Properties of Ti-based PbO2 Electrocatalytic Anodes with an Arc Sprayed ZrN-interlayer

doi:10.11901/1005.3093.2019.578

Chinese Journal of Materials Research

2020, Vol. 34

Issue (7): 527-534 DOI: 10.11901/1005.3093.2019.578

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Properties of Ti-based PbO₂ Electrocatalytic Anodes with an Arc Sprayed ZrN-interlayer

TANG Changbin¹(

), WANG Fei¹, NIU Hao¹, YU Lihua¹, XUE Juanqin¹, YIN Xiangyang²

1.School of Metallurgy and Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, China
2.Shaanxi Xinxing Thermal Spraying Technology Co. Ltd. , Xi'an 710000, China

Cite this article:

TANG Changbin, WANG Fei, NIU Hao, YU Lihua, XUE Juanqin, YIN Xiangyang. Properties of Ti-based PbO₂ Electrocatalytic Anodes with an Arc Sprayed ZrN-interlayer. Chinese Journal of Materials Research, 2020, 34(7): 527-534.

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Abstract

The Ti/ZrN/PbO₂ electrodes were prepared via an arc spraying ZrN-interlayer on the Ti-substrate and then followed by anodic electrodeposition of β-PbO₂ surface coating. By taking the plain Ti/PbO₂ electrode as comparison, the prepared electrodes were characterized in terms of microstructure, surface roughness, coating adhesion, accelerated life assessment, electrochemical performance and electro-oxidation of phenol. The results show that the accelerated life-time for Ti/ZrN/PbO₂ anodes was obviously prolonged to 8 times of that for the plain Ti/PbO₂electrode. Meanwhile, the electrocatalytic degradation activity of this anode for the organic pollutants was enhanced. This is directly related to the improvement of the conductivity of the electrode brought by the arc sprayed ZrN interlayer and which then enables the layer of electrodeposited PbO₂ to be significantly refined and thicker with much flat surface and better adhesive to the substrate, as well as more active sites caused by the rough surface characteristics of this arc spraying intermediate layer.

Key words: surface and interface in the materials titanium-based lead dioxide anode interlayer zirconium nitride arc spray coating electro-oxidation life extension

Received: 10 December 2019

ZTFLH:

TQ174

Fund: National Natural Science Foundation of China(51874227);the Natural Science Basic Research Plan of Shaanxi Province(2018JM5131);the Natural Science Basic Research Plan of Shaanxi Province(2018JM5139)

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	Changbin TANG
	Fei WANG
	Hao NIU
	Lihua YU
	Juanqin XUE
	Xiangyang YIN

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https://www.cjmr.org/EN/10.11901/1005.3093.2019.578 OR https://www.cjmr.org/EN/Y2020/V34/I7/527

Fig.1 Schematic diagram of ZrN interlayer prepared by arc spraying (1: spraying power supply; 2: wire disk; 3: metal wire; 4: wire feeding roller; 5: conductive block; 6: conductive nozzle; 7: air nozzle; 8: compressed air; 9: arc; 10: spraying particle flow; 11: ZrN coating; 12: titanium substrate)

Fig.2 Results analysis of PbO₂coated electrodes fabricated by electrodepositing and ZrN interlayer prepared by arc spraying (a) Morphology of ZrN interlayer (b) XRD spectrum of the interlayer (c) surface morphology of Ti/ZrN/PbO₂ electrode (d) XRD comparison of PbO₂ electrode with and without the interlayer (E) sur- face morphology of Ti/PbO₂ electrode (f) crossed-morphology of Ti/ZrN/PbO₂ electrode (g) surface rough- ness comparison of Ti/ZrN/PbO₂ electrode

Fig.3 Cell voltage vs. time variation of electrodes in accelerated life test

Table 1 Lifetime comparison between this study and Ti-based PbO₂ electrodes reported in literatures

Fig.4 Electrocatalytic activity site test (a) and Nyquist plot of kinetics process (b) of oxygen evolution reaction for Ti/ZrN/PbO₂ electrode

Table 2 EIS impedance fitting results of oxygen evolution reaction

Fig.5 Comparison of the removal rate of phenol and COD vs. time (a) and kinetic fitting (b) during the electrocatalytic degradation process of phenol wastewater

Table 3 Degradation kinetics comparison of different electrodes

[1]	Chen B M, Wang S C, Liu J H, et al. Corrosion resistance mechanism of a novel porous Ti/Sn-Sb-RuO_x/β-PbO₂ anode for zinc eletrowinning [J]. Corrosion Science, 2018, 144: 136 doi: 10.1016/j.corsci.2018.08.049
[2]	He J X, Zhou J C,Chen K N. Electrochemical synthesis of butyl butyrate on conductive oxide electrode [J]. Electrochemistry, 1998,4 (4): 423
	(何俊翔, 周锦成, 陈康宁. 导电氧化物电极上丁酸丁酯电化学合成的研究 [J]. 电化学, 1998, 4(4): 423)
[3]	Yang W T, Yang W H, Fu F. Preparation and Characterization of PbO₂ electrode modified with a mixture of PEG and CPB [J]. Chinese Journal of Materials Research, 2012, 26(1): 8
	(杨武涛, 杨卫华, 付芳. PEG/CPB复配改性二氧化铅电极的制备和性能 [J]. 材料研究学报, 2012, 26(1): 8)
[4]	Bian X Z, Xia Y, Zhan T T, et al. Electrochemical removal of amoxicillin using a Cu doped PbO₂ electrode: Electrode characterization, operational parameters optimization and degradation mech-anism [J]. Chemosphere, 2019, 233: 762 pmid: 31200136
[5]	Duan X Y, Zhao C M, Liu W, et al. Fabrication of a novel PbO₂ electrode with a graphene nanosheet interlayer for electrochemical oxidation of 2-chlorophenol [J]. Electrochimica Acta, 2017, 240: 424 doi: 10.1016/j.electacta.2017.04.114
[6]	Zhao G H, Zhang Y G, Lei Y Z, et al. Fabrication and electrochemical treatment application of a novel lead dioxide anode with superhydrophobic surface, high oxygen evolution potential, and oxidation capability [J]. Environmental science & technology, 2010, 44 (5): 1754 pmid: 20180602
[7]	Zhang Z X. Application of titanium coated electrode for forty years [J]. 2007, 26(1): 50
	(张招贤. 涂层电极的40年 [J]. 电镀与涂层, 2007, 26(1): 50)
[8]	Zhang W L, Kong H S, Lin H B, et al. Fabrication characterization and electrocatalytic application of a lead dioxide electrode with porous titanium substrate [J]. Journal of Alloys and Compounds, 2015, 650: 705 doi: 10.1016/j.jallcom.2015.07.222
[9]	Jiang Y, Hu Z, Zhou Met al. Efficient degradation of p-nitrophenol by electro-oxidation on Fe doped Ti/TiO₂ nanotube/PbO₂ anode [J]. Separation & Purification Technology, 2014, 128(325): 67
[10]	Li X L, Xu H, Yan W. Electrochemical oxidation of aniline by a novel Ti/TiO_xHy/Sb-SnO₂ electrode [J]. Chinese Journal of Catalysis, 2016, 37(11): 1860 doi: 10.1016/S1872-2067(16)62555-X
[11]	Chen B M, Guo Z C, Yang X W, et al. Progress on electrodeposition of doped-PbO₂ surface [J]. The Chinese Journal of Nonferrous Metals, 2008, 18(9): 1711
	(陈步明, 郭忠诚, 杨显万等. 电沉积掺杂二氧化铅表面的研究进展 [J]. 中国有色金属学报, 2008, 18(9): 1711)
[12]	Yang H T, Chen B M, Guo Z C, et al. Effects of current density on preparation and performance of Al/conductive coing/α-PbO₂-CeO₂-TiO₂/β-PbO₂-MnO₂-WC-ZrO₂ composite electrode materials [J]. Transaction of Nonferrous Metals Society of China, 2014: 24(10): 3394 doi: 10.1016/S1003-6326(14)63482-8
[13]	Sun F M, Pan J Y, Luo Q F. Preparation and properties of lead dioxide anode with platinum interlayer [J]. Materials Protection, 2006, 39(1): 53
	(孙凤梅, 潘建跃, 罗启富. 含铂中间层二氧化铅阳极的制备及其性能 [J]. 材料保护, 2006, 39(1): 53)
[14]	Wang Y Q,Gu B,Xu W L,et al. Electrochemical oxidation of Phenol on Ti-Based PbO₂ Electrodes [J]. Rare Metal Materials and Engineering, 2007, 36(5): 874
	(王雅琼, 顾彬, 许文林等. 钛基PbO₂电极上苯酚的电化学氧化 [J]. 稀有金属材料与工程, 2007, 36(5): 874)
[15]	Tang C B, Zheng C, Yu L H, et al. Effect of electroplating nickel inter-layer on performance of Ti-based lead dioxide electrodes [J]. Rare Metal Materials and Engineering, 2019, 48(1): 143
	(唐长斌, 郑超, 于丽花等. 电镀镍中间层对钛基二氧化铅阳极性能的影响 [J]. 稀有金属材料与工程, 2019, 48(1): 143)
[16]	Xu L, Zhao F, Nong J Y, et al. Preparation, characterization and electro-catalytic properties investigation of lead dioxide electrode [J]. Chinese Journal of Environmental Engineering, 2008, 2(7): 97
	(徐亮, 赵芳, 农佳莹等. 二氧化铅电极的制备、表征及其电催化性能研究 [J]. 环境工程学报, 2008, 2(7): 97)
[17]	Liang Y J, Che M C. Handbook of Thermodynamics of Inorganic Materials [M]. Shen Yang: Northeast University Press, 1993
	(梁英教, 车荫昌. 无机物热力学数据手册 [M]. 沈阳: 东北大学出版社, 1993)
[18]	Sirés I., Low C. T. J., Ponce-de-León C., et al. The characterisation of PbO₂-coated electrodes prepared from aqueous methanesulfonic acid under controlled deposition conditions [J]. Electrochimica Acta, 2010, 55(6): 2163 doi: 10.1016/j.electacta.2009.11.051
[19]	Xia Y, Dai Q, Chen J. Electrochemical degradation of aspirin using a Ni doped PbO₂ electrode [J]. Journal of Electroanalytical Chemistry, 2015, 744: 117 doi: 10.1016/j.jelechem.2015.01.021
[20]	Li X, Xu H, Yan W. Effects of twelve sodium dodecyl sulfate (SDS) on electro-catalytic performance and stability of PbO₂, electrode [J]. Journal of Alloys and Compounds, 2017, 718: 386 doi: 10.1016/j.jallcom.2017.05.147
[21]	Song S, Fan J, He Z, et al. Electrochemical degradation of azo dye C. I. Reactive Red 195 by anodic oxidation on Ti/SnO₂-Sb/PbO₂ electrodes [J]. Electrochimica Acta, 2010, 55(11): 606
[22]	Amado-Piña Deysi, Roa-Morales Gabriela, Barrera-Díaz Carlos, et al. Synergic effect of ozonation and electrochemical methods on oxidation and toxicity reduction: Phenol degradation [J]. Fuel, 2017, 198: 82 doi: 10.1016/j.fuel.2016.10.117

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