Preparation and Catalyst Properties of S2O2-8/Al–Zn–O Solid Acid Modified by Ce

Chin J Mater Res

2011, Vol. 25

Issue (5): 522-526 DOI:

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Preparation and Catalyst Properties of S₂O^2-₈/Al–Zn–O Solid Acid Modified by Ce

PAN Hui¹, WANG Junxia¹, MENG Dawei^1,2, CHENG Ming¹, WANG Yongqian¹, LIU Xiaoyang²,

1.Engineering Research Center of Nano–Geo Materials of the Ministry of Education, Faculty of Materials Science and Chemical Engineering, China University of Geosciences, Wuhan 430074
2.State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012

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PAN Hui WANG Junxia MENG Dawei CHENG Ming WANG Yongqian LIU Xiaoyang. Preparation and Catalyst Properties of S₂O^2-₈/Al–Zn–O Solid Acid Modified by Ce. Chin J Mater Res, 2011, 25(5): 522-526.

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Abstract S2O2−8 /Al–Zn–Ce–O solid acid catalysts were synthesized by sol–gel. The structures and properties of the catalyst were characterized by means of infrared spectrum (IR), X–ray powder diffraction (XRD), thermogravimetric analysis–differential scanning calorimetry (TG/DSC) and scanning electron microscopy (SEM). The catalytic activities and reusabilities for the synthesis of n–butyl acetate from acetic acid and n-butanol were investigated. Compared with S2O2−8 /Al–Zn–O solid acid catalyst, S2O2−8 /Al–Zn–Ce–O solid acid catalyst exhibited better stability with above 94% esterification efficiency even after being used repeatedly for five times.

Key words: inorganic non-metallic materials Al-based solid acids modification esterification reaction catalytic properties

Received: 23 February 2011

ZTFLH:	TB321
	O643

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Supported by the Special Fund for Basic Scientific Research of Central Colleges, China University of Geosciences (Wuhan) No.CUGL09 0227.

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https://www.cjmr.org/EN/ OR https://www.cjmr.org/EN/Y2011/V25/I5/522

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