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| Effect of SO2−4 on the Structure and Luminescence Properties of Manganese-doped Sulfophosphate Glasses |
| YANG Yifan1, ZENG Huidan1, REN Jing1, CHEN Danping2, CHEN Guorong1, |
1.Key Laboratory for Ultrafine Materials of Ministry of Education, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237
2. Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800 |
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Cite this article:
YANG Yifan ZENG Huidan REN Jing CHEN Danping CHEN Guorong. Effect of SO2−4 on the Structure and Luminescence Properties of Manganese-doped Sulfophosphate Glasses. Chin J Mater Res, 2011, 25(5): 517-521.
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Abstract Manganese-doped sulfophosphate glasses (P2O5–ZnO–ZnSO4–Na2O) were synthesized by traditional melting–quenching method. The structure and luminescence properties of the glasses with varying SO2−4 content were studied. The results revealed that a broad emission band of Mn2+ from 500 to 750 nm excited by a 409 nm laser was observed. With the introduction of SO2−4 , the ligand field around Mn2+ was affected, resulting in the increasing of the luminescence intensity and full width at half maximum (FWHM) of Mn2+ emission.
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Received: 01 July 2011
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| Fund: Supported by the Shanghai Leading Academic Discipline Project B502 and the Fundamental Research Funds for the Central Universities WD1014035. |
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