Effect of Co Content on Tribological Behavior of Ni-Co-Al P/M Superalloy

doi:10.11901/1005.3093.2014.019

Chinese Journal of Materials Research

2014, Vol. 28

Issue (7): 490-496 DOI: 10.11901/1005.3093.2014.019

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Effect of Co Content on Tribological Behavior of Ni-Co-Al P/M Superalloy

Chenglai XIN^1,²,Wenzhen WANG^1,^**(

),Qin MA²,Hongjian GUO¹

1. State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000
2. School of Materials Science and Engineering, Lanzhou University of Technology, Lanzhou 730050

Cite this article:

Chenglai XIN,Wenzhen WANG,Qin MA,Hongjian GUO. Effect of Co Content on Tribological Behavior of Ni-Co-Al P/M Superalloy. Chinese Journal of Materials Research, 2014, 28(7): 490-496.

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Abstract

Ni-Co-Al high temperature alloys with different Co content were prepared by powder metallurgy (mechanical alloying and hot-press sintering), of which the high temperature tribological properties were investigated at 800℃. The results showed that the hardness and compressive strength, as well as the tribological properties of alloys could be improved with a Co addition in a range from 5-30 mass%, among which 20 mass% is the optimal. The observation of worn surfaces by SEM, XPS and EDS revealed that a “glaze-like film” consisted of CoO and other oxides existed on the worn surface. The high temperature tribological properties of the alloys are highly related with the composition and the spallation tendency of the formed glaze film during the friction and wear process.

Key words: metallic materials P/M superalloy tribological behavior oxide

Received: 18 January 2014

Fund: *Supported by National Natural Science Foundation of China No. 51101166.

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	Chenglai XIN
	Wenzhen WANG
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	Hongjian GUO

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https://www.cjmr.org/EN/10.11901/1005.3093.2014.019 OR https://www.cjmr.org/EN/Y2014/V28/I7/490

表1 合金的成分和球磨、热压烧结主要参数及烧结试样的密度

Fig.1 XRD spectra of mixed powder with different Co contents after ball-milling

Fig.2 XRD spectra of sintered specimens with different Co contents

Fig.3 SEM images of alloys after electrolytic corrosion (a) NA, (b) NAC10, (c) NAC20

Fig.4 Variations of hardness and compressive strength with Co content of alloys

Fig.5 Variations of friction coefficient and wear rate of alloys with Co contents at 800℃

Fig.6 Variations of friction coefficient with time at 800℃

Fig.7 SEM images of wear surfaces of alloys (a) NA, (b) NAC5, (c) NAC20, (d) NAC30

Fig.8 XPS patterns of elements of worn surface of NAC20

表2 Frictional coeffcients of single oxide(matched with stainless steel)

Table 3 Comparison table of Binding energy

Table 4 Elements content of wore surfaces of alloys after 800℃ (%, mass fraction)

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