4 Modified Bi2O3[J]. 材料研究学报, 2023, 37(8): 633-640.
[4] LIU Mingzhu, FAN Rao, ZHANG Xiaoyu, MA Zeyuan, LIANG Chengyang, CAO Ying, GENG Shitong, LI Ling. Effect of Photoanode Film Thickness of SnO2 as Scattering Layer on the Photovoltaic Performance of Quantum Dot Dye-sensitized Solar Cells[J]. 材料研究学报, 2023, 37(7): 554-560.
[5] LI Yanwei, LUO Kang, YAO Jinhuan. Lithium Ions Storage Properties of Ni(OH)2 Anode Materials Prepared with Sodium Dodecyl Sulfate as Accessory Ingredient[J]. 材料研究学报, 2023, 37(6): 453-462.
[6] YU Moxin, ZHANG Shuhai, ZHU Bowen, ZHANG Chen, WANG Xiaoting, BAO Jiamin, WU Xiang. Preparation of Nitrogen-doped Biochar and its Adsorption Capacity for Co2+[J]. 材料研究学报, 2023, 37(4): 291-300.
[7] ZHU Mingxing, DAI Zhonghua. Study on Energy Storage Properties of SrSC0.5Nb0.5O3 Modified BNT-based Lead-free Ceramics[J]. 材料研究学报, 2023, 37(3): 228-234.
[8] LIU Zhihua, YUE Yuanchao, QIU Yifan, BU Xiang, YANG Tao. Preparation of g-C3N4/Ag/BiOBr Composite and Photocatalytic Reduction of Nitrate[J]. 材料研究学报, 2023, 37(10): 781-790.
[9] ZHOU Yi, TU Qiang, MI Zhonghua. Effect of Preparing Methods on Structure and Properties of Phosphate Glass-ceramics[J]. 材料研究学报, 2023, 37(10): 739-746.
[10] XIE Feng, GUO Jianfeng, WANG Haitao, CHANG Na. Construction of ZnO/CdS/Ag Composite Photocatalyst and Its Catalytic and Antibacterial Performance[J]. 材料研究学报, 2023, 37(1): 10-20.
[11] FANG Xiangming, REN Shuai, RONG Ping, LIU Shuo, GAO Shiyong. Fabrication and Infrared Detection Performance of Ag-modified SnSe Nanotubes[J]. 材料研究学报, 2022, 36(8): 591-596.
[12] LI Fulu, HAN Chunmiao, GAO Jiawang, JIANG Jian, XU Hui, LI Bing. Temperature Dependent Luminescence Properties of Graphene Oxide[J]. 材料研究学报, 2022, 36(8): 597-601.
[13] ZHU Xiaodong, XIA Yangwen, YU Qiang, Yang Daixiong, HE Lili, FENG Wei. Preparation and Characterization of Cu Doped Rutile TiO2 and Photocatalytic Property[J]. 材料研究学报, 2022, 36(8): 635-640.
[14] XIONG Tinghui, CAI Wenhan, MIAO Yu, CHEN Chenlong. Simultaneous Epitaxy Growth and Photoelectrochemical Performance of ZnO Nanorod Arrays and Films[J]. 材料研究学报, 2022, 36(7): 481-488.
[15] MENG Xiangdong, ZHEN Chao, LIU Gang, CHENG Huiming. Controlled Synthesis of CuO Nanoarrays as Efficient Photocathodes for Photoelectrochemical (PEC) for Water Splitting[J]. 材料研究学报, 2022, 36(4): 241-249.
No Suggested Reading articles found!