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Influence of Y2O3 and Nano-AlN Powders on the Sintering and Thermal Conductivity of AlN Ceramics |
YANG Qinghua1 LI Hongwei1 WANG Huanping1 MA Hongping2 LEI Ruoshan1 XU Shiqing1** |
1. College of Materials Science and Engineering, China Jiliang University, Hangzhou 310018 2. School of Mechanical & Automotive Engineering, Zhejiang University of Science and Technology, Hangzhou 310023 |
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Cite this article:
YANG Qinghua LI Hongwei WANG Huanping MA Hongping LEI Ruoshan XU Shiqing**. Influence of Y2O3 and Nano-AlN Powders on the Sintering and Thermal Conductivity of AlN Ceramics. Chinese Journal of Materials Research, 2013, 27(4): 342-348.
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Abstract AlN ceramics doped with 4% Y2O3 and appropriate nano-AlN powders were sintered at 1700-1850℃, the influences of Y2O3 and nano-AlN powders on the sintering and thermal conductivity of AlN ceramics were investigated. The results show that the Al2O3 powders distributed in the surface of nano-AlN took the priority to react with Y2O3, and second phase of Al5Y3O12 with higher activity were gotten, which could form liquid at lower temperature. In addition, the nano-AlN powders can also promote the density of AlN ceramics. The two factors have a synergetic action on the sintering of AlN ceramics, and can improve the distribution of second phase in the microstructure of AlN ceramics. Therefore, AlN ceramics with higher thermal conductivity can be prepared at lower sintering temperature. The AlN ceramics with 4% Y2O3 and 1.5% nano-AlN doped, sintered at 1800℃ have a density of 3.26 gcm-3and a thermal conductivity of 151.75 W/(mK) , and second phase distributes in the boundaries of AlN grains.
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